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arXiv:2406.11205 · Open Systems & Information Dynamics

CP Conditions for GKSL-Like Master Equations

Akane Watanabe, Makoto Unoki, Hiromichi Nakazato, Takayuki Suzuki

Published Dec 1, 2024• 1 citation
arXivHTMLPDF

Abstract

Complete positivity (CP) of a quantum dynamical map (QDM) is, in general, difficult to show when its master equation (ME) does not conform to the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) form. The GKSL ME describes Markovian dynamics, comprising a unitary component with time-independent Hermitian operators and a nonunitary component with time-independent Lindblad operators and positive time-independent damping rates. Recently, non-Markovian dynamics have received growing attention, and the various types of GKSL-like MEs with time-dependent operators are widely discussed; however, rigorous discussions on their CP conditions remain limited. This paper presents conditions for QDMs to be CP, whose MEs take the GKSL-like form with arbitrary time dependence. One case considered is where its ME takes the time-local integro-differential GKSL-like form, which includes CP-divisible cases. Another case considered is where the ME is time-non-local but can be approximated to be time-local in the weak-coupling regime. As a special case of the time-non-local case, the same discussion holds for the time-convoluted GKSL-like form, which should be compared to previous studies.

DOI
10.1142/s1230161224500173

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Complete positivity (CP) of a quantum dynamical map (QDM) is, in general, difficult to show when its master equation (ME) does not conform to the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) form. The GKSL ME describes Markovian dynamics, comprising a unitary component with time-independent Hermitian operators and a nonunitary component with time-independent Lindblad operators and positive time-independent damping rates. Recently, non-Markovian dynamics have received growing attention, and the various types of GKSL-like MEs with time-dependent operators are widely discussed; however, rigorous discussions on their CP conditions remain limited. This paper presents conditions for QDMs to be CP, whose MEs take the GKSL-like form with arbitrary time dependence. One case considered is where its ME takes the time-local integro-differential GKSL-like form, which includes CP-divisible cases. Another case considered is where the ME is time-non-local but can be approximated to be time-local in the weak-coupling regime. As a special case of the time-non-local case, the same discussion holds for the time-convoluted GKSL-like form, which should be compared to previous studies.
In 1976, Gorini, Kossakowski, Sudarshan and Lindblad independently discovered a general form of master equations for an open quantum Markovian dynamics. In honor of all the authors, the equation is nowadays called the GKLS master equation. In this paper, we show universal constraints on the relaxation times valid for any d-level GKLS master equations, which is a generalization of the well-known constraints for 2-level systems. Specifically, we show that any relaxation rate, the inverse-relaxation time, is not greater than half of the sum of all relaxation rates. Since the relaxation times are measurable in experiments, our constraints provide a direct experimental test for the validity of the GKLS master equations, and hence for the conditions of the complete positivity and Markovianity.
Time-local quantum master equations that describe open quantum systems beyond the limit of ultraweak system-bath coupling are often not of Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) form. Prominent examples are the Redfield equation approximating general open quantum systems and the Hu-Paz-Zhang equation precisely describing a damped harmonic oscillator. In this study, we demonstrate that not only the former but also the latter can be brought to pseudo-Lindblad form. This form features a dissipator resembling that of a GKSL equation, with the distinction that some of the terms have negative weights. Moreover, we systematically investigate transformations that leave the dissipator of pseudo-Lindblad equations unchanged, while changing the relative weight between its positive and negative terms. These can be used to minimize the weights of the negative terms, which is optimal both for the convergence of a recently developed quantum-trajectory unraveling of pseudo-Lindblad equations and the truncation of the negative terms to obtain a GKSL equation.
The year 2026 marks the fiftieth anniversary of the two seminal papers in which Gorini, Kossakowski, and Sudarshan, and independently Lindblad, characterized the generators of completely positive quantum dynamical semigroups. We revisit the conceptual and historical route leading to the Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) master equation and examine several of its early developments and consequences. Our aim is to show how several initially separate mathematical and physical ideas converged in the GKLS structure theorem, imme- diately opening the way to manifold consequences for the description of dissipative quantum phenomena and how that theorem, fifty years later, remains both a foundational result and an active framework for open quantum dynamics.
We investigate the long-time behavior of quantum Markovian dynamics generated by time-dependent Gorini–Kossakowski–Lindblad–Sudarshan (GKLS) master equations. We introduce a notion of weak relaxation and derive sufficient conditions guaranteeing asymptotic independence from the initial state. Our results provide a quantitative extension of the Spohn–Frigerio theorem to time-dependent generators, yielding explicit contraction bounds in terms of the instantaneous steady state and the jump operators. For a class of microscopically derived master equations, we further obtain a graph-theoretic characterization of the aforementioned conditions that directly links the structure of the jump operators to the relaxation properties. The general theory is illustrated by applications to driven finite-level systems, including a detailed three-level example, and is extended to a non-Markovian setting by means of time-local master equations that become of GKLS form at long times. These findings pave the way for the development of a more general theory of relaxation beyond the Markovian case.
Derivation of a quantum master equation for a system weakly coupled to a bath which takes into account non-secular effects, but, nevertheless, has the mathematically correct Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) form (in particular, preserves positivity of the density operator) and also satisfies the standard thermodynamic properties is a known long-standing problem in theory of open quantum systems. The non-secular terms are important when some energy levels of the system or their differences (Bohr frequencies) are nearly degenerate. We provide a fully rigorous derivation of such equation based on a formalization of the weak-coupling limit for the general case.
A well established approach to describe open quantum system dynamics is the celebrated Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) master equation. In this article we aim to shed light on semigroup dynamics that are not of this form. Such dynamics may appear in real physical systems describing asymptotic long-time dynamics. Thus, they correspond to semigroup dynamics applicable to a restricted set of initial states only. As a way of motivating our studies, first we review known results about the single-mode Gaussian Quantum Brownian motion channel and corresponding master equations. Next we discuss a conceptually simpler family of qubit semigroup generators and identify parameter regions of completely positive, merely positive, and non-positive dynamics. We then focus on the latter case to which we will refer to as restricted-positive, as the semigroup generator may well be physically meaningful when applied to a restricted set of admissible initial states.