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arXiv:2004.10726 · Physical Review Research

Assessing the role of initial correlations in the entropy production rate for nonequilibrium harmonic dynamics

Giorgio Zicari, Matteo Brunelli, Mauro Paternostro

Published Oct 1, 2020• 13 citations
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Abstract

Entropy production provides a general way to state the second law of thermodynamics for nonequilibrium scenarios.In open quantum system dynamics, it also serves as a useful quantifier of the degree of irreversibility.In this work we shed light on the relation between correlations, initial preparation of the system, and non-Markovianity by studying a system of two harmonic oscillators independently interacting with their local baths.Their dynamics, described by a time-local master equation, is solved to show, both numerically and analytically, that the global purity of the initial state of the system influences the behavior of the entropy production rate and that the latter depends algebraically on the entanglement that characterizes the initial state.

DOI
10.1103/physrevresearch.2.043006

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Entropy production provides a general way to state the second law of thermodynamics for nonequilibrium scenarios.In open quantum system dynamics, it also serves as a useful quantifier of the degree of irreversibility.In this work we shed light on the relation between correlations, initial preparation of the system, and non-Markovianity by studying a system of two harmonic oscillators independently interacting with their local baths.Their dynamics, described by a time-local master equation, is solved to show, both numerically and analytically, that the global purity of the initial state of the system influences the behavior of the entropy production rate and that the latter depends algebraically on the entanglement that characterizes the initial state.
Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovianity. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovianity and when it does not. For a system coupled to a single heat bath, this can be established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a Markovian master equation and (ii) the classical Hamiltonian dynamics of a system coupled to a bath. The quantum version of the latter result is shown not to hold despite the fact that the integrated thermodynamic description is formally equivalent to the classical case. The instantaneous fixed point of a non-Markovian dynamics plays an important role in our study. Our key contribution is to provide a consistent theoretical framework to study the finite-time thermodynamics of a large class of dynamics with a precise link to its non-Markovianity.
We discuss fundamental features of the local expression for the entropy production rate of the nonequilibrium quantum dynamics of open systems and its relations to memory effects and the spectrum of the generator of the dynamics. Defining the entropy production rate as negative rate of change of the relative entropy with respect to an instantaneous fixed point, it is shown that positivity of the entropy production rate for all possible initial states implies that the real parts of the eigenvalues of the time-local generator for the quantum master equation are always negative. It is further demonstrated that Markovian dynamics, identified as P-divisibility of the quantum dynamical map, implies positivity of entropy production rate, thus providing a kind of generalized second law in the nonequilibrium regime. We also prove by means of the counterexample of a phase covariant quantum master equation that the converse of this statement is not true, i.e., there are non-Markovian dynamics for which the entropy production rate is always positive. Thus, we conclude that the emergence of negative entropy production rates is a sufficient but not necessary condition for non-Markovianity of the quantum dynamics. Finally, we also consider a recently introduced map-based notion of entropy production and show the equivalence between its positivity and Markovianity for general finite-dimensional systems.
We investigate a total thermodynamic entropy production rate of an isolated quantum system. In particular, we consider a quantum model of coupled harmonic oscillators in a star configuration, where a central harmonic oscillator (system) is coupled to a finite number of surrounding harmonic oscillators (bath). In this model, when the initial state of the total system is given by the tensor product of the Gibbs states of the system and the bath, every harmonic oscillator is always in a Gibbs state with a time-dependent temperature. This enables us to define time-dependent thermo-dynamic entropy for each harmonic oscillator and total non-equilibrium thermodynamic entropy as the summation of them. We analytically confirm that the total thermodynamic entropy satisfies the third law of thermodynamics. Our numerical solutions show that, even when the dynamics of the system is well approximated by the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL)-type Markovian master equation, the total thermodynamic entropy production rate can be negative, while the total thermodynamic entropy satisfies the second law of thermodynamics. This result is a counterexample to the common belief that the total entropy production rate is non-negative when the system is under the GKSL-type Markovian dynamics.
The second law of thermodynamics can be expressed in terms of entropy production, which can be used to quantify the degree of irreversibility of a process. In this Chapter, we consider the standard scenario of open quantum systems, where a system irreversibly interacts with an external environment. We show that the standard approach, based on von Neumann entropy, can be replaced by a phase-space formulation of the problem. In particular, we focus on spin systems that can be described using the so-called spin coherent states. We deploy this formalism to study the interplay between the entropy production rate and the initial quantum coherence available to the system.
We investigate a total thermodynamic entropy production rate of an isolated quantum system. In particular, we consider a quantum model of coupled harmonic oscillators in a star configuration, where a central harmonic oscillator (system) is coupled to a finite number of surrounding harmonic oscillators (bath). In this model, when the initial state of the total system is given by the tensor product of the Gibbs states of the system and the bath, every harmonic oscillator is always in a Gibbs state with a time-dependent temperature. This enables us to define time-dependent thermodynamic entropy for each harmonic oscillator and total nonequilibrium thermodynamic entropy as the summation of them. We analytically confirm that the total thermodynamic entropy satisfies the third law of thermodynamics. Our numerical solutions show that, even when the dynamics of the system is well approximated by the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL)-type Markovian master equation, the total thermodynamic entropy production rate can be negative, while the total thermodynamic entropy satisfies the second law of thermodynamics. This result is a counterexample to the common belief that the total entropy production rate is non-negative when the system is under the GKSL-type Markovian dynamics.
The thermodynamics of a qubit undergoing dephasing due to the coupling with the external environment is discussed. First of all, we assume the dynamics of the system to be described by a master equation in Lindblad form. In this framework, we review a standard formulation of the first and second law of thermodynamics that has been known in literature for a long time. After that, we explicitly model the environment with a set of quantum harmonic oscillators choosing the interaction such that the global dynamics of system and bath is analytically solvable and the Lindblad master equation is recovered in the weak-coupling limit. In this generalized setting, we can show that the correlations between system and bath play a fundamental role in the heat exchange. Moreover, the internal entropy production of the qubit is proven to be positive for arbitrary coupling strength.