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arXiv:2505.07152

Ordering of Energy Levels in the Fröhlich Model

Fumio Hiroshima, Akihiro Kobayashi, Tadahiro Miyao, Shunsuke Tomioka

Published May 11, 2025• 0 citations
arXivHTMLPDF

Abstract

Consider a one-dimensional system of \( N \) electrons subject to an external potential \( U \). Let \( E_{\rm el}(S) \) denote the ground state energy of the system with total spin \( S \). The Mattis--Lieb theorem asserts that, for a broad class of potentials \( U \), the inequality \( E_{\rm el}(S) < E_{\rm el}(S') \) holds whenever \( S < S' \). This result implies that the ground state of a one-dimensional many-electron system is non-ferromagnetic. In the present work, we demonstrate that the Mattis--Lieb theorem can be extended to electron-phonon interacting systems governed by the Fröhlich model. Our analysis is carried out in the setting without an ultraviolet cutoff. The cornerstone of our approach is the construction of a Feynman--Kac-type formula for the heat semigroup generated by the Fröhlich Hamiltonian.

DOI
10.48550/arxiv.2505.07152

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Consider a one-dimensional system of ( N ) electrons subject to an external potential ( U ). Let ( E_{\rm el}(S) ) denote the ground state energy of the system with total spin ( S ). The Mattis--Lieb theorem asserts that, for a broad class of potentials ( U ), the inequality ( E_{\rm el}(S) < E_{\rm el}(S') ) holds whenever ( S < S' ). This result implies that the ground state of a one-dimensional many-electron system is non-ferromagnetic. In the present work, we demonstrate that the Mattis--Lieb theorem can be extended to electron-phonon interacting systems governed by the Fröhlich model. Our analysis is carried out in the setting without an ultraviolet cutoff. The cornerstone of our approach is the construction of a Feynman--Kac-type formula for the heat semigroup generated by the Fröhlich Hamiltonian.
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A theorem about the spin properties of the ground state and the ordering of the energy levels for different spins of an interacting-electron model including an arbitrary diagonal interacting potential, an antiferromagnetic exchange, and an electron pair-hopping term for particles on a one-dimensional lattice is stated and proved. We show that when the number of electrons N=4n+2 (n an integer) with periodic boundary conditions or N=4n with antiperiodic boundary conditions, the ground state is a nondegenerate singlet. This theorem generalizes a similar theorem Lieb and Mattis proved for the one-dimensional interacting electron system.
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Recently Feynman's path-integral formalism of the Fröhlich optical polaron problem is generalized, by which it is easy and natural to get the second-order perturbation result in the weak-coupling case and the Pekar's result in the strongcoupling case, even in the crudest ground-state approximation. By using numerical method to the equations which are given by the ground-state approximation, the ground-state energy of the electron-optical phonon system can obtained for the overall range of coupling strength. In addition, a self-consistent set of equations is derived for a central optimized potential without using the ground-state approximation. This effective local, central potential is the solution of a linear integral equation which was similar to the extensive work of optimized-potential model (OPM) in atomic physics. By using OPM formalism, no particular choice of interaction form is taken, therefore, except the approximation by Jensen's inequality, the ground-state energy of the electron-optical phonon interacting system can be obtained without any approximation.