Abstract We propose a scheme to measure a nuclear magnetic quadrupole moment (MQM), a C P -violating electromagnetic moment that appears in the nuclear sector, using the long-lived 3 P 2 metastable state in neutral 173Yb atoms. Laser-cooling and trapping techniques enable us to prepare ultracold 173Yb atoms in the 3 P 2 state trapped in an optical lattice or an optical tweezer array, providing an ideal experimental platform with long spin coherence time. In addition, our relativistic configuration interaction calculation for the 3 P 2 electronic wavefunction reveals a large magnetic field gradient generated by the atomic electrons in this state, which amplifies the measurable effect of an MQM. Our scheme could lead to an improvement of more than one order of magnitude in MQM sensitivity compared to the best previous measurement (Murthy e t a l 1989 Phys. Rev. Lett. 63, 965).
Abstract We propose a scheme to measure a nuclear magnetic quadrupole moment (MQM), a C P -violating electromagnetic moment that appears in the nuclear sector, using the long-lived 3 P 2 metastable state in neutral 173Yb atoms. Laser-cooling and trapping techniques enable us to prepare ultracold 173Yb atoms in the 3 P 2 state trapped in an optical lattice or an optical tweezer array, providing an ideal experimental platform with long spin coherence time. In addition, our relativistic configuration interaction calculation for the 3 P 2 electronic wavefunction reveals a large magnetic field gradient generated by the atomic electrons in this state, which amplifies the measurable effect of an MQM. Our scheme could lead to an improvement of more than one order of magnitude in MQM sensitivity compared to the best previous measurement (Murthy e t a l 1989 Phys. Rev. Lett. 63, 965).
Abstract Improved nuclear spin-dependent parity violation measurements will enable experimental determination of poorly known electroweak coupling parameters. Here, we investigate the suitability of optically trapped linear polyatomic molecules as probes of nuclear spin-dependent parity violation. The presence of closely spaced, opposite-parity ℓ ℓ -doublets is a general feature of such molecules, allowing parity-violation-sensitive pairs of levels to be brought to degeneracy in magnetic fields typically 100 times smaller than in diatomics. Assuming laser cooling and trapping of polyatomics at the current state-of-the-art for diatomics, we expect to measure nuclear spin-dependent parity-violating matrix elements iW with 70 times better sensitivity than the current best measurements. Our scheme should allow for 10% measurements of iW in nuclei as light as Be or as heavy as Yb, with averaging times on the order of 10 days and 1 s, respectively.
Cold heavy molecules are promising systems for exploring nuclear P- and CP-violating phenomena in search of new physics beyond the Standard Model. However, most proposed experimental strategies and their early realizations to date have been limited to proof-of-principle molecular species with effectively spin-zero nuclei that are not sensitive to nuclear symmetry-violating phenomena. Here, we introduce a comprehensive experimental toolbox that integrates cooling, trapping, coherent state manipulation, and a complete precision-measurement protocol that is applicable to molecules carrying relevant nuclear spins. Using 137Ba19F and nuclear-spin-dependent parity violation (NSD-PV) as representative species and benchmark application, respectively, our approach achieves a projected statistical sensitivity roughly two orders of magnitude beyond comparable molecular beams by combining techniques already demonstrated individually in current experiments. This level of precision could provide realistic experimental access not only to the enhanced NSD-PV signals arising from the heavy 137Ba nucleus within this molecule but also to the contributions from the lighter 19F nucleus, bringing direct benchmarks of nuclear \textit{ab initio} theory within reach. We further identify a candidate magic wavelength as a route to second-scale rotational coherence in future experiments. The techniques developed here can be transferred to measurements of nuclear Schiff and magnetic quadrupole moments in molecules containing deformed nuclei, establishing a general platform for laboratory searches for nuclear symmetry violations.
We report on the realization of a fast, scalable, and high-fidelity qubit architecture, based on 171 Yb atoms in an optical tweezer array.We demonstrate several attractive properties of this atom for its use as a building block of a quantum information processing platform.Its nuclear spin of 1=2 serves as a long-lived and coherent two-level system, while its rich, alkaline-earth-like electronic structure allows for low-entropy preparation, fast qubit control, and high-fidelity readout.We present a near-deterministic loading protocol, which allows us to fill a 10 × 10 tweezer array with 92.73(8)% efficiency and a single tweezer with 96.0(1.4)%efficiency.In the future, this loading protocol will enable efficient and uniform loading of target arrays with high probability, an essential step in quantum simulation and information applications.Employing a robust optical approach, we perform submicrosecond qubit rotations and characterize their fidelity through randomized benchmarking, yielding 5.2ð5Þ × 10 -3 error per Clifford gate.For quantum memory applications, we measure the coherence of our qubits with T Ã 2 ¼ 3.7ð4Þ s and T 2 ¼ 7.9ð4Þ s, many orders of magnitude longer than our qubit rotation pulses.We measure spin depolarization times on the order of tens of seconds and find that this can be increased to the 100 s scale through the application of a several-gauss magnetic field.Finally, we use 3D Raman-sideband cooling to bring the atoms near their motional ground state, which will be central to future implementations of two-qubit gates that benefit from low motional entropy.
Probing P,T-Symmetry Violation with Optically Trapped Asymmetric Top Molecules
Searches for P,T-violating electromagnetic moments are among the most sensitive probes of physics beyond the Standard Model. Extending beyond current limits will benefit from molecules with fully controllable orientation at low electric fields, long coherence times, and laser coolability---all offered by asymmetric top molecules (ATMs). Exploiting the intrinsic rotational K-doubling in ATMs and the associated long-lived (T1≳10 s) parity doublets afforded by C2v symmetry and nuclear-spin statistics, these species combine large electric polarizability with long coherence times in modest laboratory fields. We study alkaline-earth(-like) monoamides, M--NH2 (M = Ca, Sr, Ba, Yb, Ra), which possess favorable electronic structure for laser cooling. We perform \textit{ab initio} calculations of fine and hyperfine constants, identifying the importance of relativistic effects in the spin-rotation tensor. An effective Hamiltonian then models the rotational and hyperfine structure of the vibronic ground state, quantifying electron electric dipole moment (EDM) sensitivities and identifying feasible measurement schemes. We compute the effect of external fields and identify engineered clock transitions that suppress sensitivity to external perturbations while retaining strong EDM sensitivity, and characterize the magic trapping conditions that null differential light shifts in an optical trap. Under these conditions we project a statistical electron-EDM sensitivity over an order of magnitude beyond current best experimental limits, with further gains available from increased molecule number and coherence time. Our results establish asymmetric top molecules as a tunable platform for sensitive symmetry-violation measurements with long coherence times.
Recently, alkaline-earth (-like) atoms and alkaline earth metals (AEL) gained experimental and theoretical interest principally related to the possibility offered in metrological field by the excitation of visible and UV clock transitions. AEL atoms, in their neutral \nform and in the ground state, have a null total electronic momentum, resulting nearly insensitive to external magnetic fields. While the absence of magnetic coupling does not allow the simply interactions tuning by exploiting Feshbach resonances as it occurs \nin alkaline atoms, these atoms are characterized by highly symmetric ground states allowing the simulation of SU(N) systems. This characteristic, that can be attributed in AEL atoms to the decoupling between electronic and nuclear atomic momenta, can be \nexploited to perform quantum simulation of a wealth of novel systems and constitutes a fundamental property of isotopes that have a nonzero nuclear spin, as it occurs for all the fermionic species and in particular for 173Yb and 87Sr. This feature also ensures the \nabsence of spin-changing collisions in ground state sublevels, implying that nuclear-spin mixtures are observationally stable. This attribute is fundamental for the study of transitions between different nuclear-spin states, for example by exploiting the two-photon \nRaman coupling. The degeneracy related to the SU(N) symmetry can be controllably removed by applying a two-photon Raman coupling, allowing for the simulation of systems with broken symmetries. \nBesides the possibility to induce couplings within the nuclear-spin degree of freedom, AEL atoms also offer the possibility to access a second, electronic degree of freedom; the possibility to address visible doubly-forbidden transitions between long-lived electronic \nclock states comprises a fantastic tool that allowed the building of optical lattice clocks improving metrological measurements and offering a richer platform for simulating complex systems. \nThe main difference between the two internal degrees of freedom offered by AEL atoms is that the possibility to address ultranarrow optical clock transitions exists also for AEL bosonic isotopes in which the nuclear-spin degree of freedom is not present because the \ntotal atomic momentum is absent. \nThe possibilities related to the excitation of long-lived metastable triplet levels, that, referring only to the lowest lying atomic levels are 3P(0;2) (in Russell-Saunders approximation they result doubly forbidden with respect to the electric dipole operator), are \nmultiple. If bosonic atoms are considered, the metrological applications based on the clock transition at the state of the art have performances comparable to optical lattice clocks realized with fermionic isotopes. Bosonic isotopes, requiring external fields in order \nto excite transitions from the ground state to long-lived states, have been proposed as good candidates in order to build a reliable and fast system in which controllable qu-bits could be realized. Most of these applications, and in particular the possibility to create \nquantum computers with neutral atoms, crucially rely on the control of the scattering properties of atoms in different electronic states. \nRegarding fermionic isotopes, the clock transitions recently allowed for the demonstration of spin-orbit coupling and quantum simulation via the synthetic dimension approach. As recently discovered, the clock transitions from the ground to the 3P(0;2) states give rise to rich interactions possibilities between atoms in the fundamental and in the metastable states. The spin-exchange interaction that has been observed between ground and metastable states, supports also a new kind of Feshbach resonance, called Orbital Feshbach Resonance (OrbFR). As occurs in magnetic Feshbach resonances for alkali atoms, also the OrbFR, that occurs in AEL atoms, supports the existence of extremely shallow homonuclear molecules. After considering the (s-wave) scattering parameters of all the AEL atoms that have been characterized experimentally, 173Yb is the only isotope in which the production and manipulation of Orbital Feshbach molecules (produced e.g. with photoassociation) is experimentally viable. Molecules generated by employing this atom, may lead to the investigation of fermionic superfluidity in still-unexplored regimes. In this thesis we report the characterization of interactions in bosonic 174Yb isotope by probing the clock transition between the singlet 1S0 ground state and the triplet 3P0 \nmetastable excited state. Interactions and inelastic losses between ground-state and excited metastable-state atoms have been experimentally determined with high accuracy, resulting consistent with an indipendent evaluation realized in the same period by Yb \nBEC group at LKB. \nThe obtained values for the interactions among ground and metastable atoms for the specified isotope constitute a first step in order to design an experimental system in which quantum information can be realized by means of exploiting the clock transition of bosonic Yb atoms. \nThis work, by exploiting the internal degrees of freedom of 173Yb atoms, reports a study on Orbital Feshbach molecules, showing experimentally the possibility to employ the nuclear degree of freedom in 173Yb atoms to manipulate and precisely detect homo-nuclear photoassociated molecules. \nThis first result regarding this new kind of shallow-bound molecules allowed the characterization of interactions between ground-state and metastable-state of 173Yb atoms. \nThis first intensive study of orbital Feshbach molecules is a fundamental step for future studies on the possibilities offered by these homo-nuclear molecules. \nFinally, we exploited the ground state SU(N) symmetry and its controlled breaking via Raman coupling (in 173Yb N = 1...6) to simulate the physical processes that are supposed to be driven by the hybridation of d-orbitals of iron atoms in iron based-superconductors, \nin which orbital-selective Mott insulating phases have been experimentally observed and are suspected to be the fundamental ingredient to achieve high-temperature superconductivity in these compounds.
Abstract We report on the trapping and imaging of individual ytterbium atoms in arrays of optical tweezers, loaded from a magneto-optical trap (MOT) formed by only five beams in an orthogonal configuration. In our five-beam MOT, operating on the narrow 1 S 0 → 3 P 1 intercombination transition, gravity balances the radiation pressure of a single upward-directed beam. This approach enables efficient trapping and cooling of the most common ytterbium isotopes ( 171 Yb, 173 Yb and 174 Yb) to ≲ 20 μ K at densities ∼ 10 11 atoms cm −3 within less than one second. This configuration allows for significantly reducing the complexity of the optical setup, potentially benefiting any ytterbium-atom based quantum science platform leveraging single-atom microscopy, from quantum processors to novel optical clocks. We then demonstrate the first single-atom-resolved imaging of the fermionic, large-spin isotope 173 Yb ( I = 5 / 2 ), employing a two-color imaging scheme that does not rely on magic-wavelength trapping. We achieve a high single-atom imaging fidelity of 99.96 ( 1 ) % and a large survival probability of 98.5 ( 2 ) % , despite large differential light shifts affecting all nuclear spin sublevels of the excited 3 P