Advancing quantum sensing tools for investigating atomic and nanoscale systems is crucial for the progress of quantum technologies. While many protocols use quantum probes to extract information from stationary or weakly coupled environments, challenges intensify at the atomic scale and the nanoscale, where the environment is inherently out of equilibrium and/or strongly coupled with the sensor. In this work, we demonstrate that time-reversal symmetry in the control dynamics of a quantum sensor is broken when the qubit sensor interacts with environments that are out of equilibrium (with nonstationary fluctuations), contain quantum non-Gaussian correlations, or exhibit intrinsic time-reversal symmetry breaking. Leveraging this phenomenon, we introduce a quantum sensing paradigm based on time-asymmetric dynamical control sequences, enabling the probing of the distance of an environment from equilibrium, its time-reversal symmetry-breaking behavior, or its quantum non-Gaussian nature. Additionally, we propose sensing strategies to distinguish between these different sources of symmetry breaking. We validate our approach through proof-of-principle experimental quantum simulations using solid-state nuclear magnetic resonance, where we drive the environment of a qubit sensor out of equilibrium and use our protocol to quantify the nonstationary characteristics of the generated states. Our findings highlight the potential of this framework for quantifying nonstationary behavior, designing tailored pump-probe experiments (including measurements of quantum information scrambling), and detecting quantum states that exhibit time-reversal symmetry breaking, time-crystal structures, or quantum non-Gaussian fluctuations. Overall, this work constitutes a step forward in designing quantum devices for atomic scale and nanoscale sensing, broadening their applicability to complex and dynamic quantum environments.
Advancing quantum sensing tools for investigating atomic and nanoscale systems is crucial for the progress of quantum technologies. While many protocols use quantum probes to extract information from stationary or weakly coupled environments, challenges intensify at the atomic scale and the nanoscale, where the environment is inherently out of equilibrium and/or strongly coupled with the sensor. In this work, we demonstrate that time-reversal symmetry in the control dynamics of a quantum sensor is broken when the qubit sensor interacts with environments that are out of equilibrium (with nonstationary fluctuations), contain quantum non-Gaussian correlations, or exhibit intrinsic time-reversal symmetry breaking. Leveraging this phenomenon, we introduce a quantum sensing paradigm based on time-asymmetric dynamical control sequences, enabling the probing of the distance of an environment from equilibrium, its time-reversal symmetry-breaking behavior, or its quantum non-Gaussian nature. Additionally, we propose sensing strategies to distinguish between these different sources of symmetry breaking. We validate our approach through proof-of-principle experimental quantum simulations using solid-state nuclear magnetic resonance, where we drive the environment of a qubit sensor out of equilibrium and use our protocol to quantify the nonstationary characteristics of the generated states. Our findings highlight the potential of this framework for quantifying nonstationary behavior, designing tailored pump-probe experiments (including measurements of quantum information scrambling), and detecting quantum states that exhibit time-reversal symmetry breaking, time-crystal structures, or quantum non-Gaussian fluctuations. Overall, this work constitutes a step forward in designing quantum devices for atomic scale and nanoscale sensing, broadening their applicability to complex and dynamic quantum environments.
Non-reciprocal propagation of energy and information is fundamental to a wide range of quantum technology applications. In this work, we explore the quantum many-body dynamics of a qubit ensemble coupled to a shared bath that mediates coherent and dissipative inter-qubit interactions with both symmetric and anti-symmetric components. We find that the interplay between anti-symmetric (symmetric) coherent and symmetric (anti-symmetric) dissipative interactions results in non-reciprocal couplings, which, in turn, generate a spatially asymmetric emission pattern. We demonstrate that this pattern arises from non-reciprocal interactions coupling different quantum many-body states within a specific excitation manifold. Focusing on solid-state baths, we show that their lack of time-reversal and inversion symmetry is a key ingredient for generating non-reciprocal dynamics in the qubit ensemble. With the plethora of quantum materials that exhibit this symmetry breaking at equilibrium, our approach paves the way for realizing cooperative non-reciprocal transport in qubit ensembles without requiring time-modulated external drives or complex engineering. Using an ensemble of nitrogen-vacancy (NV) centers coupled to a generic non-centrosymmetric ferromagnetic bath as a concrete example, we demonstrate that our predictions can be tested in near-future experiments. As the spatial asymmetry in the relaxation dynamics of the qubit ensemble is a direct probe of symmetry breaking in the solid-state bath, our work also opens the door to developing model-agnostic quantum sensing schemes capable of detecting bath properties invisible to current state-of-the-art protocols, which operate solid-state defects as single-qubit sensors.
Controlling the dynamics of targeted quantum correlations is a central goal across many disciplines of quantum science. For applications in nanoscale quantum sensing, nitrogen-vacancy (NV) centers in diamond have recently emerged as a leading platform due to their atom-like nature, exquisite magnetic sensitivity and well-developed coherent control techniques under ambient conditions. However, harnessing the entanglement structure required to improve this sensitivity beyond the standard quantum limit (SQL) from the native dipolar interactions between NV centers is challenging due to their strong positional disorder, three-dimensional geometry and low-fidelity readout. Coupled tightly to proof of principle experimental demonstrations, this thesis provides a theoretical blueprint to realize practical, entanglement-enhanced quantum sensing in the solid-state via far-from-equilibrium dynamics of dense ensembles of NV centers in diamond. Our most fundamental contribution is to identify a universal mechanism exploiting the thermalization of long-wavelength spin textures to generate scalable spin squeezing in the absence of finite temperature symmetry breaking. We further develop a novel sensing protocol based on asymmetric time-reversal capable of rapidly breaking the SQL without high-fidelity readout. Challenging long-standing beliefs in the field, these results open the door to a new era of entanglement-enhanced sensing under ambient conditions, with applications ranging from nanoscale imaging of biological structures to covariance magnetometry of exotic quantum materials.
Quantum sensors offer exceptional sensitivity to nanoscale magnetic fluctuations, where non-stationary effects -- such as spin diffusion -- and non-Markovian dynamics arising from coupling to few environmental degrees of freedom play critical roles. Because fully reconstructing the microscopic structure of realistic spin baths is often infeasible, a practical challenge is to identify the dynamical features that are actually encoded in the sensor's decoherence signal. Here, we demonstrate how quantum sensors can operationally characterize the statistical nature of environmental noise, distinguishing between stationary and non-stationary behaviors, as well as Markovian and non-Markovian dynamics. Using nitrogen-vacancy (NV) centers in diamond as a platform, we develop a physical noise model that captures the essential dynamical features of realistic environments relevant to sensor observables -- independently of the microscopic bath details -- and provides analytical predictions for Ramsey decay across different regimes. These predictions are experimentally validated through controlled noise injection with tunable correlation properties. Our results showcase the capability of quantum sensors to isolate and identify key dynamical properties of complex environments, without requiring full microscopic bath reconstruction. This work clarifies the operational signatures of non-stationarity and non-Markovian behavior at the nanoscale and lays the foundation for strategies that mitigates decoherence while exploiting environmental dynamics for enhanced quantum sensing.
Quantum probing is a fairly wide topic deepening its roots into many fields as it can borrow tools from, and be applied to, many-body physics, open quantum systems theory, quantum information and quantum thermodynamics. Its wide range of applicability, i.e. the diverse systems under investigations and their specific properties, contributes in making a general theory of quantum probing a rather challenging, if not impossible, task. Despite the need to specialize the probing technique to the various physical systems, we have identified a leitmotiv in our probing approach. Specifically, we will consider a perturbation potential acting as the source of the probing procedure, in most cases this will be an impurity in the complex environment acting as quantum probe. We will generally quantify the information exchange between the probe and its environment, and explore the connection to the concept of non-Markovian, i.e. memoryless, quantum dynamics. This thesis aims at discussing probing protocols for atomic systems confined in optical lattices, both fermionic and bosonic species, as well as trapped ions. The systems inquired can be currently implemented in the field of ultra cold atoms, where they have attracted interest as ideal candidates for quantum simulators and quantum technologies. We will show how to design protocols in which these cold many-body systems act as an environment to a quantum probe, often designed as an impurity atom. Exploiting tools from open quantum systems theory we will discuss how to detect, from the dynamics of the probe, the characteristics of the complex environment. The key idea is to use the quantum probe as read-out device, the properties of the environment are then inferred trough measurements performed exclusively on the probe. Quantities of interest will be related to the environment energy spectrum, equilibrium properties and temperature. The quantum probing paradigm will also allow us to investigate critical phenomena such as phase transitions and orthogonality catastrophe. Finally, we will show how the memory effects induced in the reduced dynamics of an immersed quantum probe can witness, to some extent, the character of the excitations of the environment hinting to a natural link between non-Markovianity and localisation phenomena.
Electronic spins of nitrogen vacancy (NV) centers in diamond constitute a promising system for micro- and nano-scale magnetic sensing, due to their operation under ambient conditions, ease of placement in close proximity to sensing targets, and biological compatibility. At high densities, the electronic spins interact through dipolar coupling, which typically limits but can also potentially enhance sensing performance. Here we report the experimental demonstration of many-body signal amplification in a solid-state, room temperature quantum sensor. Our approach utilizes time-reversed two-axis-twisting interactions, engineered through dynamical control of the quantization axis and Floquet engineering in a two-dimensional ensemble of NV centers. Strikingly, we observe that the optimal amplification occurs when the backward evolution time equals twice the forward evolution time, in sharp contrast to the conventional Loschmidt echo. These observations can be understood as resulting from an underlying time-reversed mirror symmetry of the microscopic dynamics, providing key insights into signal amplification and opening the door towards entanglement-enhanced practical quantum sensing.
Discrete time crystals are non-equilibrium phases of matter in periodically driven systems, characterized by robust subharmonic oscillations and broken discrete time-translation symmetry. Their long-lived coherent dynamics and resilience to imperfections make them promising resources for quantum sensing. A disorder-free discrete-time crystal probe can provide the quantum-enhanced estimation of the coupling parameter. Here, we extend this sensing mechanism to nonlinear interactions and show that this nonlinear profile strongly enhances the sensing precision by increasing the system-size scaling exponent of the quantum Fisher information. Our analytical discussion separates a rigorous seminorm upper bound from the physically relevant scaling realized by product-state probes in the time crystal regime. Numerically, we find that the quantum Fisher information retains its quadratic long-time growth with the number of Floquet cycles, while its system-size exponent increases approximately linearly with the nonlinearity exponent, identifying nonlinearity as a resource for quantum-enhanced sensitivity. We further show that stronger nonlinearities shrink the time crystal stability window, making the probe more sensitive to small deviations from the resonant condition. We also analyze the effect of imperfect pulses and show that such imperfections can enhance, rather than suppress, the information encoded in the evolved state. Finally, we discuss a digital implementation of the nonlinear DTC sensing protocol using superconducting qubits.