Abstract The reduced state of a small system strongly coupled to a thermal bath may be athermal and used as a small battery once disconnected. The unitarily extractable energy (a.k.a. ergotropy) will be negligible if the disconnecting process is too slow. To study the efficiency of this battery, we consider the cycle of disconnecting, extracting, and connecting the battery back to the bath. Efficiency, i.e. the ratio between ergotropy and connecting plus disconnecting work, is a function of disconnecting time. We consider the Caldeira–Leggett model of a quantum battery in two scenarios. In the first scenario, we assume that the discharged battery is uncorrelated to the bath when connecting back and find that the efficiency peaks at an optimal disconnecting time. In the second scenario, the discharged battery is correlated to the bath, and see that the optimal efficiency corresponds to an instantaneous disconnection. On top of these results, we analyze various thermodynamic quantities for these Caldeira–Leggett quantum batteries and express the first and second laws of thermodynamics for the cycles in simple form despite the system-bath initial correlations and strong coupling regime of the working device.
Abstract The reduced state of a small system strongly coupled to a thermal bath may be athermal and used as a small battery once disconnected. The unitarily extractable energy (a.k.a. ergotropy) will be negligible if the disconnecting process is too slow. To study the efficiency of this battery, we consider the cycle of disconnecting, extracting, and connecting the battery back to the bath. Efficiency, i.e. the ratio between ergotropy and connecting plus disconnecting work, is a function of disconnecting time. We consider the Caldeira–Leggett model of a quantum battery in two scenarios. In the first scenario, we assume that the discharged battery is uncorrelated to the bath when connecting back and find that the efficiency peaks at an optimal disconnecting time. In the second scenario, the discharged battery is correlated to the bath, and see that the optimal efficiency corresponds to an instantaneous disconnection. On top of these results, we analyze various thermodynamic quantities for these Caldeira–Leggett quantum batteries and express the first and second laws of thermodynamics for the cycles in simple form despite the system-bath initial correlations and strong coupling regime of the working device.
Abstract The reduced state of a small system strongly coupled to a charger in thermal equilibrium may be athermal and used as a small battery once disconnected. By harnessing the battery-charger correlations, the battery’s extractable energy can increase above the ergotropy. We introduce a protocol that uses a quantum system as a memory that measures the charger and leaves the battery intact in its charged state. Using the information gained from the measurement, the daemonic ergotropy of the battery is extracted. Then the battery is reconnected to the charger, thermalizing and charging it. However, the memory should return to its initial standard state to close the thermodynamic cycle. Thus, on the one hand, the work cost of the cycle is the sum of the disconnecting and reconnecting battery-charger work plus the measurement and erasure work. On the other hand, the extracted energy is the daemonic ergotropy of the battery plus the ergotropy of the memory. The ratio of these quantities defines the efficiency of the cycle. The protocol is exemplified by a modified transverse spin 1/2 Ising chain, one spin functioning as the battery and the others as the charger. The memory is another auxiliary spin 1/2. We found pairs of measurement schemes from which we extract the same daemonic ergotropy from the battery, they dissipate the same amount of energy, and one leaves the memory in an active state, the other in a passive state. We study the memory’s ergotropy and the daemonic ergotropy of the battery. We find that with measurements, the efficiency can surpass that of the unmeasured protocol, given conditions on temperature, coupling, and choice of the measurement operators.
Abstract Starting from the observation that the reduced state of a system strongly coupled to a bath is, in general, an athermal state, we introduce and study a cyclic battery–charger quantum device that is in thermal equilibrium, or in a ground state, during the charge storing stage. The cycle has four stages: the equilibrium storage stage is interrupted by disconnecting the battery from the charger, then work is extracted from the battery, and then the battery is reconnected with the charger; finally, the system is brought back to equilibrium. At no point during the cycle are the battery–charger correlations artificially erased. We study the case where the battery and charger together comprise a spin-1/2 Ising chain, and show that the main characteristics—the extracted energy and the thermodynamic efficiency—can be enhanced by operating the cycle close to the quantum phase transition point. When the battery is just a single spin, we find that the output work and efficiency show a scaling behavior at criticality and derive the corresponding critical exponents. Due to always present correlations between the battery and the charger, operations that are equivalent from the perspective of the battery can entail different energetic costs for switching the battery–charger coupling. This happens only when the coupling term does not commute with the battery’s bare Hamiltonian, and we use this purely quantum leverage to further optimize the performance of the device.
Abstract We introduce a cyclic quantum battery QB model, based on an interacting bipartite system, weakly coupled to a thermal bath. The working cycle of the battery consists of four strokes: system thermalization, disconnection of subsystems, ergotropy extraction, and reconnection. The thermal bath acts as a charger in the thermalization stroke, while ergotropy extraction is possible because the ensuing thermal state is no longer passive after the disconnection stroke. Focusing on the case of two interacting qubits, we show that phase coherence, in the presence of non-trivial correlations between the qubits, can be exploited to reach working regimes with efficiency higher than 50% while providing finite ergotropy. Our protocol is illustrated through a simple and feasible circuit model of a cyclic superconducting QB. Furthermore, we simulate the considered cycle on superconducting IBM quantum machines. The good agreement between the theoretical and simulated results strongly suggests that our scheme for cyclic QBs can be successfully realized in superconducting quantum hardware.
Starting from the observation that the reduced state of a system strongly coupled to a bath is, in general, an athermal state, we introduce and study a cyclic battery-charger quantum device that is in thermal equilibrium, or in a ground state, during the charge storing stage. The cycle has four stages: the equilibrium storage stage is interrupted by disconnecting the battery from the charger, then work is extracted from the battery, and then the battery is reconnected with the charger; finally, the system is brought back to equilibrium. At no point during the cycle are the battery-charger correlations artificially erased. We study the case where the battery and charger together comprise a spin-1/2 Ising chain, and show that the main characteristics-the extracted energy and the thermodynamic efficiency-can be enhanced by operating the cycle close to the quantum phase transition point. When the battery is just a single spin, we find that the output work and efficiency show a scaling behavior at criticality and derive the corresponding critical exponents. Due to always present correlations between the battery and the charger, operations that are equivalent from the perspective of the battery can entail different energetic costs for switching the battery-charger coupling. This happens only when the coupling term does not commute with the battery's bare Hamiltonian, and we use this purely quantum leverage to further optimize the performance of the device.
The study of quantum thermodynamics has led to the development of quantum batteries. These devices use quantum advantages to store and extract useful energy from physical systems. Ergotropy is the maximum work that can be extracted from a quantum system by cyclic unitary operations. When external thermal baths couple with the quantum battery, there is energy loss due to thermal effects on the system. In some cases, a part of the total energy available in the system cannot be stored as ergotropy. Therefore, it is important to consider the amount of residual energy that cannot be extracted as useful work from quantum batteries by unitary processes. To better understand the amount of energy lost during work extraction, it is necessary to examine the constraint of unitary processes. The system exergy represents the maximum amount of work that can be extracted from the system while bringing it into equilibrium with a thermal bath. It can be separated into two parts: ergotropy and residual energy. Thus, the present chapter describes the relationship between exergy and its potential benefits and effects on the performance of quantum batteries.
Going beyond isolated system dynamics, we examine how local and spatially correlated reservoirs influence the work extraction in quantum batteries. By employing a one-dimensional spin-1/2 model coupled to baths via dephasing and amplitude-damping noise, we demonstrate that correlations in reservoirs can significantly enhance battery's performance compared to local noise. In the dephasing scenario, we prove that correlated reservoirs produce a finite amount of extractable work, or ergotropy, during the transient regime when a two-cell battery is initialized in a product state while local noise yields vanishing ergotropy at all times, despite nonvanishing stored energy in both cases. Numerical simulations confirm that this advantage persists across larger system sizes and for both entangled and product initial states. We also find that the dynamics of quantum coherence closely mirror those of ergotropy, highlighting coherence as a key resource underlying the enhanced performance of quantum batteries. Further, we observe that the fraction of stored energy extracted from quantum batteries displays a sharper contrast between the correlated and local reservoirs. Moreover, for dephasing noise, this fraction remains independent of system size, whereas in the amplitude damping case, it exhibits a clear system-size dependence within the transient regime, highlighting distinct operational behaviors under different noise models. In addition, we reveal that when the battery dynamics is governed by an effective Hamiltonian with long-range interactions, it yields higher ergotropy compared to short-range interactions, emphasizing the advantages of reservoir engineering for efficient device design.