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arXiv:2402.10384 · Physical review. E

Catalytic enhancement in the performance of the microscopic two-stroke heat engine

Tanmoy Biswas, Marcin Łobejko, Paweł Mazurek, Michał Horodecki

Published Oct 17, 2024• 7 citations
arXivHTMLPDF

Abstract

We consider a model of heat engine operating in the microscopic regime: the two-stroke engine. It produces work and exchanges heat in two discrete strokes that are separated in time. The working body of the engine consists of two d-level systems initialized in thermal states at two distinct temperatures. Additionally, an auxiliary nonequilibrium system called catalyst may be incorporated with the working body of the engine, provided the state of the catalyst remains unchanged after the completion of a thermodynamic cycle. This ensures that the work produced by the engine arises solely from the temperature difference. Upon establishing the rigorous thermodynamic framework, we characterize twofold improvement stemming from the inclusion of a catalyst. Firstly, we prove that in the noncatalytic scenario, the optimal efficiency of the two-stroke heat engine with a working body composed of two-level systems is given by the Otto efficiency, which can be surpassed by incorporating a catalyst with the working body. Secondly, we show that incorporating a catalyst allows the engine to operate in frequency and temperature regimes that are not accessible for noncatalytic two-stroke engines. We conclude with a general conjecture about the advantage brought by a catalyst: including the catalyst with the working body always allows to improve efficiency over the noncatalytic scenario for any microscopic two-stroke heat engines. We prove this conjecture for two-stroke engines where the working body is composed of two d-level systems initialized in thermal states at two distinct temperatures, as long as the final joint state leading to optimal efficiency in the noncatalytic scenario is not a product state, or at least one of the d-level system is not thermal.

DOI
10.1103/physreve.110.044120

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We consider a model of heat engine operating in the microscopic regime: the two-stroke engine. It produces work and exchanges heat in two discrete strokes that are separated in time. The working body of the engine consists of two d-level systems initialized in thermal states at two distinct temperatures. Additionally, an auxiliary nonequilibrium system called catalyst may be incorporated with the working body of the engine, provided the state of the catalyst remains unchanged after the completion of a thermodynamic cycle. This ensures that the work produced by the engine arises solely from the temperature difference. Upon establishing the rigorous thermodynamic framework, we characterize twofold improvement stemming from the inclusion of a catalyst. Firstly, we prove that in the noncatalytic scenario, the optimal efficiency of the two-stroke heat engine with a working body composed of two-level systems is given by the Otto efficiency, which can be surpassed by incorporating a catalyst with the working body. Secondly, we show that incorporating a catalyst allows the engine to operate in frequency and temperature regimes that are not accessible for noncatalytic two-stroke engines. We conclude with a general conjecture about the advantage brought by a catalyst: including the catalyst with the working body always allows to improve efficiency over the noncatalytic scenario for any microscopic two-stroke heat engines. We prove this conjecture for two-stroke engines where the working body is composed of two d-level systems initialized in thermal states at two distinct temperatures, as long as the final joint state leading to optimal efficiency in the noncatalytic scenario is not a product state, or at least one of the d-level system is not thermal.
We demonstrate how to incorporate a catalyst to enhance the performance of a heat engine. Specifically, we analyze efficiency in one of the simplest engine models, which operates in only two strokes and comprises of a pair of two-level systems, potentially assisted by a d-dimensional catalyst. When no catalysis is present, the efficiency of the machine is given by the Otto efficiency. Introducing the catalyst allows for constructing a protocol which overcomes this bound, while new efficiency can be expressed in a simple form as a generalization of Otto's formula: 1-(1/d)(ω_{c}/ω_{h}). The catalyst also provides a bigger operational range of parameters in which the machine works as an engine. Although an increase in engine efficiency is mostly accompanied by a decrease in work production (approaching zero as the system approaches Carnot efficiency), it can lead to a more favorable trade-off between work and efficiency. The provided example introduces new possibilities for enhancing performance of thermal machines through finite-dimensional ancillary systems.
Quantum thermal machines offer promising platforms for exploring the fundamental limits of thermodynamics at the microscopic scale. Building on majorization theory, we further extend the catalytic concept to a two-stroke quantum refrigerator via discrete strokes. The working medium consists of two two-level systems and two heat reservoirs at different temperatures and is assisted by an auxiliary system acting as a catalyst. We show that the presence of the catalyst leads to two significant enhancements: it enables the coefficient of performance and the cooling capacity to exceed the Otto bound and allows the refrigerator to operate in frequency and temperature regimes that are inaccessible without a catalyst. These results highlight the potential of catalytic mechanisms to broaden the operational capabilities of quantum thermal devices and to surpass conventional thermodynamic performance limits.
We consider a three-stroke engine in the microscopic regime where the working body of the engine is composed of a two-level system. The working body of the engine aims to withdraw heat from the hot heat bath, generate work, and discharge the surplus heat into the cold heat bath through the successive execution of three strokes. In this process, the interaction of the working body with the heat baths is assumed to be energy-conserving and thus can be described by thermal operations. While earlier studies analyzed the optimal performance of this engine when the working body could be transformed by any arbitrary thermal operation, we present closed expressions for the maximum work produced by the engine and the maximum efficiency of the engine when only a restricted class of thermal operations can be implemented on the working body. Furthermore, we explore the engine's optimal performance under two well-studied classes of restrictions: thermal operations realized via Jaynes-Cummings interaction and thermal operations realizable with finite-sized heat baths. Therefore, on one hand, our results are general, as they reproduce the optimal performance achieved when any arbitrary thermal operation can be implemented on the working body once the restriction is relaxed. On the other hand, our results allow us to determine the engine's maximum work production and efficiency in a more realistic scenario, where only a restricted class of thermal operations are possible, thereby bringing our findings closer to experimental feasibility.
The minimal-coupling quantum heat engine is a thermal machine consisting of an explicit energy storage system, heat baths, and a working body, which alternatively couples to subsystems through discrete strokes --- energy-conserving two-body quantum operations. Within this paradigm, we present a general framework of quantum thermodynamics, where a work extraction process is fundamentally limited by a flow of non-passive energy (ergotropy), while energy dissipation is expressed through a flow of passive energy. It turns out that small dimensionality of the working body and a restriction only to two-body operations make the engine fundamentally irreversible. Our main result is finding the optimal efficiency and work production per cycle within the whole class of irreversible minimal-coupling engines composed of three strokes and with the two-level working body, where we take into account all possible quantum correlations between the working body and the battery. One of the key new tools is the introduced ``control-marginal state" --- one which acts only on a working body Hilbert space, but encapsulates all features regarding work extraction of the total working body-battery system. In addition, we propose a generalization of the many-stroke engine, and we analyze efficiency vs extracted work trade-offs, as well as work fluctuations after many cycles of the running of the engine.
Abstract The efficiency of a quantum heat engine is maximum when the unitary strokes of the quantum Otto cycle are adiabatic. On the other hand, this may not be always possible due to small energy gaps in the system, especially at the critical point (CP) where the gap between the ground state and the first excited state vanishes and the system gets excited. With the aim to regain this lost adiabaticity, we modify one of the unitary strokes of the Otto cycle by allowing the system to first evolve with a time dependent Hamiltonian as in the case of a usual Otto cycle, followed by an additional evolution with a different time independent Hamiltonian so that the system reaches a less excited state. This will help in increasing the magnitude of the heat absorbed from the hot bath so that the work output and efficiency of the engine can be increased. We demonstrate this method using an integrable model and a non-integrable model as the working medium and discuss the generality and limitations of this method. In the case of a two spin system, the optimal value for the time till which the system needs to be freely evolved is calculated analytically in the adiabatic limit. The results show that implementing this modified unitary stroke significantly improves the work output and efficiency of the engine, especially when it crosses the CP.
We study a minimal quantum Otto heat engine, where the working medium consists of an interacting few-body system in a harmonic trap. This allows us to consider the interaction strength as an additional tunable parameter during the work strokes. We calculate the figures of merit of this engine as a function of the temperature and show clearly in which parameter regimes the interactions assist in engine performance. We also study the finite-time dynamics and the subsequent tradeoff between the efficiency and the power, comparing the interaction-enhanced cycle with the case where the system remains scale-invariant.