Abstract Conventional autonomous quantum refrigerators rely on uncorrelated heat exchange between the working system and baths via two-body interactions enabled by single-photon transitions and positive-temperature work baths, inherently limiting their cooling performance. Here, we introduce distinct qutrit refrigerators that exploit correlated heat transfer via two-photon transitions with the hot and cold baths, yielding a genuine enhancement in performance over conventional qutrit refrigerators that employ uncorrelated heat transfer. These refrigerators achieve at least a twofold enhancement in cooling power and reliability compared to conventional counterparts. Moreover, we show that cooling power and reliability can be further enhanced simultaneously by several folds, even surpassing existing cooling limits, by utilizing a synthetic negative-temperature work bath. Such refrigerators can be realized by combining correlated heat transfer and synthetic work baths, which consist of a four-level system coupled to hot and cold baths and two conventional work baths via two independent two-photon transitions. Here, the composition of two work baths effectively creates a synthetic negative-temperature work bath under suitable parameter choices. Additionally, our autonomous refrigerators with negative temperature baths significantly outperform previously studied autonomous and non-autonomous refrigerators in terms of cooling ability without requiring any additional energy resources, as they cool the cold bath to much lower temperature, which is forbidden for others refrigerators. Our results demonstrate that correlated heat transfers and baths with negative temperatures can yield thermodynamic advantages in quantum devices. Finally, we discuss the experimental feasibility of the proposed refrigerators across various existing platforms.
Abstract Conventional autonomous quantum refrigerators rely on uncorrelated heat exchange between the working system and baths via two-body interactions enabled by single-photon transitions and positive-temperature work baths, inherently limiting their cooling performance. Here, we introduce distinct qutrit refrigerators that exploit correlated heat transfer via two-photon transitions with the hot and cold baths, yielding a genuine enhancement in performance over conventional qutrit refrigerators that employ uncorrelated heat transfer. These refrigerators achieve at least a twofold enhancement in cooling power and reliability compared to conventional counterparts. Moreover, we show that cooling power and reliability can be further enhanced simultaneously by several folds, even surpassing existing cooling limits, by utilizing a synthetic negative-temperature work bath. Such refrigerators can be realized by combining correlated heat transfer and synthetic work baths, which consist of a four-level system coupled to hot and cold baths and two conventional work baths via two independent two-photon transitions. Here, the composition of two work baths effectively creates a synthetic negative-temperature work bath under suitable parameter choices. Additionally, our autonomous refrigerators with negative temperature baths significantly outperform previously studied autonomous and non-autonomous refrigerators in terms of cooling ability without requiring any additional energy resources, as they cool the cold bath to much lower temperature, which is forbidden for others refrigerators. Our results demonstrate that correlated heat transfers and baths with negative temperatures can yield thermodynamic advantages in quantum devices. Finally, we discuss the experimental feasibility of the proposed refrigerators across various existing platforms.
Conventional continuous quantum heat engines with incoherent heat transfer perform poorly as they exploit two-body interactions between the system and hot or cold baths, thus having limited capability to outperform their classical counterparts. We introduce distinct continuous quantum heat engines that utilize coherent heat transfer with baths, yielding genuine quantum enhancement in performance. These coherent engines consist of one qutrit system and two photonic baths and enable coherent heat transfer via two-photon transitions involving three-body interactions between the system and hot and cold baths. We demonstrate that coherent engines deliver significantly higher power output with much greater reliability, i.e., lower signal-to-noise ratio of the power, by hundreds of folds over their incoherent counterparts. Importantly, coherent engines can operate close to or at the maximal achievable reliability allowed by the quantum thermodynamic uncertainty relation. Moreover, coherent engines manifest more nonclassical features than incoherent engines because they violate the classical thermodynamic uncertainty relation by a greater amount and for a wider range of parameters. These genuine enhancements in the performance of coherent engines are directly attributed to their capacity to harness higher energetic coherence for the resonant driving case. The experimental feasibility of coherent engines and the improved understanding of how quantum properties can enhance performance may find applications in quantum enabled technologies.
Abstract We propose a model of two identical autonomous quantum refrigerators that interact through their qubits coupled to cold thermal baths. We consider the same specific disposition for each refrigerator related to a three-level system coupled to different thermal baths and, in turn, to a qubit as the object to be cooled. By coupling the two systems, we show that under certain conditions on the model parameters, the devices can operate in the regime of an independent autonomous quantum refrigerator or be subject to an adjustment of the thermodynamic performances. We further investigate the correlations induced by the interaction between the two refrigerators, and illustrate their behavior with respect to their thermodynamic performances. We have found that adjusting the different interaction constants of the model can lead to an evolution of the quantum correlations of the two machines that is inversely related to the behavior of the thermodynamic quantities of both refrigerators. However, this is not necessarily the case when the temperatures of the model are considered as the reference parameters.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
We propose a quantum absorption refrigerator driven by photons. The model uses a four-level system as its working substance and couples simultaneously to hot, cold, and solar heat reservoirs. Explicit expressions for the cooling power Q̇(c) and coefficient of performance (COP) η(COP) are derived, with the purpose of revealing and optimizing the performance of the device. Our model runs most efficiently under the tight coupling condition, and it is consistent with the third law of thermodynamics in the limit T→0.
We examine a quantum absorption refrigerator that comprises three qubits, each of which is connected with a separate spin-star environment, with the three qubit-bath units coupled through an effective six-body interaction. The refrigerator exhibits the feature of transient cooling, i.e., lowering of the temperature of the first qubit in sufficiently small timescales, rather than steady-state refrigeration. A key advantage of our model is that the symmetries of the Hamiltonian enable a semi-analytic solution of the reduced density matrices of the refrigerator qubits, even in the presence of a large number of environmental spins. We derive the condition for autonomous refrigeration and analyze how the optimal cold-qubit temperature scales with the number of bath spins. We find a power-law scaling towards a constant asymptotic value. We also find the scaling of the minimum time required for optimal cooling as a function of the number of bath spins. Furthermore, we quantify the non-Markovianity of the cold-qubit dynamics using a restricted Breuer-Laine-Piilo information-backflow measure and observe that stronger backflow correlates with lower transient minimum temperatures across the sampled parameter regime. The transient-cooling performance is found to be robust under broad parameter variations. Compared to a conventional Markovian three-qubit refrigerator, the CSQAR achieves lower cold-qubit temperatures on shorter timescales. We further analyze the heat currents associated with the three qubits and their respective baths.
We study the self-contained three-qubit quantum refrigerator, with a three-body interaction enabling cooling of the target qubit, in presence of baths composed of anharmonic quantum oscillators with Kerr-type nonlinearity. We show that such baths, locally connected to the three qubits, opens up the opportunity to implement superior steady-state cooling compared to using harmonic oscillator baths, aiding in access to the free energy required for empowering the refrigerator function autonomously. We find that in spite of providing significant primacy in steady-state cooling, such anharmonic baths do not impart much edge over using harmonic oscillator baths if one targets transient cooling. However, we gain access to steady-state cooling in the parameter region where only transient cooling could be achieved by using harmonic baths. Subsequently, we also study the scaling of steady-state cooling advantage and the minimum attainable temperature for varying levels of anharmonicity present in the bath oscillators. Finally, we analyse heat currents and coefficients of performance of quantum refrigerators using bath modes involving Kerr-type nonlinearity, and present a comparison with the case of using bosonic baths made of simple harmonic oscillators. On the way, we derive the decay rates in the Gorini-Kossakowski-Sudarshan-Lindblad quantum master equation for Kerr-type anharmonic oscillator baths.