We use the eigenstate thermalization hypothesis to derive a quantum master equation for a system that is weakly coupled to a chaotic finite-sized bath prepared in a pure state. We show that the emergence of Markovianity is controlled by the spectral function of the ETH and that local detailed balance emerges in the Markovian regime for a broad class of pure bath states. We numerically verify this result by comparing the master equation to dynamics computed using exact diagonalization of a chaotic Hamiltonian. We also compare the master equation to exact dynamics for an integrable bath and find that at finite size they strongly disagree. Our work puts forward eigenstate thermalization as a foundation for open quantum systems theory, thus extending it beyond ensemble bath preparations to chaotic many-body environments in generic pure states.
We use the eigenstate thermalization hypothesis to derive a quantum master equation for a system that is weakly coupled to a chaotic finite-sized bath prepared in a pure state. We show that the emergence of Markovianity is controlled by the spectral function of the ETH and that local detailed balance emerges in the Markovian regime for a broad class of pure bath states. We numerically verify this result by comparing the master equation to dynamics computed using exact diagonalization of a chaotic Hamiltonian. We also compare the master equation to exact dynamics for an integrable bath and find that at finite size they strongly disagree. Our work puts forward eigenstate thermalization as a foundation for open quantum systems theory, thus extending it beyond ensemble bath preparations to chaotic many-body environments in generic pure states.
In this paper, a method is developed for the study of a generic small central quantum system, which is locally coupled to an environment as a many-body quantum chaotic system that satisfies the eigenstate thermalization hypothesis (ETH) ansatz. The approach is based on properties of environmental branches of the total system's state, the overlaps of which give the reduced density matrix (RDM) of the central system. To study evolution of the RDM within a finite time period, the period is divided into a series of short intervals, within each of which the RDM is computed by making use of a formal solution to the time evolution of the environmental branches. The expressions thus obtained are simplified by the ETH ansatz and, further, by decay of phase correlations among the environmental branches, the latter of which also originates from chaotic dynamics of the environment. This gives a generic method of deriving master equation. And, as an application, a master equation is derived in a simplest nontrivial case, which predicts a decoherence rate in agreement with that predicted by the random-matrix theory. Furthermore, the Born approximation, which is employed in the ordinary approach to master equation, can be justified within the proposed framework; and a Markovian feature is shown for the RDM's evolution in an effective sense.
The eigenstate thermalization hypothesis (ETH) is a successful theory that provides sufficient criteria for ergodicity in quantum many-body systems. Most studies were carried out for Hamiltonians relevant for ultracold quantum gases and single-component systems of spins, fermions, or bosons. The paradigmatic example for thermalization in solid-state physics are phonons serving as a bath for electrons. This situation is often viewed from an open-quantum-system perspective. Here, we ask whether a minimal microscopic model for electron-phonon coupling is quantum chaotic and whether it obeys ETH, if viewed as a closed quantum system. Using exact diagonalization, we address this question in the framework of the Holstein polaron model. Even though the model describes only a single itinerant electron, whose coupling to dispersionless phonons is the only integrability-breaking term, we find that the spectral statistics and the structure of Hamiltonian eigenstates exhibit essential properties of the corresponding random-matrix ensemble. Moreover, we verify the ETH ansatz both for diagonal and off-diagonal matrix elements of typical phonon and electron observables, and show that the ratio of their variances equals the value predicted from random-matrix theory.
The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.
The Eigenstate Thermalization Hypothesis (ETH) has played a major role in understanding thermodynamic phenomena in closed quantum systems. However, its connection to the timescale of thermalization for open system dynamics has remained elusive. This paper establishes a rigorous link between ETH and fast thermalization to the global Gibbs state. Specifically, we demonstrate fast thermalization for a system coupled weakly to a bath of quasi-free Fermions that we refresh periodically. To describe the joint evolution, we derive a finite-time version of Davies' generator with explicit error bounds and resource estimates. Our approach exploits a critical feature of ETH: operators in the energy basis can be modeled by independent random matrices in a near-diagonal band. This gives quantum expanders at nearby eigenstates of the Hamiltonian and reduces the problem to a one-dimensional classical random walk on the energy eigenstates. Our results explain finite-time thermalization in chaotic open quantum systems.
The last decade has witnessed remarkable progress in our understanding of thermalization in isolated quantum systems. Combining the eigenstate thermalization hypothesis with quantum measurement theory, we extend the framework of quantum thermalization to open many-body systems. A generic many-body system subject to continuous observation is shown to thermalize at a single trajectory level. We show that the nonunitary nature of quantum measurement causes several unique thermalization mechanisms that are unseen in isolated systems. We present numerical evidence for our findings by applying our theory to specific models that can be experimentally realized in atom-cavity systems and with quantum gas microscopy. Our theory provides a general method to determine an effective temperature of quantum many-body systems subject to the Lindblad master equation and thus should be applicable to noisy dynamics or dissipative systems coupled to nonthermal Markovian environments as well as continuously monitored systems. Our work provides yet another insight into why thermodynamics emerges so universally.
Despite the unitary evolution of closed quantum systems, long-time expectation of local observables are well described by thermal ensembles, providing the foundation of quantum statistical mechanics. A promising route to understanding this quantum thermalization is the eigenstate thermalization hypothesis (ETH), which posits that individual energy eigenstates already appear locally thermal. Subsequent studies have extended this concept to the full ETH, which captures higher-order correlations among matrix elements through nontrivial relations. In this work, we perform a detailed exact-diagonalization study of finite-size corrections to these relations in the canonical ensemble. We distinguish two distinct sources of corrections: those arising from energy fluctuations, which decay polynomially with system size, and those originating from fluctuations within each energy window, which decay exponentially with system size. In particular, our analysis resolves the puzzle that, for certain observables, finite-size corrections exhibit anomalous growth with increasing system size even in chaotic systems. Our results provide a systematic and practical methodology for validating the full ETH in quantum many-body systems.