Quantum metrology enhances the sensitivity of parameter estimation using the distinctive resources of quantum mechanics such as entanglement. It has been shown that the precision of estimating an overall multiplicative factor of a Hamiltonian can be increased to exceed the classical limit, yet little is known about estimating a general Hamiltonian parameter. In this paper, we study this problem in detail. We find that the scaling of the estimation precision with the number of systems can always be optimized to the Heisenberg limit, while the time scaling can be quite different from that of estimating an overall multiplicative factor. We derive the generator of local parameter translation on the unitary evolution operator of the Hamiltonian, and use it to evaluate the estimation precision of the parameter and establish a general upper bound on the quantum Fisher information. The results indicate that the quantum Fisher information generally can be divided into two parts: one is quadratic in time, while the other oscillates with time. When the eigenvalues of the Hamiltonian do not depend on the parameter, the quadratic term vanishes, and the quantum Fisher information will be bounded in this case. To illustrate the results, we give an example of estimating a parameter of a magnetic field by measuring a spin-$\frac{1}{2}$ particle and compare the results for estimating the amplitude and the direction of the magnetic field.
Quantum metrology enhances the sensitivity of parameter estimation using the distinctive resources of quantum mechanics such as entanglement. It has been shown that the precision of estimating an overall multiplicative factor of a Hamiltonian can be increased to exceed the classical limit, yet little is known about estimating a general Hamiltonian parameter. In this paper, we study this problem in detail. We find that the scaling of the estimation precision with the number of systems can always be optimized to the Heisenberg limit, while the time scaling can be quite different from that of estimating an overall multiplicative factor. We derive the generator of local parameter translation on the unitary evolution operator of the Hamiltonian, and use it to evaluate the estimation precision of the parameter and establish a general upper bound on the quantum Fisher information. The results indicate that the quantum Fisher information generally can be divided into two parts: one is quadratic in time, while the other oscillates with time. When the eigenvalues of the Hamiltonian do not depend on the parameter, the quadratic term vanishes, and the quantum Fisher information will be bounded in this case. To illustrate the results, we give an example of estimating a parameter of a magnetic field by measuring a spin-21 particle and compare the results for estimating the amplitude and the direction of the magnetic field.
The Heisenberg limit provides a fundamental bound on the achievable estimation precision with a limited number of N resources used (e.g., atoms, photons, etc.). Using entangled quantum states makes it possible to scale the precision with N better than when resources would be used independently. Consequently, the optimal use of all resources involves accumulating them in a single execution of the experiment. Unfortunately, that implies that the most common theoretical tool used to analyze metrological protocols - quantum Fisher information (QFI) - does not allow for a reliable description of this problem, as it becomes operationally meaningful only with multiple repetitions of the experiment. In this thesis, using the formalism of Bayesian estimation and the minimax estimator, I derive asymptotically saturable bounds on the precision of the estimation for the case of noiseless unitary evolution. For the case where the number of resources N is strictly constrained, I show that the final measurement uncertainty is π times larger than would be implied by a naive use of QFI. I also analyze the case where a constraint is imposed only on the average amount of resources, the exact value of which may fluctuate (in which case QFI does not provide any universal bound for precision). In both cases, I study the asymptotic saturability and the rate of convergence of these bounds. In the following part, I analyze the problem of the Heisenberg limit when multiple parameters are measured simultaneously on the same physical system. In particular, I investigate the existence of a gain from measuring all parameters simultaneously compared to distributing the same amount of resources to measure them independently. I focus on two examples - the measurement of multiple phase shifts in a multi-arm interferometer and the measurement of three magnetic field components.
We study in this work the metrology precision of a probe system coupled to an ancillary qubit. Restricting the probe-qubit coupling along only one or two directions is found to be a sufficient criterion for the effective dynamical generator to achieve the Heisenberg limit in precision. Under the criterion, the quantum Fisher information (QFI) about the to-be-estimated parameter becomes the expectation value of mean square of the effective generator with respect to the initial state of the composite system. Our criterion is justified in two distinct systems. For a bosonic probe, QFI about the displacement estimation is found to be proportional to the mean excitation number of probe. It renders a counterintuitive result that quantum metrology sensitivity can be enhanced by increasing the temperature of the probe system. For a spin-ensemble probe, QFI about both rotation-phase and magnetic-field estimation exhibit a quadratic dependence on the probe-spin number. It is found that even when the spin-ensemble is prepared as a finite-temperature state, faraway from the so-called resource states, e.g., the squeezed state or the Greenberger-Horne-Zeilinger state, QFI can still manifest a Heisenberg scaling behavior.
A well-studied scenario in quantum parameter estimation theory arises when the parameter to be estimated is imprinted on the initial state by a Hamiltonian of the form $\ensuremath{\theta}G$. For such ``phase-shift Hamiltonians'' it has been shown that one cannot improve the channel quantum Fisher information by adding ancillas and letting the system interact with them. Here we investigate the general case, where the Hamiltonian is not necessarily a phase shift, and show that in this case in general it is possible to increase the quantum channel information and to reach an upper bound. This can be done by adding a term proportional to the derivative of the Hamiltonian, or by subtracting a term from the original Hamiltonian. Neither method makes use of any ancillas, which shows that, for quantum channel estimation with an arbitrary parameter-dependent Hamiltonian, entanglement with an ancillary system is not necessary to reach the best possible sensitivity. By adding an operator to the Hamiltonian we can also modify the time scaling of the channel quantum Fisher information. We illustrate our techniques with nitrogen vacancy center magnetometry and the estimation of the direction of a magnetic field in a given plane using a single spin-1 as probe.
Non-Hermitian quantum metrology, an emerging field at the intersection of quantum estimation and non-Hermitian physics, holds promise for revolutionizing precision measurement. Here, we present a comprehensive investigation of non-Hermitian quantum parameter estimation in the quantum regime, with a special focus on achieving Heisenberg scaling. We introduce a concise expression for the quantum Fisher information (QFI) that applies to general non-Hermitian Hamiltonians, enabling the analysis of estimation precision in these systems. Our findings unveil the remarkable potential of non-Hermitian systems to attain the Heisenberg scaling of 1/ t , where t represents time. Moreover, we derive optimal measurement conditions based on the proposed QFI expression, demonstrating the attainment of the quantum Cramér-Rao bound. By constructing non-unitary evolutions governed by two non-Hermitian Hamiltonians, one with parity-time symmetry and the other without specific symmetries, we experimentally validate our theoretical analysis. The experimental results affirm the realization of Heisenberg scaling in estimation precision, marking a substantial milestone in non-Hermitian quantum metrology.
Abstract Quantum metrology has been studied for a wide range of systems with time-independent Hamiltonians. For systems with time-dependent Hamiltonians, however, due to the complexity of dynamics, little has been known about quantum metrology. Here we investigate quantum metrology with time-dependent Hamiltonians to bridge this gap. We obtain the optimal quantum Fisher information for parameters in time-dependent Hamiltonians, and show proper Hamiltonian control is generally necessary to optimize the Fisher information. We derive the optimal Hamiltonian control, which is generally adaptive, and the measurement scheme to attain the optimal Fisher information. In a minimal example of a qubit in a rotating magnetic field, we find a surprising result that the fundamental limit of T2 time scaling of quantum Fisher information can be broken with time-dependent Hamiltonians, which reaches T4 in estimating the rotation frequency of the field. We conclude by considering level crossings in the derivatives of the Hamiltonians, and point out additional control is necessary for that case.
Unitary encoding of a single parameter provides quadratic enhancement in precision, with the quantum Fisher information scaling quadratically with the encoding time. However, when estimating multiple parameters simultaneously, this fundamental scaling is not guaranteed. Here, we establish a universal geometric obstruction that dictates when multiparameter quantum metrology fails to achieve simultaneous t−2 scaling. By decomposing the Hamiltonian derivatives into components that commute and do not commute with the system Hamiltonian, we prove that linear dependence among the commuting components inevitably generates a slow parameter direction whose Fisher information remains bounded as O(t0), limiting the overall estimation precision. We demonstrate this mechanism in both discrete- and continuous-variable setups, including collective spin magnetometry and a generalized quantum harmonic oscillator, and contrast it with the Lipkin--Meshkov--Glick model where t−2 decay is preserved. Remarkably, while the slow direction fundamentally limits the achievable precision, the measurement incompatibility between fast and slow directions decays as 1/t, rendering the symmetric logarithmic derivative bound asymptotically saturable. Our framework provides a readily computable diagnostic, given by the Gram matrix of the diagonal generators, for identifying such obstructions in arbitrary multiparameter estimation problems. We further show that the bottleneck can be circumvented by relegating slow directions to nuisance parameters or by employing adaptive quantum control.