Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2401.07833

The role of initial coherence in the phase-space entropy production rate

Giorgio Zicari, Barış Çakmak, Mauro Paternostro

Published Jan 15, 2024• 0 citations
arXivHTMLPDF

Abstract

The second law of thermodynamics can be expressed in terms of entropy production, which can be used to quantify the degree of irreversibility of a process. In this Chapter, we consider the standard scenario of open quantum systems, where a system irreversibly interacts with an external environment. We show that the standard approach, based on von Neumann entropy, can be replaced by a phase-space formulation of the problem. In particular, we focus on spin systems that can be described using the so-called spin coherent states. We deploy this formalism to study the interplay between the entropy production rate and the initial quantum coherence available to the system.

DOI
10.48550/arxiv.2401.07833

Related papers

On the role of initial coherence in the spin phase-space entropy production rate

Giorgio Zicari, Barış Çakmak, Özgür Esat Müstecaplıoğlu +1 more

Abstract Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance—such as work, heat and entropy production—on the amount of quantum coherences that is made available to a system. However, whether coherences hinder or enhance the value taken by such quantifiers of thermodynamic performance is yet to be ascertained. We show that, when considering entropy production generated in a process taking a finite-size bipartite quantum system out of equilibrium through local non-unitary channels, no general monotonicity relationship exists between the entropy production and degree of quantum coherence in the state of the system. A direct correspondence between such quantities can be retrieved when considering specific forms of open-system dynamics applied to suitably chosen initial states. Our results call for a systematic study of the role of genuine quantum features in the non-equilibrium thermodynamics of quantum processes.

arXiv:2207.05627•New Journal of Physics•Jan 1, 2023•7 citations

Spin-phase-space-entropy production

Jader P. Santos, Lucas C. Céleri, Frederico Brito +2 more

Quantifying the degree of irreversibility of an open system dynamics represents a problem of both fundamental and applied relevance. Even though a well-known framework exists for thermal baths, the results give diverging results in the limit of zero temperature and are also not readily extended to nonequilibrium reservoirs, such as dephasing baths. Aimed at filling this gap, in this paper we introduce a phase-space-entropy production framework for quantifying the irreversibility of spin systems undergoing Lindblad dynamics. The theory is based on the spin Husimi-Q function and its corresponding phase-space entropy, known as Wehrl entropy. Unlike the von Neumann entropy production rate, we show that in our framework, the Wehrl entropy production rate remains valid at any temperature and is also readily extended to arbitrary nonequilibrium baths. As an application, we discuss the irreversibility associated with the interaction of a two-level system with a single-photon pulse, a problem which cannot be treated using the conventional approach.

arXiv:1806.04463•Physical Review A•May 22, 2018•25 citations

The role of quantum coherence in non-equilibrium entropy production

Jader P. Santos, Lucas C. Céleri, Gabriel Teixeira Landi +1 more

Abstract Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. This allows us to identify a genuine quantum contribution to the entropy production in non-equilibrium quantum processes. We discuss how these features emerge both in Lindblad-Davies differential maps and finite maps subject to the constraints of thermal operations. We also show how this separation naturally leads to two independent entropic conservation laws for the global system-environment dynamics, one referring to the redistribution of populations between system and environment and the other describing how the coherence initially present in the system is distributed into local coherences in the environment and non-local coherences in the system-environment state. Finally, we discuss how the processing of quantum coherences and the incompatibility of non-commuting measurements leads to fundamental limitations in the description of quantum trajectories and fluctuation theorems.

arXiv:1707.08946•npj Quantum Information•Mar 1, 2019•185 citations

Assessing the role of initial correlations in the entropy production rate for nonequilibrium harmonic dynamics

Giorgio Zicari, Matteo Brunelli, Mauro Paternostro

Entropy production provides a general way to state the second law of thermodynamics for nonequilibrium scenarios.In open quantum system dynamics, it also serves as a useful quantifier of the degree of irreversibility.In this work we shed light on the relation between correlations, initial preparation of the system, and non-Markovianity by studying a system of two harmonic oscillators independently interacting with their local baths.Their dynamics, described by a time-local master equation, is solved to show, both numerically and analytically, that the global purity of the initial state of the system influences the behavior of the entropy production rate and that the latter depends algebraically on the entanglement that characterizes the initial state.

arXiv:2004.10726•Physical Review Research•Oct 1, 2020•13 citations

Entropy production in continuously measured Gaussian quantum systems

Alessio Belenchia, Luca Mancino, Gabriel Teixeira Landi +1 more

Abstract The entropy production rate is a key quantity in nonequilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress toward its full grasping. By using a phase space-based approach, here we take the current framework for the assessment of thermodynamic irreversibility all the way to quantum regimes by characterizing entropy production—and its rate—resulting from the continuous monitoring of a Gaussian system. This allows us to formulate a sharpened second law of thermodynamics that accounts for the measurement back action and information gain from a continuously monitored system. We illustrate our framework in a series of physically relevant examples.

arXiv:1908.09382•npj Quantum Information•Dec 4, 2020•39 citations

Thermodynamics Beyond Equilibrium in Coherent Quantum Systems

Md Manirul Ali, Po-Wen Chen

A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.

quant-pharXiv:2602.09074•APL Quantum•Feb 10, 2026•0 citations
The second law of thermodynamics can be expressed in terms of entropy production, which can be used to quantify the degree of irreversibility of a process. In this Chapter, we consider the standard scenario of open quantum systems, where a system irreversibly interacts with an external environment. We show that the standard approach, based on von Neumann entropy, can be replaced by a phase-space formulation of the problem. In particular, we focus on spin systems that can be described using the so-called spin coherent states. We deploy this formalism to study the interplay between the entropy production rate and the initial quantum coherence available to the system.
Abstract Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance—such as work, heat and entropy production—on the amount of quantum coherences that is made available to a system. However, whether coherences hinder or enhance the value taken by such quantifiers of thermodynamic performance is yet to be ascertained. We show that, when considering entropy production generated in a process taking a finite-size bipartite quantum system out of equilibrium through local non-unitary channels, no general monotonicity relationship exists between the entropy production and degree of quantum coherence in the state of the system. A direct correspondence between such quantities can be retrieved when considering specific forms of open-system dynamics applied to suitably chosen initial states. Our results call for a systematic study of the role of genuine quantum features in the non-equilibrium thermodynamics of quantum processes.
Quantifying the degree of irreversibility of an open system dynamics represents a problem of both fundamental and applied relevance. Even though a well-known framework exists for thermal baths, the results give diverging results in the limit of zero temperature and are also not readily extended to nonequilibrium reservoirs, such as dephasing baths. Aimed at filling this gap, in this paper we introduce a phase-space-entropy production framework for quantifying the irreversibility of spin systems undergoing Lindblad dynamics. The theory is based on the spin Husimi-Q function and its corresponding phase-space entropy, known as Wehrl entropy. Unlike the von Neumann entropy production rate, we show that in our framework, the Wehrl entropy production rate remains valid at any temperature and is also readily extended to arbitrary nonequilibrium baths. As an application, we discuss the irreversibility associated with the interaction of a two-level system with a single-photon pulse, a problem which cannot be treated using the conventional approach.
Abstract Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. This allows us to identify a genuine quantum contribution to the entropy production in non-equilibrium quantum processes. We discuss how these features emerge both in Lindblad-Davies differential maps and finite maps subject to the constraints of thermal operations. We also show how this separation naturally leads to two independent entropic conservation laws for the global system-environment dynamics, one referring to the redistribution of populations between system and environment and the other describing how the coherence initially present in the system is distributed into local coherences in the environment and non-local coherences in the system-environment state. Finally, we discuss how the processing of quantum coherences and the incompatibility of non-commuting measurements leads to fundamental limitations in the description of quantum trajectories and fluctuation theorems.
Entropy production provides a general way to state the second law of thermodynamics for nonequilibrium scenarios.In open quantum system dynamics, it also serves as a useful quantifier of the degree of irreversibility.In this work we shed light on the relation between correlations, initial preparation of the system, and non-Markovianity by studying a system of two harmonic oscillators independently interacting with their local baths.Their dynamics, described by a time-local master equation, is solved to show, both numerically and analytically, that the global purity of the initial state of the system influences the behavior of the entropy production rate and that the latter depends algebraically on the entanglement that characterizes the initial state.
Abstract The entropy production rate is a key quantity in nonequilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress toward its full grasping. By using a phase space-based approach, here we take the current framework for the assessment of thermodynamic irreversibility all the way to quantum regimes by characterizing entropy production—and its rate—resulting from the continuous monitoring of a Gaussian system. This allows us to formulate a sharpened second law of thermodynamics that accounts for the measurement back action and information gain from a continuously monitored system. We illustrate our framework in a series of physically relevant examples.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.