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arXiv:2501.00209 · Physical Review A

Unraveling the switching dynamics in a quantum double-well potential

Qile David Su, Rodrigo G. Cortiñas, Jayameenakshi Venkatraman, Shruti Puri

Published Sep 2, 2025• 4 citations
arXivHTMLPDF

Abstract

The spontaneous switching of a quantum particle between the wells of a double-well potential is a phenomenon of general interest to physics and chemistry. It was broadly believed that the switching rate decreases steadily as a function of the size of the energy barrier. This view was challenged by a recent experiment on a driven superconducting Kerr nonlinear oscillator (often called the Kerr-cat qubit or the Kerr parametric oscillator), whose energy barrier can be continuously increased by ramping up the drive. Remarkably, as the drive amplitude increases, the switching rate exhibits a steplike decrease termed the ``staircase.'' The view challenged by the experimental staircase demands a deep review of our understanding of the role of quantum effects in double wells. In this work, we use a Lindbladian model of dissipation to derive a semianalytical formula for the switching rate, resolving a continuous transition between tunneling-dominated dynamics and dissipation-dominated dynamics. These two dynamics are observed respectively in the flat part and the steep part of each step in the staircase. Our formula exposes two distinct dissipative processes that limit tunneling: the dephasing of interwell superpositions freezes tunneling via the quantum Zeno effect, and the decay from one excited state to another limits the time during which tunneling can be attempted. This physical understanding allows us to pinpoint the critical drive amplitude that separates the flat and steep part of each step using an equation involving the rates of the two dissipative processes and the tunnel splitting. In addition, analyzing the transition matrix elements in the formula shows that in the regime of a few ($\ensuremath{\lesssim}10$) states in the well and under moderate to low temperatures, highly excited states are populated predominantly via cascaded and direct thermal heating rather than quantum heating. At very low temperatures, we find that the perturbation induced by the non-Hermitian Hamiltonian part of the Lindbladian model becomes increasingly important and facilitates a form of quantum heating that has not been identified before. We numerically map the activation mechanism as a function of drive amplitude, damping rate, and temperature. Our theory deepens the understanding of switching dynamics between metastable quantum states, highlights the importance of a general interplay between tunneling and dissipation, and identifies a novel quantum regime in activated transitions.

DOI
10.1103/dqv5-bvd4

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The spontaneous switching of a quantum particle between the wells of a double-well potential is a phenomenon of general interest to physics and chemistry. It was broadly believed that the switching rate decreases steadily as a function of the size of the energy barrier. This view was challenged by a recent experiment on a driven superconducting Kerr nonlinear oscillator (often called the Kerr-cat qubit or the Kerr parametric oscillator), whose energy barrier can be continuously increased by ramping up the drive. Remarkably, as the drive amplitude increases, the switching rate exhibits a steplike decrease termed the ``staircase.'' The view challenged by the experimental staircase demands a deep review of our understanding of the role of quantum effects in double wells. In this work, we use a Lindbladian model of dissipation to derive a semianalytical formula for the switching rate, resolving a continuous transition between tunneling-dominated dynamics and dissipation-dominated dynamics. These two dynamics are observed respectively in the flat part and the steep part of each step in the staircase. Our formula exposes two distinct dissipative processes that limit tunneling: the dephasing of interwell superpositions freezes tunneling via the quantum Zeno effect, and the decay from one excited state to another limits the time during which tunneling can be attempted. This physical understanding allows us to pinpoint the critical drive amplitude that separates the flat and steep part of each step using an equation involving the rates of the two dissipative processes and the tunnel splitting. In addition, analyzing the transition matrix elements in the formula shows that in the regime of a few (\ensuremath≲10\ensuremath{\lesssim}10\ensuremath≲10) states in the well and under moderate to low temperatures, highly excited states are populated predominantly via cascaded and direct thermal heating rather than quantum heating. At very low temperatures, we find that the perturbation induced by the non-Hermitian Hamiltonian part of the Lindbladian model becomes increasingly important and facilitates a form of quantum heating that has not been identified before. We numerically map the activation mechanism as a function of drive amplitude, damping rate, and temperature. Our theory deepens the understanding of switching dynamics between metastable quantum states, highlights the importance of a general interplay between tunneling and dissipation, and identifies a novel quantum regime in activated transitions.
Abstract We explore dissipative quantum tunnelling, a phenomenon central to various physical and chemical processes, utilizing a model based on a double-well potential. This paper aims to bridge gaps in understanding the crossover from thermal activation to quantum tunnelling, a domain still shrouded in mystery despite extensive research. By numerically investigating a model derived from Caldeira–Leggett’s work on quantum Brownian motion, examining both Lindblad and stochastic Schrödinger dynamics, we offer new insights into the transition states in the crossover region. Contrary to a common belief that temperature strongly dampens all quantum effects, our findings reveal that under certain conditions temperature instead alters the nature of tunnelling from a deterministic and periodic process to a stochastic yet still very quantum phenomenon. This underscores the profound influence of quantum effects on transition rates and the critical role of temperature in modulating tunnelling behaviours. Additionally, we introduce a new model for quantum Brownian motion that takes Lindblad form and is formulated as a modification of the widely known model found in Breuer and Petruccione. In our approach, we remove the zero-temperature singularity resulting in a better description of low-temperature quantum Brownian motion near a potential minima. Despite these advancements, we recognize persistent challenges in accurately simulating the dynamics at extremely low temperatures for arbitrary potentials, particularly those that cannot be closely approximated locally by a quadratic function.
We analytically investigate the switching rate in a two-photon driven Kerr oscillator with finite detuning and two-photon dissipation. This system exhibits quantum bistability and supports a logical manifold for a bosonic qubit. Using Kramer's theory together with the PPP-representation, we derive an analytical expression for the bit-flip error rate within the potential-barrier approximation. The agreement is demonstrated between analytical calculations and numerical simulations obtained by diagonalization of the Liouvillian superoperator. In the purely dissipative limit, the switching rate increases monotonically with detuning, as the two metastable states approach each other in phase space. However, the exponential contribution to the bit-flip rate exhibits a nontrivial dependence on system parameters, extending beyond the naive scaling with the average photon number. In the presence of large Kerr nonlinearity, the switching rate becomes a nonmonotonic function of the detuning and reaches a minimum at a finite detuning. This effect arises because detuning lowers the activation barrier for weak nonlinearity but increases it for large ones, ensuring a minimum of the switching-rate at nonzero detuning. These results establish key conditions for optimizing the performance of critical cat qubits and are directly relevant for the design of scalable superconducting bosonic quantum architectures.
We study the quantum dynamics of a Bose–Einstein condensate trapped in a double-well potential with a rising interwell barrier. We analytically find the characteristic timescales of the splitting process and compare our results with numerical analyses available in the literature. In the first stage of the dynamics, the relative phase of the two condensates evolves adiabatically. At a critical time t ad , small-amplitude phase fluctuations around the average trajectory increase exponentially fast, signalling the breakdown of adiabaticity. After this stage, it is still not possible to neglect the tunnelling exchange between the two wells. We find highly non-trivial dependences of the dephasing time on t ad and on the ramping time of the interwell barrier.
The stabilizing effect of quantum fluctuations on the escape process and the relaxation dynamics from a quantum metastable state are investigated. Specifically, the quantum dynamics of a multilevel bistable system coupled to a bosonic Ohmic thermal bath in strong dissipation regime is analyzed. The study is performed by a non-perturbative method based on the real-time path integral approach of the Feynman-Vernon influence functional. We consider a strongly asymmetric double well potential with and without a monochromatic external driving, and with an out-of-equilibrium initial condition. In the absence of driving we observe a nonmonotonic behavior of the escape time from the metastable region, as a function both of the system-bath coupling coefficient and the temperature. This indicates a stabilizing effect of the quantum fluctuations. In the presence of driving our findings indicate that, as the coupling coefficient γ increases, the escape time, initially controlled by the external driving, shows resonant peaks and dips, becoming frequency-independent for higher γ values. Moreover, the escape time from the metastable state displays a nonmonotonic behavior as a function of the temperature, the frequency of the driving, and the thermal-bath coupling, which indicates the presence of a quantum noise enhanced stability phenomenon. Finally, we investigate the role of different spectral densities, both in sub-Ohmic and super-Ohmic dissipation regime and for different cutoff frequencies, on the relaxation dynamics from the quantum metastable state. The results obtained indicate that, in the crossover dynamical regime characterized by damped intrawell oscillations and incoherent tunneling, the spectral properties of the thermal bath influence non-trivially the short time behavior and the time scales of the relaxation dynamics from the metastable state.
Motivated by recent experimental progress to readout quantum bits implemented in superconducting circuits via the phenomenon of dynamical bifurcation, transitions between steady orbits in a driven anharmonic oscillator, the Duffing oscillator, are analyzed. In the regime of weak dissipation a consistent diffusion equation in the semiclassical limit is derived to capture the intimate relation between finite tunneling and reflection and bath induced quantum fluctuations. From the corresponding steady-state distribution an analytical expression for the switching probability is obtained. It is shown that a reduction of the transition rate due to finite reflection at the phase-space barrier is overcompensated by an increase due to environmental quantum fluctuations that are specific for diffusion processes over dynamical barriers. The scaling behavior of the rate is discussed and it is revealed that close to the bifurcation threshold the escape dynamics enters an overdamped domain such that the quantum-mechanical energy scale associated with friction even exceeds the thermal energy scale.
For suitable parameters, the classical Duffing oscillator has a known bistability in its stationary states, with low- and high-amplitude branches. As expected from the analogy with a particle in a double-well potential, transitions between these states become possible either at finite temperature, or in the quantum regime due to tunneling. In this analogy, besides local stability, one can also discuss global stability by comparing the two potential minima. For the Duffing oscillator, the stationary states emerge dynamically so that a priori, a potential-minimum criterion for them does not exist. However, global stability is still relevant, and definable as the state containing the majority population for long times, low temperature, and close to the classical limit. Further, the crossover point is the parameter value at which global stability abruptly changes from one state to the other. For the double-well model, the crossover point is defined by potential-minimum degeneracy. Given that this analogy is so effective in other respects, it is thus striking that for the Duffing oscillator, the crossover point turns out to be non-unique. Rather, none of the three aforementioned limits commute with each other, and the limiting behaviour depends on the order in which they are taken. More generally, as both $\hbar\To0$ and $T\To0$, the ratio ℏω0/kBT\hbarω_0/k_\mathrm{B}Tℏω0​/kB​T continues to be a key parameter and can have any nonnegative value. This points to an apparent conceptual difference between equilibrium and nonequilibrium tunneling. We present numerical evidence by studying the pertinent quantum master equation in the photon-number basis. Independent verification and some further understanding are obtained using a semi-analytical approach in the coherent-state representation.