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arXiv:2310.14645 · Physical Review A

Temperature-heat uncertainty relation in nonequilibrium quantum thermometry

Ning Zhang, Si‐Yuan Bai, Chong Chen

Published Jul 11, 2024• 5 citations
arXivHTMLPDF

Abstract

We investigate the temperature uncertainty relation in the nonequilibrium probe-based temperature estimation process. We demonstrate that it is the fluctuation of heat that fundamentally determines temperature precision through the temperature-heat uncertainty relation. Specifically, we find that heat is divided into trajectory heat and correlation heat, which are associated with the heat exchange along the thermometer's evolution and the correlation between the thermometer and the sample, respectively. Based on two types of thermometers, we show that both of these heat terms are resources for enhancing temperature precision. By clearly distinguishing the resources for enhancing estimation precision, our findings not only explain why various quantum features are crucial for accurate temperature sensing but also provide valuable insights for designing ultrahigh-sensitive quantum thermometers. Additionally, we demonstrate that the temperature-heat uncertainty relation is consistent with the well-known temperature-energy uncertainty relation in thermodynamics. It establishes a connection between the information theory and the thermodynamics.

DOI
10.1103/physreva.110.012211

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We investigate the temperature uncertainty relation in the nonequilibrium probe-based temperature estimation process. We demonstrate that it is the fluctuation of heat that fundamentally determines temperature precision through the temperature-heat uncertainty relation. Specifically, we find that heat is divided into trajectory heat and correlation heat, which are associated with the heat exchange along the thermometer's evolution and the correlation between the thermometer and the sample, respectively. Based on two types of thermometers, we show that both of these heat terms are resources for enhancing temperature precision. By clearly distinguishing the resources for enhancing estimation precision, our findings not only explain why various quantum features are crucial for accurate temperature sensing but also provide valuable insights for designing ultrahigh-sensitive quantum thermometers. Additionally, we demonstrate that the temperature-heat uncertainty relation is consistent with the well-known temperature-energy uncertainty relation in thermodynamics. It establishes a connection between the information theory and the thermodynamics.
Temperature uncertainty of a quantum system in canonical ensemble is inversely determined by its energy fluctuation, which is known as the temperature-energy uncertainty relation. No such uncertainty relation was discovered for a non-equilibrium open quantum system. In this article, we derive a universal temperature uncertainty relation for general non-equilibrium processes. We find that it is the fluctuation of heat, which is defined as the change in bath energy, determines the temperature uncertainty in non-equilibrium case. Specifically, the heat is divided into trajectory heat and backaction heat, which are associated with the system's trajectory of evolution and the backaction of partial measurement on system, respectively. Based on this decomposition, we reveal that both correlations between system and bath's process function and state function are the resources for enhancing temperature precision. Our findings are conductive to design ultrahigh sensitive quantum thermometer.
Abstract It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions with the environment. Here we include such interactions and, using quantum estimation theory, derive a generalised thermodynamic uncertainty relation valid for classical and quantum systems at all coupling strengths. We show that the non-commutativity between the system’s state and its effective energy operator gives rise to quantum fluctuations that increase the temperature uncertainty. Surprisingly, these additional fluctuations are described by the average Wigner-Yanase-Dyson skew information. We demonstrate that the temperature’s signal-to-noise ratio is constrained by the heat capacity plus a dissipative term arising from the non-negligible interactions. These findings shed light on the interplay between classical and non-classical fluctuations in quantum thermodynamics and will inform the design of optimal nanoscale thermometers.
Quantum thermometry aims to measure temperature in nanoscale quantum systems, paralleling classical thermometry. However, temperature is not a quantum observable, and most theoretical studies have therefore concentrated on analyzing fundamental precision limits set by the quantum Fisher information through the quantum Cramer-Rao bound. In contrast, whether a direct temperature readout can be achieved in quantum thermometry remains largely unexplored, particularly under the nonequilibrium conditions prevalent in real-world applications. To address this, we develop a direct temperature readout scheme based on a thermodynamic inference strategy. The scheme integrates two conceptual developments: (i) By applying the maximum entropy principle with the thermometer's mean energy as a constraint, we assign a reference temperature to the nonequilibrium thermometer. We demonstrate that this reference temperature outperforms a commonly used effective temperature defined through equilibrium analogy. (ii) We obtain positive semi-definite error functions that lower-bound the deviation of the reference temperature from the true temperature-in analogy to the quantum Cramer-Rao bound for the mean squared error-and vanish upon thermalization with the sample. Combining the reference temperature with these error functions, we introduce a notion of corrected dynamical temperature which furnishes a postprocessed temperature readout under nonequilibrium conditions. This corrected dynamical temperature can be evaluated adaptively without prior knowledge of the actual temperature. We validate the corrected dynamical temperature in a qubit-based thermometer under a range of nonequilibrium initial states, confirming its capability to estimate the true temperature. Importantly, we find that increasing quantum coherence can enhance the precision of this readout.
It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions with the environment. Here we include such interactions and, using quantum estimation theory, derive a generalised thermodynamic uncertainty relation valid for classical and quantum systems at all coupling strengths. We show that the non-commutativity between the system's state and its effective energy operator gives rise to quantum fluctuations that increase the temperature uncertainty. Surprisingly, these additional fluctuations are described by the average Wigner-Yanase-Dyson skew information. We demonstrate that the temperature's signal-to-noise ratio is constrained by the heat capacity plus a dissipative term arising from the non-negligible interactions. These findings shed light on the interplay between classical and non-classical fluctuations in quantum thermodynamics and will inform the design of optimal nanoscale thermometers.
We discuss the application of techniques of quantum estimation theory and quantum metrology to thermometry. The ultimate limit to the precision at which the temperature of a system at thermal equilibrium can be determined is related to the heat capacity when global measurements are performed on the system. We prove that if technical or practical limitations restrict our capabilities to local probing, the highest achievable accuracy to temperature estimation reduces to a sort of mesoscopic version of the heat capacity. Adopting a more practical perspective, we also discuss the relevance of qubit systems as optimal quantum thermometers, in order to retrieve the temperature, or to discriminate between two temperatures, characterizing a thermal reservoir. We show that quantum coherence and entanglement in a probe system can facilitate faster, or more accurate measurements of temperature. While not surprising given this has been demonstrated in phase estimation, temperature is not a conventional quantum observable, therefore these results extend the theory of parameter estimation to measurement of non-Hamiltonian quantities. Finally we point out the advantages brought by a less standard estimation technique based on sequential measurements, when applied to quantum thermometry.
In this work we propose a theory of temperature estimation of quantum systems, which is applicable in the regime of non-negligible prior temperature uncertainty and limited measurement data. In this regime the problem of establishing a well-defined measure of estimation precision becomes nontrivial. Furthermore, the construction of a suitable criterion for optimal measurement design must be reexamined to account for the prior uncertainty. We propose a fully Bayesian approach to temperature estimation based on the concept of thermodynamic length, which solves both these problems. As an illustration of this framework, we consider thermal spin-1/21/21/2 particles and investigate the fundamental difference between two cases: on the one hand, when the spins are probing the temperature of a heat reservoir and, on the other, when the spins themselves constitute the sample.