Abstract We report on the experimental measurement of the work statistics of a genuinely open quantum system using a quantum computer. Such measurement has remained elusive thus far due to the inherent difficulty in measuring the total energy change of a system-bath compound (which is the work) in the open quantum system scenario. We overcome this difficulty by applying the interferometric scheme, originally conceived for closed systems, to the open system case and implement it on a superconducting quantum computer, taking advantage of the relatively high levels of noise on current quantum hardware to realize an open quantum system. We demonstrate that the method can be used as a diagnostic tool to probe physical properties of the system-bath compound, such as its temperature and specific transition frequencies in its spectrum. Our experiments corroborate that the interferometric scheme is a promising tool to achieve the long-sought experimental validation of the Jarzynski equality for arbitrary open quantum systems.
Abstract We report on the experimental measurement of the work statistics of a genuinely open quantum system using a quantum computer. Such measurement has remained elusive thus far due to the inherent difficulty in measuring the total energy change of a system-bath compound (which is the work) in the open quantum system scenario. We overcome this difficulty by applying the interferometric scheme, originally conceived for closed systems, to the open system case and implement it on a superconducting quantum computer, taking advantage of the relatively high levels of noise on current quantum hardware to realize an open quantum system. We demonstrate that the method can be used as a diagnostic tool to probe physical properties of the system-bath compound, such as its temperature and specific transition frequencies in its spectrum. Our experiments corroborate that the interferometric scheme is a promising tool to achieve the long-sought experimental validation of the Jarzynski equality for arbitrary open quantum systems.
Work is an important quantity in thermodynamics. In a closed quanutm system, the two-point energy measurements can be applied to measure the work but cannot be utilized in an open quantum system. With the two-point energy measurements, it has been shown that the work fluctuation satisfies the Jarzynski equality. We propose a scheme to measure the work in an open quantum system through the technique of reservoir engineering. Based on this scheme, we show that the work fluctuation in open quantum system may violate the Jarzynski equality. We apply our scheme to a two-level atom coupled to an engineered reservoir and numerically justify the general results, especially demonstrating that the second law of thermodynamics can be violated.
To define the work performed on a driven quantum system in a physically sound way has turned out to be a truly non-trivial task, except in some special cases of limited applicability. This topic has been in a focus of intense research recently in the attempts to generalize the classical fluctuation relations into the quantum regime. Here we propose and demonstrate that a calorimetric measurement gives both a theoretical and experimental tool to test the Jarzynski equality (JE) and other fluctuation relations in a quantum system, and to analyze the distribution of dissipation in them, based on the very principle of conservation of energy. We focus on an experimentally feasible two-level system, a superconducting Cooper pair box subject to Landau-Zener interband transitions. Because of the small heat capacity and weak relaxation to the phonon bath, the calorimetric measurement on the electron gas (resistor) turns out to be a very feasible experimental method.
We propose a method to evaluate general thermodynamic fluctuations in open quantum systems, based on performing a two-point measurement scheme on the system using dynamics-dependent thermodynamic observables. Our approach allows one to obtain exact equalities for fluctuations of path-dependent thermodynamic quantities such as work and heat, and to isolate correction factors to Jarzynski's equality, requiring only access to the system degrees of freedom. This framework is flexible and can be applied to the limiting case of closed systems, recovering previous, yet seemingly contradictory, results from the literature. Moreover, the formalism admits a straightforward extension to strongly coupled open quantum systems. We investigate the effect of specific dynamical classes on the fluctuation relations, and show that the pure decoherence case is particularly special, as it deterministically does not contain any heat contribution and thus constitutes a class of open system dynamics for which the Jarzynski equality for work fluctuations is identically true at any coupling strength. Finally, we look explicitly at the shape and size of the correction factors to Jarzynski's equality for a qubit undergoing phase covariant dynamics, both in the weakly-coupled regime and in the deep non-Markovian regime.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.
The quantum Jarzynski equality and the Crooks relation are fundamental laws connecting equilibrium processes with nonequilibrium fluctuations.They are promising tools to benchmark quantum devices and measure free energy differences.While they are well established theoretically and also experimental realizations for few-body systems already exist, their experimental validity in the quantum many-body regime has not been observed so far.Here, we present results for nonequilibrium protocols in systems with up to 16 interacting degrees of freedom obtained on trapped ion and superconducting qubit quantum computers, which test the quantum Jarzynski equality and the Crooks relation in the many-body regime.To achieve this, we overcome present-day limitations in the preparation of thermal ensembles and in the measurement of work distributions on noisy intermediate-scale quantum devices.We discuss the accuracy to which the Jarzynski equality holds on different quantum computing platforms subject to platformspecific errors.The analysis reveals the validity of Jarzynski's equality in a regime with energy dissipation, compensated for by a fast unitary drive.This provides new insights for analyzing errors in many-body quantum simulators.
Inspired by the idea that quantum computers can be useful in advancing basic science, we use a quantum processor to experimentally validate a number of theoretical results in non-equilibrium quantum thermodynamics, that were not (or were very little) corroborated so far.In order to do so, we first put forward a novel method to implement the so called two-point measurement scheme, which is at the basis of the study of nonequilibrium energetic exchanges in quantum systems.Like previously established methods, our method uses an ancillary system, but at variance with them, it provides direct access to the energy exchange statistics, and is, accordingly more effective, at least when applied to small quantum systems.Using a quantum computer as a remotely programmable experimental platform, we first validate our ancilla-assisted two-point measurement scheme, and then apply it to (i) experimentally verify that fluctuation theorems are robust against projective measurements, a theoretical prediction, which was not validated so far; (ii) experimentally verify the so-called heat-engine fluctuation relation, by implementing a SWAP quantum heat engine; (iii) experimentally verify that the heat-engine fluctuation relation holds for measurement-fueled quantum heat engines, by implementing the design at the basis of the so-called quantum-measurement-cooling concept.For both engines, we report the measured average heat and work exchanged and single out their operation mode.Our experiments constitute an experimental basis for the understanding of the nonequilibrium energetics of quantum computation and for the implementation of energy-management devices on quantum processors.