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arXiv:2412.12489 · Journal of Physics A Mathematical and Theoretical

A quantum entropy production operator

Ge Bai, Francesco Buscemi, Valerio Scarani

Published Jul 6, 2026• 1 citation
arXivHTMLPDF

Abstract

Abstract We introduce a fully quantum notion of entropy production based on the non-commutative extension of the classical log-ratio between forward and reverse processes. Given a pair of quantum objects associated with the forward and reverse descriptions, we define a Hermitian entropy-production operator whose expectation value is non-negative and equal to the Belavkin–Staszewski relative entropy. The operator satisfies exact integral and detailed fluctuation theorems without requiring commutativity. We then specialize this construction to the case in which the forward process is described by a single quantum channel and the reverse process is defined inferentially, through Bayesian retrodiction relative to a prior state, with the Petz transpose map as the Bayesian inverse. In this setting, the relevant quantities can be evaluated explicitly, leading to a number of natural structural and physical properties. The framework recovers the classical formula in the commutative limit, yields explicit expressions for the average entropy production, and clarifies where the fully quantum case departs from standard thermodynamic expectations.

DOI
10.1088/1751-8121/ae86cb

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Abstract We introduce a fully quantum notion of entropy production based on the non-commutative extension of the classical log-ratio between forward and reverse processes. Given a pair of quantum objects associated with the forward and reverse descriptions, we define a Hermitian entropy-production operator whose expectation value is non-negative and equal to the Belavkin–Staszewski relative entropy. The operator satisfies exact integral and detailed fluctuation theorems without requiring commutativity. We then specialize this construction to the case in which the forward process is described by a single quantum channel and the reverse process is defined inferentially, through Bayesian retrodiction relative to a prior state, with the Petz transpose map as the Bayesian inverse. In this setting, the relevant quantities can be evaluated explicitly, leading to a number of natural structural and physical properties. The framework recovers the classical formula in the commutative limit, yields explicit expressions for the average entropy production, and clarifies where the fully quantum case departs from standard thermodynamic expectations.
We establish the general framework of quantum fluctuation theorems by finding the symmetry between the forward and backward transitions of any given quantum channel. The Petz recovery map is adopted as the reverse quantum channel, and the notion of entropy production in thermodynamics is extended to the quantum regime. Our result shows that the fluctuation theorems, which are normally considered for thermodynamic processes, can be a powerful tool to study the detailed statistics of quantum systems as well as the effect of coherence transfer in an arbitrary non-equilibrium quantum process. We introduce a complex-valued entropy production to fully understand the relation between the forward and backward processes through the quantum channel. We find the physical meaning of the imaginary part of entropy production to witness the broken symmetry of the quantum channel. We also show that the imaginary part plays a crucial role in deriving the second law from the quantum fluctuation theorem. The dissipation and fluctuation of various quantum resources including quantum free energy, asymmetry and entanglement can be coherently understood in our unified framework. Our fluctuation theorem can be applied to a wide range of physical systems and dynamics to query the reversibility of a quantum state for the given quantum processing channel involving coherence and entanglement.
Entropy production and the detailed fluctuation theorem are of fundamental importance for thermodynamic processes. In this paper we study the multiple entropy production for multitime quantum processes in a unified framework. For closed quantum systems and Markovian open quantum systems, the given entropy productions all satisfy the detailed fluctuation relation. This also shows that the entropy production rate under these processes is non-negative. For non-Markovian open quantum systems, the memory effect can lead to a negative-entropy production rate. Thus, in general, the entropy production of the marginal distribution does not satisfy the detailed fluctuation theorem relation. Our framework can be applied to a wide range of physical systems and dynamics. It provides a systematic tool for studying entropy production and its rate under arbitrary quantum processes.
An invariant state of a quantum Markov semigroup is an equilibrium state if it satisfies a quantum detailed balance condition. In this paper, we introduce a notion of entropy production for faithful normal invariant states of a quantum Markov semigroup on B(h) as a numerical index measuring "how much far" they are from equilibrium. The entropy production is defined as the derivative of the relative entropy of the one-step forward and backward evolution in analogy with the classical probabilistic concept. We prove an explicit trace formula expressing the entropy production in terms of the completely positive part of the generator of a norm continuous quantum Markov semigroup showing that it turns out to be zero if and only if a standard quantum detailed balance condition holds.
We propose an alternative notion of time reversal in open quantum systems as represented by linear quantum operations, and a related generalization of classical entropy production in the environment. This functional is the ratio of the probability to observe a transition between two states under the forward and the time reversed dynamics, and leads, as in the classical case, to fluctuation relations as tautological identities. As in classical dynamics in contact with a heat bath, time reversal is not unique, and we discuss several possibilities. For any bistochastic map its dual map preserves the trace and describes a legitimate dynamics reversed in time, in that case the entropy production in the environment vanishes. For a generic stochastic map we construct a simple quantum operation which can be interpreted as a time reversal. For instance, the decaying channel, which sends the excited state into the ground state with a certain probability, can be reversed into the channel transforming the ground state into the excited state with the same probability.
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We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and Markovian regime, holds for both local and global master equations, corroborating the thermodynamic consistency of local quantum master equations. The theorem is genuinely quantum, as it can be expressed in terms of conservation of a Hermitian operator, describing the dynamics of the system state operator and of the entropy change in the baths. The integral fluctuation theorem follows from the properties of such an operator. Furthermore, it is also valid when the system is described by a time-dependent Hamiltonian. As such, the quantum Jarzynski equality is a particular case of the general result presented here. Moreover, our result can be extended to nonthermal baths, as long as microreversibility is preserved. We present some numerical examples to showcase the exact results previously obtained. We finally generalize the fluctuation theorem to the case where the interaction between the system and the bath is explicitly taken into account. We show that the fluctuation theorem amounts to a relation between time-reversed dynamics of the global density matrix and a two-time correlation function along the forward dynamics involving the baths' entropy alone.