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arXiv:2406.00618 · Physical Review A

Magnetic Feshbach resonances in ultracold atom-molecule collisions

Masato Morita, Maciej B. Kosicki, Piotr Szymon Żuchowski, Paul W. Brumer, Timur V. Tscherbul

Published Aug 14, 2024• 8 citations
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Abstract

The authors present quantum scattering calculations on magnetic Feshbach resonances (MFRs) in ultracold atom-molecule collisions. The calculations predict a wealth of experimentally detectable MFRs in Rb-SrF collisions and uncover new MFRs due to the intramolecular spin-rotation interaction. These results open up the possibility of unbiased theoretical simulations on MFRs in ultracold atom-molecule collisions with realistic interactions.

DOI
10.1103/physreva.110.l021301

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Magnetic Feshbach resonances play a central role in experimental research on atomic gases at ultracold temperatures, as they allow one to control the microscopic interactions between ultracold atoms by tuning an applied magnetic field. These resonances arise due to strong hyperfine interactions between the unpaired electron and the nuclear magnetic moment of the alkali metal atoms. A major thrust of current research is to create an ultracold gas of diatomic alkali metal molecules in the ground rovibrational state of the ground electronic ${}^{1}\ensuremath{\Sigma}$ state. Unlike alkali metal atoms, ${}^{1}\ensuremath{\Sigma}$ diatomic molecules have no unpaired electrons. However, the hyperfine interactions of molecules may give rise to magnetic Feshbach resonances. We use quantum scattering calculations to study the possible width of these resonances. Our results show that the widths of magnetic Feshbach resonances in ultracold molecule-molecule collisions for ${}^{1}\ensuremath{\Sigma}$ molecules may exceed 1 mG, rendering such resonances experimentally detectable. We hope that this work will stimulate the experimental search of these resonances.
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We investigate the presence of Feshbach resonances in ultracold alkali-dialkali reactive collisions. A potential-energy surface of Na3{\text{Na}}_{3}Na3​ in the lowest quartet state is constructed and used in quantum scattering calculations. An analysis of scattering features is performed through a systematic variation in the nonadditive three-body interaction potential. Our results should provide useful information for interpreting future atom-molecule collision experiments.