Catalysis refers to the possibility of enabling otherwise inaccessible quantum state transitions by supplying an auxiliary system, provided that the auxiliary is returned to its initial state at the end of the protocol. We show that previous studies on catalysis are largely impractical, because even small errors in the system's initial state can irreversibly degrade the catalyst. To overcome this limitation, we introduce "robust catalytic transformations" and explore the fundamental extent of their capabilities. We demonstrate that robust catalysis is closely tied to the property of resource broadcasting. In particular, in completely resource nongenerating theories, robust catalysis is possible if and only if resource broadcasting is possible. We develop a no-go theorem under a set of general axioms, demonstrating that robust catalysis is unattainable for a broad class of quantum resource theories. However, surprisingly, we also identify thermodynamical scenarios where maximal robust catalytic advantage can be achieved. Our approach clarifies the practical prospects of catalytic advantage for a wide range of quantum resources, including entanglement, coherence, thermodynamics, nonstabilizerness, and imaginarity.
Catalysis refers to the possibility of enabling otherwise inaccessible quantum state transitions by supplying an auxiliary system, provided that the auxiliary is returned to its initial state at the end of the protocol. We show that previous studies on catalysis are largely impractical, because even small errors in the system's initial state can irreversibly degrade the catalyst. To overcome this limitation, we introduce "robust catalytic transformations" and explore the fundamental extent of their capabilities. We demonstrate that robust catalysis is closely tied to the property of resource broadcasting. In particular, in completely resource nongenerating theories, robust catalysis is possible if and only if resource broadcasting is possible. We develop a no-go theorem under a set of general axioms, demonstrating that robust catalysis is unattainable for a broad class of quantum resource theories. However, surprisingly, we also identify thermodynamical scenarios where maximal robust catalytic advantage can be achieved. Our approach clarifies the practical prospects of catalytic advantage for a wide range of quantum resources, including entanglement, coherence, thermodynamics, nonstabilizerness, and imaginarity.
Quantum catalysis, the ability to enable previously impossible transformations by using auxiliary systems without degrading them, has emerged as a powerful tool in various resource theories. Although catalytically enabled state transformations have been formally characterized by the monotonic behavior of entropic quantifiers (e.g., the von Neumann entropy or nonequilibrium free energy), such characterizations often rely on unphysical assumptions, namely, the ability of using catalysts of infinitely large dimension. This approach offers very limited insights into the practical significance of using catalysis for quantum information processing. Here, we address this problem across a broad class of quantum resource theories. Leveraging quantum information tools beyond the asymptotic regime, we establish sufficient conditions for the existence of catalytic transformations with finite-size catalysts. We further unveil connections between finite-size catalysis and multicopy transformations. Notably, we discover a phenomenon of catalytic resonance: by carefully tailoring the catalysts's state, one can drastically reduce the required dimension of the catalyst, thus enabling efficient catalytic transformations with minimal resources. Finally, we illustrate our findings with examples from the resource theories of entanglement and thermodynamics, as well in the context of catalytic unitary transformations.
Understanding the fundamental limits of state convertibility is crucial for establishing the boundaries of quantum information processing and thermodynamic efficiency. While auxiliary systems, catalysts, can facilitate otherwise impossible transformations, standard catalysis rigidly requires the auxiliary system to return to its exact initial state. In this work, we investigate the power of flexible catalysis, where the catalyst evolves through a cycle of states, restoring its initial configuration only after a finite number of steps. Focusing on the regime of fixed, finite dimensions, we analyze the capabilities of flexible catalysis within the resource theories of entanglement and quantum thermodynamics. In the context of entanglement, we derive conditions limiting flexible catalysts, yet show that flexible catalysis can be strictly more powerful than same-dimensional standard catalysis: it enables deterministic transformations achievable by no standard catalyst of the same dimension, and it strictly increases the success probability of stochastic local operations and classical communication. A similar deterministic advantage arises in quantum thermodynamics, where flexible catalysis enables state transformations that are impossible with any standard catalyst of fixed dimension and Hamiltonian but become achievable via flexible catalysis.
Entanglement is a key quantum resource in various quantum protocols, with a rich set of laws governing its manipulation. In this context, catalysis refers to the possibility of an auxiliary state that enables a previously forbidden manipulation, while being completely returned at the end. While the catalytic setting has been thoroughly examined in the single-copy regime, much less is known in the asymptotically many copy regime. In this work, we focus on the entanglement cost of preparing asymptotically many copies of a given state exactly. We show that catalysis can significantly lower the exact entanglement cost by constructing an explicit catalytic protocol. Additionally, these findings generalize readily to other resource theories, showing a general catalytic advantage in the resource dilution task.
Catalysts are substances that assist transformation of other resourceful objects without being consumed in the process. However, the fact that their ``catalytic power'' is limited and can be depleted is often overlooked, especially in the recently developing theories on catalysis of quantum randomness utilizing building correlation with catalyst. In this work, we establish a resource theory of one-shot catalytic randomness in which uncorrelatedness is consumed in catalysis of randomness. We do so by completely characterizing bipartite unitary operators that can be used to implement catalysis of randomness using partial transpose. By doing so, we find that every catalytic channel is factorizable, and therefore there exists a unital channel that is not catalytic. We define a family of catalytic entropies that quantifies catalytically extractable R\'enyi entropies from a quantum state and show how much the degeneracy of a quantum state can boost the catalytic entropy beyond its ordinary entropy. Based on this, we demonstrate that a randomness source can be actually exhausted after a certain amount of randomness is extracted. We apply this theory to systems under superselection rules that forbids superposition of certain quantum states and find that nonmaximally mixed states can yield the maximal catalytic entropy. We discuss implications of this theory to various topics, including catalytic randomness absorption, the no-secret theorem, and the possibility of multiparty infinite catalysis.
Catalysis refers to the possibility of performing an otherwise impossible local state transformation by sharing an additional state, i.e. a catalyst, which is returned at the end of the protocol. There is a stronger version, known as supercatalysis, in which the borrowed catalyst is returned in an enhanced form, i.e. more entangled. However, this phenomenon has remained little explored. In this work we introduce the supercatalytic entanglement gain as a figure of merit taking values in [0,1] that quantifies the performance of the protocol (with 0 corresponding to the standard case of catalysis and 1 representing the maximal possible gain) and we study in which cases it can be greater than zero and which strategies can maximize it. While it turns out that every catalytic transformation can be implemented in a supercatalytic fashion with entanglement gain equal to 1 if the state that is borrowed is chosen appropriately, other choices can make the gain strictly less than 1 and even 0. In fact, we prove that a large class of catalytic transformations are not fully supercatalyzable, i.e. there is at least one choice of catalyst for which the entanglement gain vanishes. On the other hand, the construction that shows that supercatalysis is always possible with maximal gain uses artificially highly entangled catalysts. For this reason, we also study minimal supercatalysis, where the entanglement content of the borrowed state is constrained in a precise and natural way. While we consider a scenario where we prove it is impossible to have entanglement gain equal to 1 in this case, we show that there exist minimal supercatalytic transformations with gain as close to 1 as desired. We also explore several examples and observe that, although choosing a catalyst with the least possible entanglement is often an optimal strategy for minimal supercatalysis, this is not necessarily always the case.
Determining whether a given state can be transformed into a target state using free operations is one of the fundamental questions in the study of resource theories. Free operations in resource theories can be enhanced by allowing for a catalyst system that assists the transformation and is returned unchanged, but potentially correlated, with the target state. While this has been an active area of recent research, very little is known about the necessary properties of such catalysts. Here, we prove fundamental limits applicable to a large class of correlated catalytic transformations by showing that a small residual correlation between a catalyst and target state implies that the catalyst needs to be highly resourceful. In fact, the resource required diverge in the limit of vanishing residual correlation. In addition, we establish that in imperfect catalysis a small error generally implies a highly resourceful embezzling catalyst. We develop our results in a general resource theory framework and discuss its implications for the resource theory of athermality, the resource theory of coherence, and entanglement theory.