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arXiv:2404.00177

Quantum Transition Probabilities

Stanley Gudder

Published Mar 29, 2024• 1 citation
arXivHTMLPDF

Abstract

Transition probabilities are an important and useful tool in quantum mechanics. However, in their present form, they are limited in scope and only apply to pure quantum states. In this article we extend their applicability to mixed states and to transitions between quantum effects. We also present their dependence on a measured operation or instrument. We begin by defining our concepts on a general quantum effect algebra. These concepts are illustrated using Holevo operations and instruments. We then present transition probabilities in the special case of the Hilbert space formulation of quantum mechanics. We show that for pure states and particular types of operations the transition probabilities reduce to their usual form. We give examples in terms of Lüders operations and instruments.

DOI
10.48550/arxiv.2404.00177

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Transition probabilities are an important and useful tool in quantum mechanics. However, in their present form, they are limited in scope and only apply to pure quantum states. In this article we extend their applicability to mixed states and to transitions between quantum effects. We also present their dependence on a measured operation or instrument. We begin by defining our concepts on a general quantum effect algebra. These concepts are illustrated using Holevo operations and instruments. We then present transition probabilities in the special case of the Hilbert space formulation of quantum mechanics. We show that for pure states and particular types of operations the transition probabilities reduce to their usual form. We give examples in terms of Lüders operations and instruments.
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We begin with a study of operations and the effects they measure. We define the probability that an effect aaa occurs when the system is in a state ρ\rhoρ by Pρ(a)=Tr(ρa)P_{\rho}(a)=\textrm{Tr}(\rho a)Pρ​(a)=Tr(ρa). If Pρ(a)≠0P_{\rho}(a)\ne0Pρ​(a)=0 and I\mathcal{I}I is an operation that measures aaa, we define the conditional probability of an effect bbb given aaa relative to I\mathcal{I}I by Pρ(b∣a)=Tr[I(ρ)b]/Pρ(a)P_{\rho}(b\mid a)=\textrm{Tr}[\mathcal{I}(\rho)b]/P_{\rho}(a)Pρ​(b∣a)=Tr[I(ρ)b]/Pρ​(a). We characterize when Bayes' quantum second rule Pρ(b∣a)=Pρ(b)Pρ(a) Pρ(a∣b)P_{\rho}(b\mid a)=\frac{P_{\rho}(b)}{P_{\rho}(a)}\,P_{\rho}(a\mid b)Pρ​(b∣a)=Pρ​(a)Pρ​(b)​Pρ​(a∣b) holds. We then consider Lüders and Holevo operations. We next discuss instruments and the observables they measure. If AAA and BBB are observables and an instrument I\mathcal{I}I measures AAA, we define the observable BBB conditioned on AAA relative to I\mathcal{I}I and denote it by (B∣A)(B\mid A)(B∣A). Using these concepts, we introduce Bayes' quantum first rule. We observe that this is the same as the classical Bayes' first rule, except it depends on the instrument used to measure AAA. We then extend this to Bayes' quantum first rule for expectations. We show that two observables BBB and CCC are jointly commuting if and only if there exists an atomic observable AAA such that B=(B∣A)B=(B\mid A)B=(B∣A) and C=(C∣A)C=(C\mid A)C=(C∣A). We next obtain a general uncertainty principle for conditioned observables. Finally, we discuss observable conditioned quantum entropies. The theory is illustrated with many examples. Quanta 2024; 13: 1–10.
Abstract This chapter develops the fundamental notions and concepts of the probabilistic and statistical interpretation of quantum mechanics. It begins with a brief review of the mathematical structure given by a Hilbert space of state vectors and an algebra of observables represented by selfadjoint operators. Special emphasis is laid on the connection between the spectral representation of a selfadjoint operator and a corresponding random variable that describes the possible measurement outcomes. The chapter further introduces the concepts of a composite quantum system, of the reduced density matrix, and of entangled quantum states. A section on quantum entropies is included, as well as the mathematical formulation of the generalized theory of quantum measurements in terms of completely positive quantum operations and effects.
Max Born's statistical interpretation made probabilities play a major role in quantum theory. Here we show that these quantum probabilities and the classical probabilities have very different origins. While the latter always result from an assumed probability measure, the first include transition probabilities with a purely algebraic origin. Moreover, the general definition of transition probability introduced here comprises not only the well-known quantum mechanical transition probabilities between pure states or wave functions, but further novel cases. A transition probability that differs from 0 and 1 manifests the typical quantum indeterminacy in a similar way as Heisenberg's and others' uncertainty relations and, furthermore, rules out deterministic states in the same way as the Bell-Kochen-Specker theorem. However, the transition probability defined here achieves a lot more beyond that: it demonstrates that the algebraic structure of the Hilbert space quantum logic dictates the precise values of certain probabilities and it provides an unexpected access to these quantum probabilities that does not rely on states or wave functions.
Max Born's statistical interpretation made probabilities play a major role in quantum theory. Here we show that these quantum probabilities and the classical probabilities have very different origins. Although the latter always result from an assumed probability measure, the first include transition probabilities with a purely algebraic origin. Moreover, the general definition of transition probability introduced here comprises not only the well-known quantum mechanical transition probabilities between pure states or wave functions, but further physically meaningful and experimentally verifiable novel cases. A transition probability that differs from 0 and 1 manifests the typical quantum indeterminacy in a similar way as Heisenberg's and others' uncertainty relations and, furthermore, rules out deterministic states in the same way as the Bell-Kochen-Specker theorem. However, the transition probability defined here achieves a lot more beyond that: it demonstrates that the algebraic structure of the Hilbert space quantum logic dictates the precise values of certain probabilities and it provides an unexpected access to these quantum probabilities that does not rely on states or wave functions.