The nitrogen-vacancy (NV) center in diamond is a solid-state spin defect that has been widely adopted for quantum sensing and quantum information processing applications. Typically, experiments are performed either with a single isolated NV center or with an unresolved ensemble of many NV centers, resulting in a trade-off between measurement speed and spatial resolution or control over individual defects. In this work, we introduce an experimental platform that bypasses this trade-off by addressing multiple optically resolved NV centers in parallel. We perform charge- and spin-state manipulations selectively on multiple NV centers from within a larger set, and we manipulate and measure the electronic spin states of over 100 NV centers in parallel. We show that the high signal-to-noise ratio of the measurements enables the detection of shot-to-shot pairwise correlations between the spin states of 108 NV centers, corresponding to the simultaneous measurement of 5778 unique correlation coefficients. We discuss how our platform can be scaled to parallel experiments with thousands of individually resolved NV centers. These results enable parallelized high-throughput sensing experiments that retain the spatial resolution of single defects and will, thereby, help to unlock advances in applications such as single-molecule NMR and characterization of integrated circuits. In addition, our approach to multiplexing provides a natural platform for the application of recently developed correlated sensing techniques.
The nitrogen-vacancy (NV) center in diamond is a solid-state spin defect that has been widely adopted for quantum sensing and quantum information processing applications. Typically, experiments are performed either with a single isolated NV center or with an unresolved ensemble of many NV centers, resulting in a trade-off between measurement speed and spatial resolution or control over individual defects. In this work, we introduce an experimental platform that bypasses this trade-off by addressing multiple optically resolved NV centers in parallel. We perform charge- and spin-state manipulations selectively on multiple NV centers from within a larger set, and we manipulate and measure the electronic spin states of over 100 NV centers in parallel. We show that the high signal-to-noise ratio of the measurements enables the detection of shot-to-shot pairwise correlations between the spin states of 108 NV centers, corresponding to the simultaneous measurement of 5778 unique correlation coefficients. We discuss how our platform can be scaled to parallel experiments with thousands of individually resolved NV centers. These results enable parallelized high-throughput sensing experiments that retain the spatial resolution of single defects and will, thereby, help to unlock advances in applications such as single-molecule NMR and characterization of integrated circuits. In addition, our approach to multiplexing provides a natural platform for the application of recently developed correlated sensing techniques.
Single nitrogen vacancy (NV) centers in diamond have been used extensively for high-sensitivity nanoscale sensing, but conventional approaches use confocal microscopy to measure individual centers sequentially, limiting throughput and access to nonlocal physical properties, where simultaneous, high-fidelity measurement of multiple centers is required. Here, we design and implement a multiplexed NV sensing platform that allows us to read out many single NV centers simultaneously using a low-noise camera. Using this platform, we coherently manipulate and read out the spin states of hundreds of individual NV centers in parallel, achieving comparable magnetic field sensitivity to confocal measurements. We also implement a parallelized version of spin-to-charge-conversion readout for low NV center spin state readout noise and use it to demonstrate multiplexed covariance magnetometry, in which we measure ten two-point magnetic field correlators from five NV centers simultaneously. From these measurements, we demonstrate the quantitative reconstruction of spatially varying magnetic correlations arising from a current-carrying wire. The number of correlators we can measure is limited only by the available laser power, opening the door to massively multiplexed covariance magnetometry. In contrast to scanning probes for imaging spatially varying magnetic fields, our approach measures the temporal dynamics of the magnetic field at many precisely defined positions simultaneously, from which the local noise spectrum and nonlocal properties such as correlation functions can be computed. This high-fidelity readout platform will find immediate applications in studying condensed matter phenomena that are characterized by the noise spectrum or correlation functions, including quantum phase transitions, dynamics far from equilibrium, magnetic order, and correlated electron phenomena.
Nitrogen vacancy (NV) centers in diamond are atom-scale defects that can be used to sense magnetic fields with high sensitivity and spatial resolution. Typically, the magnetic field is measured by averaging sequential measurements of single NV centers, or by spatial averaging over ensembles of many NV centers, which provides mean values that contain no nonlocal information about the relationship between two points separated in space or time. Here, we propose and implement a sensing modality whereby two or more NV centers are measured simultaneously, and we extract temporal and spatial correlations in their signals that would otherwise be inaccessible. We demonstrate measurements of correlated applied noise using spin-to-charge readout of two NV centers and implement a spectral reconstruction protocol for disentangling local and nonlocal noise sources.
Nitrogen vacancy (NV) centers in diamond are widely deployed as local magnetic sensors, using coherent, single qubit control to measure both time-averaged fields and noise with nanoscale spatial resolution. Moving beyond single qubits to multi-qubit control enables new sensing modalities such as measuring nonlocal spatiotemporal correlators, or using entangled states to improve measurement sensitivity. Here, we describe protocols to use optically unresolved NV center pairs and nuclear spins as multi-qubit sensors for measuring correlated noise, enabling covariance magnetometry at nanometer length scales. For NV centers that are optically unresolved but have spectrally resolved spin transitions, we implement a phase-cycling protocol that disambiguates magnetic correlations from variance fluctuations by alternating the relative spin orientations of the two NV centers. For NV centers that are both optically and spectrally unresolved, we leverage the presence of a third qubit, a 13C nucleus that is strongly coupled to one of the NV centers, to effect coherent single-NV spin flips and enable a similar phase-cycling protocol. For length scales around 10 nm, we create maximally entangled Bell states through dipole-dipole coupling between two NV centers, and use these entangled states to directly read out the magnetic field correlation, rather than reconstructing it from independent measurements of unentangled NV centers. Importantly, this changes the scaling of sensitivity with readout noise from quadratic to linear. For conventional off-resonant readout of the NV center spin state (for which the readout noise is roughly 30 times the quantum projection limit), this results in a dramatic sensitivity improvement. Finally, we demonstrate methods for the detection of high spatial- and temporal-resolution correlators with pairs of strongly interacting NV centers.
This work investigates the applicability of the nitrogen-vacancy (NV) defect center in diamond for quantum computation and metrology purposes. The NV center is a molecule like defect in the diamond lattice which is optically active and possesses an electron spin in its ground state. The spin can be used as a quantum bit and as a field sensor. The NV center has three major properties enabling individual control of single defects. Its optical properties depend on the spin state, the spin can be polarized optically and the spin state has an exceptionally long lifetime. Single NV centers can be controlled by optical and microwave radiation. Generally, the research on individually controllable quantum systems is not only motivated by quantum computation and communication. With the ongoing miniaturization nowadays electronic and electro-optic devices will soon reach the limit of single quantum building blocks. While in these applications the full complexity of single quantum systems might not be needed, small sensors based on single atoms or molecules might very well take advantage of the susceptibility of quantum coherences to environmental conditions. Major challenges for all approaches towards single quantum system control are the individual addressing, the measurement of the quantum state and the protection of quantum coherence from environmental noise. Today, there is a variety of systems (including the NV center) that allow control on the single quantum level. These are for example single photons, single ions and atoms in traps, single spins in semiconductors or single molecules in solid state systems. Rather mesoscopic examples are superconducting devices, nanomechanical oscillators or surface plasmon polaritons. Regarding the NV center it has been shown that the magnetic moment of its electron spin allows individual sensing and coupling to other surrounding electron and nuclear spins. Especially single nuclear spins were shown to be exceptional quantum memories. In this work small quantum registers of up to 5 spins have been used to test major requirements for a feasible quantum processor. Therefore, mainly artificially created high purity diamond samples with controlled spin and impurity concentration were used. The NV centers were either grown in or created via ion implantation techniques in a controlled fashion. As a first requirement for quantum computation entanglement among up to three spins has been generated and was verified by quantum state tomography. This proves the access of the full Hilbert space. Especially, entanglement among nuclear spins was very long-living. In further experiments this processor was used for first quantum algorithms like super-dense coding and the Deutsch algorithm. In addition, this work demonstrates new methods to initialize nuclear spin qubits into a desired quantum state. This is particularly important as improper initialization inhibits quantum computation. One of these methods is related to dynamic nuclear spin polarization and the other to measurement based state preparation. Nuclear spins in the diamond lattice originate mainly from the C-13 isotope. By artificially altering its content the influence on the NV center spin was investigated. The coherence times of the NV center were increasing inversely with the nuclear spin density. Even increasing nuclear spin density to offer more nuclear spin qubits to an operational quantum register was possible. As an alternative route of scaling up the quantum register pairs of closely spaced NV centers were investigated. For the first time two qubit gates among two NV centers mediated by magnetic dipolar coupling have been realized. Furthermore the sensing ability was demonstrated by measuring the relative distance of the two centers (10 nm) with sub-nm precision. Eventually, this work contains new insight into the electronically excited state of the NV center which allowed a more advanced control of the electron and nuclear spins. A comparably high magnetic field was used to decouple electron and nuclear spins. Finally, this allowed quantum nondemolition measurements on single nuclear spins which manifests in the observation of quantum jumps. The new insight was used to drastically improve the performance of quantum state readout. Summarizing, it was shown that single NV centers and proximal nuclear spins form versatile small quantum registers which can be interconnected with neighboring such NV quantum registers. Although the number of qubits used in this work is still small the experimental results propose a way of how to proceed when building a quantum computer. Regarding quantum metrology, however, the use of such a small register which can sense fields and store and process the results would already outperform a single NV electron spin by orders of magnitude.
Individual nitrogen vacancy (NV) centers in diamond have recently emerged as a leading candidate for a building block for quantum information processing systems. Individual NV centers have many properties that are desirable for qubits. For example their spin states can be manipulated, initialized and measured even at room temperature. In order to build a quantum information processing system that consists of more than a single NV center, these individual NV centers have to be connected via quantum channels that distribute entanglement and allow quantum state transfer between NV centers. This thesis explores how the optical properties of the NV center can be used and manipulated to form these quantum channels. Likewise we show how the same properties can be used to better control the nuclear spin environment surrounding the NV center. We first introduce, review and experimentally study the relevant optical properties of the NV center. These quantum optical techniques are then used to experimentally demonstrate spin-photon entanglement between the electronic spin of an individual NV center and a single photon. We next demonstrate quantum interference of two photons produced by NV centers in distinct diamond samples separated by two meters. These two demonstrations pave the way for entanglement generation, leading to quantum channels, between remote NV centers. Finally we demonstrate optical cooling, real-time measurement and conditional preparation of the nuclear spin environment around an NV center using all-optical manipulation of its electronic spin. This technique can lead to better control of individual NV centers and thus more robust quantum information processing systems.
A functioning qubit must be able to be initialized and measured. The fidelity of these operations is essential for all quantum applications, including quantum sensing, communication, and computation. The diamond nitrogen-vacancy (NV) center is a point defect in the lattice with an optical interface to a coherent ground-state spin, which makes the NV center one of the few spin qubits operable at room temperature. While the NV center spin state can be initialized and read out optically, the fidelity of these operations are far from perfect due to the charge and orbital dynamics. In typical conditions, the NV center is in the proper charge state 75% of the time, and measuring the spin state results in a non-zero signal only 1% of the time. These inefficient mechanisms make many measurements practically intractable. This thesis focuses on improving the preparation and measurement fidelities of NV centers through precise all-optical control of the charge, orbital, and spin dynamics. I first discuss an improved spin readout mechanism which relies on spin-to-charge conversion (SCC) and discuss the potential for single-shot spin readout. Following, I present how charge readout and SCC can be implemented in ensembles of NV centers within nanodiamonds and demonstrate that it provides improvements for spin-relaxometry studies. Finally, I develop a method for initializing a single NV center's charge state with real-time control and show that this capability improves spin readout performance for sensing. To conclude, I discuss how these improved initialization and readout capabilities can be applied to detecting and controlling coupled nuclear spins in the diamond lattice and consider other applications of real-time control.