We generalize the classical thermal Mpemba effect (where an initially hot system relaxes faster to the final equilibrium state than a cold one) to open quantum systems coupled to several reservoirs. We show that, in general, two different types of quantum Mpemba effects are possible. They may be distinguished by quantum state tomography. However, the existence of a quantum Mpemba effect (without determining the type) can already be established by measuring simpler observables such as currents or energies. We illustrate our general results for the experimentally feasible case of an interacting two-site Kitaev model coupled to two metallic leads.
We generalize the classical thermal Mpemba effect (where an initially hot system relaxes faster to the final equilibrium state than a cold one) to open quantum systems coupled to several reservoirs. We show that, in general, two different types of quantum Mpemba effects are possible. They may be distinguished by quantum state tomography. However, the existence of a quantum Mpemba effect (without determining the type) can already be established by measuring simpler observables such as currents or energies. We illustrate our general results for the experimentally feasible case of an interacting two-site Kitaev model coupled to two metallic leads.
The Mpemba effect, in which a system farther from equilibrium relaxes faster than one closer to it, defies the intuition of nonequilibrium statistical mechanics. Here, we introduce a general framework to unambiguously witness this phenomenon based on a single observable defined for Markovian open quantum systems. The Mpemba observable bypasses full state tomography, offering utility for state preparation and thermal task optimization. We illustrate our method using local magnetization as a Mpemba signature, applying it to a qubit under generalized amplitude damping.
The Mpemba effect refers to the anomalous relaxation of a quantum state that, despite being initially farther from equilibrium, relaxes faster than a closer counterpart. Detecting such a quantum Mpemba effect typically requires full knowledge of the quantum state during its time evolution, which is an experimentally challenging task since state tomography becomes exponentially difficult as system size increases. This poses a significant obstacle in studying Mpemba effect in complex many-body systems. In this work, we demonstrate that this limitation can be overcome by identifying suitable observables that signal rapid relaxation. Moreover, as long as the system equilibrates to a known unique steady-state, it is possible to fully detect the occurrence of quantum Mpemba effect just by measuring the observable for known state preparations. Our approach thus significantly reduces experimental complexity and offers a practical route for observing the quantum Mpemba effect in complex and extended multi-qubit setups.
Since its rediscovery in the twentieth century, the Mpemba effect, where a far-from-equilibrium state may relax faster than a state closer to equilibrium, has been extensively studied in classical systems and has recently received attention in quantum systems. Many theories explaining this counter-intuitive behavior in classical systems rely on memory effects. However, in quantum systems, the relation between the Mpemba effect and memory has remained unexplored. In this Letter, we consider general non-Markovian open quantum systems and reveal new classes of quantum Mpemba effects, with no analog in Markovian quantum dynamics. Generically, open quantum dynamics possess a finite memory time and a unique steady state. Because of non-Markovian dynamics, even if the system is initialized in the steady state it can take a long time to relax back. We find other initial states that reach the steady state much faster. Most notably, we demonstrate that there can be an initial state in which the system reaches the steady state within the finite memory time itself, giving the fastest possible relaxation to stationarity. We verify the effect for quantum dot systems coupled to electronic reservoirs in equilibrium and nonequilibrium setups at weak, intermediate and strong coupling. Our Letter provides new insights into the rich physics underlying accelerated relaxation in quantum systems.
We demonstrate the quantum Mpemba effect in a quantum dot coupled to two reservoirs, described by the Anderson model. We show that the system temperatures starting from two different initial values (hot and cold) cross each other at finite time (and thereby reverse their identities; i.e., hot becomes cold and vice versa) to generate thermal quantum Mpemba effect. The slowest relaxation mode believed to play the dominating role in Mpemba effect in Markovian systems does not contribute to such anomalous relaxation in the present model. In this connection, our analytical result provides necessary condition for producing quantum Mpemba effect in the density matrix elements of the quantum dot, as a combined effect of the remaining relaxation modes.
We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.
The Mpemba effect was originally referred to as the faster icing of a higher-temperature system than a lower-temperature system, and was later generalized to anomalous decays of both classical and quantum observables to equilibrium states. Mpemba effect is mostly considered in classical systems and during cooling processes toward equilibrium states. We investigate the emergence of the effect in nonequilibrium quantum systems where the system has no asymptotic equilibrium state to approach. Instead, the system is put in contact with two different baths, and only a nonequilibrium state exists, sustained by constant energy injection from the surrounding thermal baths. First, we show that the nonequilibrium conditions can dramatically enlarge the parameter regimes where the MPE emerges. Second, we demonstrate that the anomalous MPEs and inverse MPEs emerge in the evolution of quantum correlations in the two-site fermionic system and that nonequilibrium conditions can expedite or delay the MPEs. Third, we show that the nonequilibrium-induced quantum coherence can have considerable contributions to the emergence of the MPE which the conventional Lindbladian dynamics fails to capture. Published by the American Physical Society 2024