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arXiv:2401.10343 · Physical Review Letters

Estimation of Hamiltonian Parameters from Thermal States

Luis Pedro García-Pintos, Kishor Bharti, Jacob Bringewatt, Hossein Dehghani, Adam Ehrenberg, Nicole Yunger Halpern, Alexey Vyacheslavovich Gorshkov

Published Jul 26, 2024• 15 citations
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Abstract

We upper bound and lower bound the optimal precision with which one can estimate an unknown Hamiltonian parameter via measurements of Gibbs thermal states with a known temperature. The bounds depend on the uncertainty in the Hamiltonian term that contains the parameter and on the term's degree of noncommutativity with the full Hamiltonian: higher uncertainty and commuting operators lead to better precision. We apply the bounds to show that there exist entangled thermal states such that the parameter can be estimated with an error that decreases faster than 1/sqrt[n], beating the standard quantum limit. This result governs Hamiltonians where an unknown scalar parameter (e.g., a component of a magnetic field) is coupled locally and identically to n qubit sensors. In the high-temperature regime, our bounds allow for pinpointing the optimal estimation error, up to a constant prefactor. Our bounds generalize to joint estimations of multiple parameters. In this setting, we recover the high-temperature sample scaling derived previously via techniques based on quantum state discrimination and coding theory. In an application, we show that noncommuting conserved quantities hinder the estimation of chemical potentials.

DOI
10.1103/physrevlett.133.040802

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We upper bound and lower bound the optimal precision with which one can estimate an unknown Hamiltonian parameter via measurements of Gibbs thermal states with a known temperature. The bounds depend on the uncertainty in the Hamiltonian term that contains the parameter and on the term's degree of noncommutativity with the full Hamiltonian: higher uncertainty and commuting operators lead to better precision. We apply the bounds to show that there exist entangled thermal states such that the parameter can be estimated with an error that decreases faster than 1/sqrt[n], beating the standard quantum limit. This result governs Hamiltonians where an unknown scalar parameter (e.g., a component of a magnetic field) is coupled locally and identically to n qubit sensors. In the high-temperature regime, our bounds allow for pinpointing the optimal estimation error, up to a constant prefactor. Our bounds generalize to joint estimations of multiple parameters. In this setting, we recover the high-temperature sample scaling derived previously via techniques based on quantum state discrimination and coding theory. In an application, we show that noncommuting conserved quantities hinder the estimation of chemical potentials.
We consider the estimation of an unknown parameter θ through a quantum probe at thermal equilibrium. The probe is assumed to be in a Gibbs state according to its Hamiltonian H_{θ}, which is divided in a parameter-encoding term H_{θ}^{P} and an additional, parameter-independent control H^{C}. Given a fixed encoding, we find the maximal quantum Fisher information attainable via arbitrary H^{C}, which provides a fundamental bound on the measurement precision. We elucidate the role of quantum coherence between encoding and control in different temperature regimes, which include ground state metrology as a limiting case. In the case of locally encoded parameters, the optimal sensitivity presents an N^{2} scaling in terms of the number of particles of the probe, which can be reached, at finite temperature, with local measurements and no entanglement. We apply our results to paradigmatic spin chain models, showing that these fundamental limits can be approached using local two-body interactions. Our results set the fundamental limits and optimal control for metrology with thermal and ground state probes, including probes at the verge of criticality.
Estimation of physical parameters encoded in a Hamiltonian is a central task in quantum sensing and learning. While the ultimate precision limit for estimating a single parameter coupled to a single generator is well established, the corresponding bound for estimating a function of multiple parameters-each coupled to distinct and possibly non-commuting generators-remains unknown in general. Here, we derive the ultimate quantum limit and present an estimation protocol for any function of parameters in a general Hamiltonian that attains this bound. We show that, although the task is fundamentally a multiparameter problem, our tight bound reduces to an optimized single-parameter quantum Cramér-Rao bound, even for arbitrary generator sets. Our result unifies and extends previous works, providing a general framework for optimal function estimation in quantum systems.
Quantum metrology enhances the sensitivity of parameter estimation using the distinctive resources of quantum mechanics such as entanglement. It has been shown that the precision of estimating an overall multiplicative factor of a Hamiltonian can be increased to exceed the classical limit, yet little is known about estimating a general Hamiltonian parameter. In this paper, we study this problem in detail. We find that the scaling of the estimation precision with the number of systems can always be optimized to the Heisenberg limit, while the time scaling can be quite different from that of estimating an overall multiplicative factor. We derive the generator of local parameter translation on the unitary evolution operator of the Hamiltonian, and use it to evaluate the estimation precision of the parameter and establish a general upper bound on the quantum Fisher information. The results indicate that the quantum Fisher information generally can be divided into two parts: one is quadratic in time, while the other oscillates with time. When the eigenvalues of the Hamiltonian do not depend on the parameter, the quadratic term vanishes, and the quantum Fisher information will be bounded in this case. To illustrate the results, we give an example of estimating a parameter of a magnetic field by measuring a spin-12\frac{1}{2}21​ particle and compare the results for estimating the amplitude and the direction of the magnetic field.
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We discuss the application of techniques of quantum estimation theory and quantum metrology to thermometry. The ultimate limit to the precision at which the temperature of a system at thermal equilibrium can be determined is related to the heat capacity when global measurements are performed on the system. We prove that if technical or practical limitations restrict our capabilities to local probing, the highest achievable accuracy to temperature estimation reduces to a sort of mesoscopic version of the heat capacity. Adopting a more practical perspective, we also discuss the relevance of qubit systems as optimal quantum thermometers, in order to retrieve the temperature, or to discriminate between two temperatures, characterizing a thermal reservoir. We show that quantum coherence and entanglement in a probe system can facilitate faster, or more accurate measurements of temperature. While not surprising given this has been demonstrated in phase estimation, temperature is not a conventional quantum observable, therefore these results extend the theory of parameter estimation to measurement of non-Hamiltonian quantities. Finally we point out the advantages brought by a less standard estimation technique based on sequential measurements, when applied to quantum thermometry.
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