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arXiv:2503.04152

Thermalization and irreversibility of an isolated quantum system

Xueyi Guo

Published Mar 6, 2025• 0 citations
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Abstract

The irreversibility and thermalization of many-body systems can be attributed to the erasure of spread non-equilibrium state information by local operations. This thermalization mechanism can be demonstrated by the sequence of $\hat{O}_i(t_i)$, where $\hat{O_i}$ is a local operator, $\hat{O_i}(t_i) = e^{i\hat{H}t_i} \hat{O_i} e^{-i\hat{H}t_i}$, $\hat{H}$ is the system Hamiltonian, $t_i$ can take positive, negative, or zero values, and the sequence is arranged according to the subscript $i$. We numerically demonstrate the information erasure of initial non-equilibrium quantum states through such sequence in a one-dimensional Hubbard model. During this process, the system's entanglement entropy increases monotonically toward a stable value. By incorporating this information erasure mechanism into an isolated system, our numerical simulations reveal that in this completely isolated system, a thermalization process emerges.

DOI
10.48550/arxiv.2503.04152

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The irreversibility and thermalization of many-body systems can be attributed to the erasure of spread non-equilibrium state information by local operations. This thermalization mechanism can be demonstrated by the sequence of O^i(ti)\hat{O}_i(t_i)O^i​(ti​), where Oi^\hat{O_i}Oi​^​ is a local operator, Oi^(ti)=eiH^tiOi^e−iH^ti\hat{O_i}(t_i) = e^{i\hat{H}t_i} \hat{O_i} e^{-i\hat{H}t_i}Oi​^​(ti​)=eiH^ti​Oi​^​e−iH^ti​, H^\hat{H}H^ is the system Hamiltonian, tit_iti​ can take positive, negative, or zero values, and the sequence is arranged according to the subscript iii. We numerically demonstrate the information erasure of initial non-equilibrium quantum states through such sequence in a one-dimensional Hubbard model. During this process, the system's entanglement entropy increases monotonically toward a stable value. By incorporating this information erasure mechanism into an isolated system, our numerical simulations reveal that in this completely isolated system, a thermalization process emerges.
The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas system model and numerically demonstrated irreversible growth of entanglement entropy caused by erasure of spread non-equilibrium state information. Here, we mathematically prove that for a typical macroscopic system in a non-equilibrium state ∣ϕ0⟩|ϕ_0\rangle∣ϕ0​⟩, the quantum state ∣ϕ0′⟩=O^(t)∣ϕ0⟩|ϕ'_0\rangle = \hat{O}(t)|ϕ_0\rangle∣ϕ0′​⟩=O^(t)∣ϕ0​⟩ will inevitably evolve toward equilibrium. Our work demonstrates that the second law of thermodynamics, and consequently the ergodic hypothesis in statistical physics, can be understood and proven from a quantum information perspective. From this perspective, the second law can be stated as: In typical macroscopic physical systems, the spreading and erasure of non-equilibrium information is inevitable.
Quantum many-body systems exhibit highly complex interactions that give rise to emergent collective phenomena beyond the behavior of individual particles. One of the most intriguing challenges in modern quantum physics is understanding how isolated quantum systems evolve toward thermal equilibrium despite following fundamentally reversible quantum dynamics. Quantum entanglement has emerged as a central mechanism governing information propagation, thermalization, and the development of statistical equilibrium in isolated many-body systems. Simultaneously, recent advances in quantum information science have enabled researchers to investigate the relationship between entanglement dynamics, information scrambling, and emergent quantum behavior using computational and analytical approaches. This study proposes a Quantum Information Analytics Framework for investigating thermalization processes in isolated many-body quantum systems through the integration of entanglement dynamics, quantum information measures, statistical mechanics, and computational modeling. The proposed framework evaluates system evolution using multiple performance indicators, including entanglement entropy, information propagation, thermal equilibrium, quantum coherence, and computational stability. The findings indicate that quantum entanglement plays a fundamental role in driving thermalization while preserving the underlying unitary evolution of isolated quantum systems. The proposed analytical framework contributes to a deeper understanding of emergent quantum dynamics and provides valuable insights for quantum computing, quantum simulation, condensed matter physics, and next-generation quantum information technologies.
Statistical mechanics relies on the maximization of entropy in a system at thermal equilibrium. However, an isolated quantum many-body system initialized in a pure state remains pure during Schrödinger evolution, and in this sense it has static, zero entropy. We experimentally studied the emergence of statistical mechanics in a quantum state and observed the fundamental role of quantum entanglement in facilitating this emergence. Microscopy of an evolving quantum system indicates that the full quantum state remains pure, whereas thermalization occurs on a local scale. We directly measured entanglement entropy, which assumes the role of the thermal entropy in thermalization. The entanglement creates local entropy that validates the use of statistical physics for local observables. Our measurements are consistent with the eigenstate thermalization hypothesis.
We study dynamics of entanglement in the thermalization process of an isolated quantum many-body system. We propose a simple setup for measuring the propagation speed of entanglement entropy (EE) in numerical simulations and apply it to the integrable/non-integrable spin models in 1D - the transverse Ising (TI) model, the chaotic Ising (CI) model, and the extended chaotic Ising (ECI) model. We find that two distinct time-scales t∗t^\astt∗ and tdifft_{\rm {diff}}tdiff​ arise in the dynamics of EE in the thermalization process: the former represents the time-scale for the saturation of EE and the latter characterizes spreading of EE over the entire system. Evaluating the propagation speed of entanglement from tdifft_{\rm diff}tdiff​, we find that entanglement propagates ballistically with a constant velocity irrespective of the integrability of the model. The propagation speed of entanglement is found to coincide with the maximum group velocity of quasi-particle excitations in the TI model. We also evaluate the propagation speed of entanglement by mutual information and find the characteristic time-scale tMIt_{\mathrm{MI}}tMI​. We show that the propagation speeds of entanglement evaluated by tMIt_{\mathrm{MI}}tMI​ and tdifft_{\rm {diff}}tdiff​ agree well. We discuss the condition for thermalization based on the numerical results and propose that scrambling of the entire system has to take place before saturation of EE for thermalization.
Thermalization in isolated quantum many-body systems can be nonmonotonic, with its process dependent on an initial state. We propose a numerical method to construct a low-entangled initial state that creates a "burst" -- a transient deviation of an observable from its thermal equilibrium value -- at a designated time. We apply this method to demonstrate that a burst of magnetization can be realized for a nonintegrable mixed-field Ising chain on a timescale comparable to the onset of quantum scrambling. Contrary to the typical spreading of information in this regime, the created burst is accompanied by a slow or even negative entanglement growth. Analytically, we show that a burst becomes probabilistically rare after a long time. Our results suggest that a nonequilibrium state is maintained for an appropriately chosen initial state until scrambling becomes dominant. These predictions can be tested with programmable quantum simulators.
A very fundamental problem in quantum statistical mechanics involves whether—and how—an isolated quantum system will reach thermal equilibrium after waiting a long time. In quantum systems that do thermalize, the long-time expectation value of any “reasonable” operator will match its predicted value in the canonical ensemble. The Eigenstate Thermalization Hypothesis (ETH) posits that this thermalization occurs at the level of each individual energy eigenstate; in fact, any single eigenstate in a microcanonical energy window will predict the expectation values of such operators exactly. In the first part of this dissertation, we identify, for a generic model system, precisely which operators satisfy ETH, as well as limits to the information contained in a single eigenstate. Remarkably, our results strongly suggest that a single eigenstate can contain information about energy densities—and therefore temperatures—far away from the energy density of the eigenstate.Additionally, we study the possible breakdown of quantum thermalization in a model of itinerant electrons on a one-dimensional chain, with both spin and charge degrees of freedom. This model exhibits peculiar properties in the entanglement entropy, the apparent scaling of which is modified from a “volume law” to an “area law” after performing a partial, site-wise measurement on the system. These properties and others suggest that this model realizes a new, non-thermal phase of matter, known as a Quantum Disentangled Liquid (QDL). The putative existence of this phase has striking implications for the foundations of quantum statistical mechanics.