The Eigenstate Thermalization Hypothesis (ETH) has played a major role in understanding thermodynamic phenomena in closed quantum systems. However, its connection to the timescale of thermalization for open system dynamics has remained elusive. This paper establishes a rigorous link between ETH and fast thermalization to the global Gibbs state. Specifically, we demonstrate fast thermalization for a system coupled weakly to a bath of quasi-free Fermions that we refresh periodically. To describe the joint evolution, we derive a finite-time version of Davies' generator with explicit error bounds and resource estimates. Our approach exploits a critical feature of ETH: operators in the energy basis can be modeled by independent random matrices in a near-diagonal band. This gives quantum expanders at nearby eigenstates of the Hamiltonian and reduces the problem to a one-dimensional classical random walk on the energy eigenstates. Our results explain finite-time thermalization in chaotic open quantum systems.
The Eigenstate Thermalization Hypothesis (ETH) has played a major role in understanding thermodynamic phenomena in closed quantum systems. However, its connection to the timescale of thermalization for open system dynamics has remained elusive. This paper establishes a rigorous link between ETH and fast thermalization to the global Gibbs state. Specifically, we demonstrate fast thermalization for a system coupled weakly to a bath of quasi-free Fermions that we refresh periodically. To describe the joint evolution, we derive a finite-time version of Davies' generator with explicit error bounds and resource estimates. Our approach exploits a critical feature of ETH: operators in the energy basis can be modeled by independent random matrices in a near-diagonal band. This gives quantum expanders at nearby eigenstates of the Hamiltonian and reduces the problem to a one-dimensional classical random walk on the energy eigenstates. Our results explain finite-time thermalization in chaotic open quantum systems.
Quantum thermalization is well understood via the eigenstate thermalization hypothesis (ETH). The general form of ETH, describing all the relevant correlations of matrix elements, may be derived on the basis of a "typicality" argument of invariance with respect to local rotations involving nearby energy levels. In this Letter, we uncover the close relation between this perspective on ETH and free probability theory, as applied to a thermal ensemble or an energy shell. This mathematical framework allows one to reduce in a straightforward way higher-order correlation functions to a decomposition given by minimal blocks, identified as free cumulants, for which we give an explicit formula. This perspective naturally incorporates the consistency property that local functions of ETH operators also satisfy ETH. The present results uncover a direct connection between the eigenstate thermalization hypothesis and the structure of free probability, widening considerably the latter's scope and highlighting its relevance to quantum thermalization.
This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, the fluctuation–dissipation relation, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. In some cases, it is possible to extend their regimes of applicability beyond the standard thermal equilibrium domain. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We present results from numerical experiments and analytical studies of quantum quenches at integrability. We introduce the concept of the generalized Gibbs ensemble and discuss its connection with ideas of prethermalization in weakly interacting systems.
The eigenstate thermalization hypothesis (ETH) is foundational to modern discussions of thermalization in closed quantum systems. In this work, we expand on traditional explanations for the prevalence of ETH by emphasizing the role of operator locality. We introduce an operator-specific perturbation problem that can be thought of as a means of understanding the onset or breakdown of ETH for specific classes of operators in a given system. We derive explicit functional forms for the off-diagonal variances of operator matrix elements for typical local operators under various `scrambling ansatzes', expressed in terms of system parameters and parameters of the corresponding perturbation problem. We provide simple tests and illustrations of these ideas in chaotic spin chain systems.
The Eigenstate Thermalization Hypothesis (ETH) explains how isolated quantum many-body systems thermalize by proposing that each energy eigenstate is already thermal. The hypothesis is believed to be essential to the understanding of quantum chaos and implies various important thermodynamic relations. While by now there are many numerical validations of the ETH, only few analytical arguments supporting the ETH have been found (M. Rigol et al., Nature 452, 2008). One of them is based on a semiclassical limit (M. Srednicki, Phys. Rev. E 50, 1994). Another important reasoning was given by Deutsch, who showed how a small interaction, which is modeled by a random matrix, leads to ETH (J.M. Deutsch, Phys. Rev. A 43, 1991). This thesis aims to find justification for the assumptions made by Deutsch from a microscopic point of view. The idea is to analyze whether a generic quantum system can be brought to a form that satisfies Deutsch's ansatz. The method is to use flow equations to define unitary transformations to map the initial Hamiltonian to an effective one, which can be compared to a random matrix. The test system is a one-dimensional hardcore boson model, which is set up using exact diagonalization and numerous symmetries. We analyze the statistical properties of the numerically obtained Hamiltonian matrices and test for normality and compare them to a random transformation. In a second step we verify that the continuous unitary transformations do not destroy the structure of typical few-body observables by studying the scaling of the inverse participation ratio. The obtained results support our hypothesis that it is possible to extend Deutsch's argument to generic microscopic many-body Hamiltonians.
Proving thermalization from the unitary evolution of closed quantum systems is one of the oldest questions that is still only partially resolved. Efforts led to various versions of the eigenstate thermalization hypothesis (ETH), which implies thermalization under certain conditions. Whether the ETH holds in specific systems is however difficult to verify from the microscopic description of the system. In this work, we focus on thermalization under local Hamiltonians of low-entanglement initial states, which are operationally accessible in many natural physical settings, including schemes for testing thermalization in experiments and quantum simulators. We prove thermalization of these states under precise conditions that have operational significance. More specifically, motivated by arguments of unavoidable finite resolution, we define a random energy smoothing on local Hamiltonians that leads to local thermalization when the initial state has low entanglement. Finally we show that this transformation affects neither the Gibbs state locally nor, under generic smoothness conditions on the spectrum, the short-time dynamics.
The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.