In this habilitation thesis, I briefly present my work at Imperial College London on trapping atomic clouds in micro-pyramids fabricated on silicon chips, which led to the fabrication of an on-chip integrated atom source. Next, I describe the research carried out at the Laboratoire de Physique des Lasers in the SAI group. Our experiments demonstrated the temperature dependence of near-field Casimir-Polder interactions due to thermal excitation of surface waves, thus advancing our understanding of the dielectric properties of matter and the quantum vacuum that surrounds it. I also present spectroscopic experiments with atomic vapors confined in nanostructures (nano-sphere opals) aiming at the fabrication of miniature frequency references. Finally, I explore the possibility of performing spectroscopic experiments on molecular gases close to surfaces.
In this habilitation thesis, I briefly present my work at Imperial College London on trapping atomic clouds in micro-pyramids fabricated on silicon chips, which led to the fabrication of an on-chip integrated atom source. Next, I describe the research carried out at the Laboratoire de Physique des Lasers in the SAI group. Our experiments demonstrated the temperature dependence of near-field Casimir-Polder interactions due to thermal excitation of surface waves, thus advancing our understanding of the dielectric properties of matter and the quantum vacuum that surrounds it. I also present spectroscopic experiments with atomic vapors confined in nanostructures (nano-sphere opals) aiming at the fabrication of miniature frequency references. Finally, I explore the possibility of performing spectroscopic experiments on molecular gases close to surfaces.
Selective reflection spectroscopy at normal incidence provides signals with sub-Doppler resolution, linear with optical intensity. Frequency modulated (FM) selective reflection probes atomic vapours at distances comparable to the excitation wavelength (~λ/2π) and is used extensively to probe the Casimir-Polder interactions between an excited state atom and a macroscopic surface. Extending selective reflection spectroscopy to molecular gases allows probing a thin layer of molecular gas next to a surface. This is a very attractive prospect that allows envisaging high-resolution molecular spectroscopy and molecular frequency references in a compact and miniaturised apparatus, such as a thin cell [1] or a photonic crystal [2]. Additionally, it paves the way for spectroscopic probing of the Casimir-Polder interaction with molecules. The molecule-surface interaction has been the object of extensive theoretical investigations, focusing on the effects of molecular orientation and chirality. However, experimental tests are few and comparison with theoretical predictions has been challenging [3].
The entry into the new millennium was marked in the quantum community by the first experimental realizations of the Bose-Einstein condensation of atoms in a vapor, achieved in different research groups. Twenty-five years later, such systems are 'routinely' produced and are the core of many experiments. At the frontier between condensed matter their y, quantum optics, and atomic physics, ultra-cold atoms are subjects of high scientific interest.Ultra-cold gas can be trapped in optical lattices, giving a realistic way of experimentally realizing a new range of lattice Hamiltonians, that are used to simulate condensed matter systems. In these simulations, ultra-cold atoms are used to mimic the behavior of electrons in a solid-state material and could be used to simulate a wide range of complex condensed matter phenomena, such as the fractional quantum Hall effect, topological insulators, and high-temperature superconductivity.In order to study such systems, diffraction-limited quantum gas microscopes have emerged as a way to manipulate and detect atoms trapped in lattice potentials. Using far-field interference, experiments have mainly been restricted to a lattice spacing of 500 nm. This limits the speed of dynamics of all physical processes.Higher energy regimes could be accessed by reducing the lattice spacing. For this purpose, one of the long-term goals of the team is to trap atoms in the near-field of a surface and to make use of the Casimir-Polder forces to shape sub-wavelength potentials. Thanks to nano-fabrication capabilities, the spacing can be reduced to a few tens of nanometers. However, this requires to adapt the imaging techniques to observe cold-atoms with sub-wavelength spatial resolutions.In this PhD thesis, I report first on the advances toward implementing an atom chip in our experiment, which will serve as an integrated platform to manipulate the quantum gas. I present simulations and study an experimental solution allowing the cloud to be transported to the near-field. The method is based on the interference of a laser radiation in the near field of a rotating surface. It has been fully simulated, and the limitations have been numerically and experimentally assessed. I conclude this part by presenting the first model of chip that has been fabricated.In a second part, I report on the development of a sub-wavelength imaging method of cold Rubidium 87 atoms which is based on excited state dressing. I detail the concept of this nano-metric spatial resolution method and apply it to super-resolve a single longitudinal wave function trapped in a tight lattice that exhibits a width below 30 nm.
Over the past ten years, our group has investigated the effects of confinement on atoms inside metallic micron–sized cavities in order to elucidate some basic phenomena in the field of cavity quantum electrodynamics (QED). The first of these was the inhibition of spontaneous emission from an atom inside a cavity. This was followed by a laser spectroscopic measurement of the van der Waals interaction between a single Rydberg atom and a gold cavity, which showed that a simple electrostatic model of the atom–cavity interaction is correct when the cavity is small enough. More recently, the retarded Casimir–Polder force was measured between a ground state sodium atom and a large cavity, demonstrating that the van der Waals potential fails at long enough range and that the vacuum fluctuations of the field then have an important role in the interaction of the atom with the cavity. Our group is now pushing forward these investigations to study cavities whose walls have losses and dispersion, where the theory of cavity QED is significantly more complicated. With real surfaces, we have to deal with the complex dielectric response ε(ω) of the material, which exhibits frequency–dependent absorption and dispersion. One particularly interesting case is when a downward transition in the atom is resonant with an excitation of the cavity walls. This opens a new branch for the atomic decay: as an alternative to creating a photon within the space surrounded by the cavity walls the atomic decay can now create an electromagnetic excitation of the walls themselves. Another novel feature of our experiments is that the Bohr frequencies of the atom are close to the kT/h, where T is room temperature. We therefore expect to be able to measure effects associated with QED at finite temperature; in other words, to study how the blackbody radiation affects our experiments. By conducting experiments with real surfaces, we hope to elucidate and perhaps simplify the theoretical models used to describe these systems.
Highly excited (Rydberg) atoms have exaggerated properties making them extremely sensitive to external electromagnetic fields and interacting strongly with their environment. Atomic vapor cells represent an attractive platform for studying Rydberg atoms and fabricating quantum devices. For example, Rydberg atoms in vapor cells have been used as sensitive detectors of electric fields of frequencies ranging from DC up to the THz range but also as single photon sources for quantum technology applications exploiting collective phenomena due to the Rydberg blockade effect [1]. Rydberg atoms also find applications in fundamental physics, in particular for the measurement of dispersive interactions of the Casimir-Polder type (atom-surface interactions) [2]. One major advantage of Rydberg atoms is that they expose limitations in the traditional perturbative approach of Casimir-Polder (CP) theory [3, 4]. Indeed, in the extreme near-field, the dipole approximation breaks down and higher-order terms need to be considered. We report on extensive experimental measurements of the Rydberg-surface interaction using spectroscopy in cesium vapor nanocells of a thickness ranging roughly from 200-700nm, as well as selective reflection spectroscopy on a macroscopic cesium all-sapphire cell. Atoms are first excited to the Cs(6P) level with a 894nm pump laser and subsequently a green laser ≈ 510nm probes Rydberg nD or nS states, where the principal quantum number n ranges between 15-17. Our experiments evidence the dipole-dipole term of the Casimir-Polder interaction providing a measurement of the C3 coefficient for cesium Rydberg states. Furthermore, our experiment clearly evidences an additional interaction that induces shifts and broadens the linewidth of the probed transitions in the vicinity of the dielectric windows of our cells. We believe that this interaction is due to electric fields that are either generated by patch charges (trapped on the surface or induced by the excitation lasers), or by cesium adsorbants. We show that the different polarizability (of opposing sign) between S and D Rydberg states can be exploited to extract quantitative measurements of the strength and distance scaling (z-dependence) of such parasitic electrostatic interactions.Our experiments suggest that the sensitivity of Rydberg atoms to external electric fields could provide a unique tool for probing electrostatic interactions in the vicinity of surfaces. This could allow systematic error corrections in Casimir-Polder experiments with excited or even ground state atoms that aim at putting bounds on the existence of non-Newtonian gravity [5]. We are currently exploring the possibility of coating the internal window interfaces with conducting 2D material such as graphene to reduce the influence of parasitic charges. This could allow us to probe atoms closer to the surface, where quadrupole interactions could be experimentally attainable for the first time [4].References[1] H. Kubler, J. P. Shaffer, T. Baluktsian, R. Loew, T. Pfau, Nat. Photon., 4, 112–116 (2013).[2] V. Sandoghdar et al., Phys. Rev. Lett 68, 3432–3435 (1993).[3] J. A. Crosse et al., Phys. Rev. A 82, 3010901 (2010).[4] B. Dutta et al., Phys. Rev. Res. 6, L022035 (2024).[5] A. Laliotis, B-S. Lu, M. Ducloy, D. Wilkowski, AVS Quantum Sci. 3, 043501 (2021).
We review the current status of the field of atom-surface interactions, with an emphasis on the regimes specific to atom chips. Recent developments in theory and experiment are highlighted. In particular, atom-surface interactions define physical limits for miniaturization and coherent operation. This implies constraints for applications in quantum information processing or matter wave interferometry. We focus on atom-surface interaction potentials induced by vacuum fluctuations (Van der Waals and Casimir-Polder forces), and on transitions between atomic quantum states that are induced by thermally excited magnetic near fields. Open questions and current challenges are sketched.