It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions with the environment. Here we include such interactions and, using quantum estimation theory, derive a generalised thermodynamic uncertainty relation valid for classical and quantum systems at all coupling strengths. We show that the non-commutativity between the system's state and its effective energy operator gives rise to quantum fluctuations that increase the temperature uncertainty. Surprisingly, these additional fluctuations are described by the average Wigner-Yanase-Dyson skew information. We demonstrate that the temperature's signal-to-noise ratio is constrained by the heat capacity plus a dissipative term arising from the non-negligible interactions. These findings shed light on the interplay between classical and non-classical fluctuations in quantum thermodynamics and will inform the design of optimal nanoscale thermometers.
It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions with the environment. Here we include such interactions and, using quantum estimation theory, derive a generalised thermodynamic uncertainty relation valid for classical and quantum systems at all coupling strengths. We show that the non-commutativity between the system's state and its effective energy operator gives rise to quantum fluctuations that increase the temperature uncertainty. Surprisingly, these additional fluctuations are described by the average Wigner-Yanase-Dyson skew information. We demonstrate that the temperature's signal-to-noise ratio is constrained by the heat capacity plus a dissipative term arising from the non-negligible interactions. These findings shed light on the interplay between classical and non-classical fluctuations in quantum thermodynamics and will inform the design of optimal nanoscale thermometers.
Abstract It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions with the environment. Here we include such interactions and, using quantum estimation theory, derive a generalised thermodynamic uncertainty relation valid for classical and quantum systems at all coupling strengths. We show that the non-commutativity between the system’s state and its effective energy operator gives rise to quantum fluctuations that increase the temperature uncertainty. Surprisingly, these additional fluctuations are described by the average Wigner-Yanase-Dyson skew information. We demonstrate that the temperature’s signal-to-noise ratio is constrained by the heat capacity plus a dissipative term arising from the non-negligible interactions. These findings shed light on the interplay between classical and non-classical fluctuations in quantum thermodynamics and will inform the design of optimal nanoscale thermometers.
Thermodynamics typically concerns the physical behaviour of macroscopic systems comprised of many particles. However, recent theoretical progress has extended the theory to both the classical-stochastic and quantum regimes, where systems are comprised of just a small number of particles. In this thesis I investigate a range of situations in which new thermodynamic phenomena emerge due to the reduced size of the systems involved. One central assumption in macroscopic thermodynamics is the weak coupling approximation, which posits that the equilibrium properties of a system are not influenced by the interactions with its surrounding environment. However, for microscopic systems this assumption can break down, and I derive new fluctuation relations that provide a refined form of the second law of thermodynamics in this strong-coupling regime, taking into account corrections stemming from these interactions. In this work I provide a characterisation of stochastic heat and entropy production for small scale classical systems that are defined regardless of the strength of interaction. I then show that these definitions lead to a consistent thermodynamic framework valid beyond the usual weak-coupling regime. The thesis also concerns the effect of interactions on the equilibrium properties of strongly-coupled quantum systems, and I investigate how these interactions can influence the resulting temperature fluctuations in this regime. Using tools from quantum estimation theory, I derive an uncertainty relation between energy and temperature valid at all coupling strengths and system sizes. The relation reveals how quantum energy coherences contribute to statistical fluctuations in the estimated temperature of small- scale systems. Finally, I investigate how quantum fluctuations influence the statistics of work extracted from slowly-driven quantum systems. I prove that, unlike in classical systems, the work dissipated by a general quantum system is no longer proportional to its statistical fluctuations. This result reveals new subtleties involved in designing optimal quantum thermodynamic processes.
We investigate the temperature uncertainty relation in the nonequilibrium probe-based temperature estimation process. We demonstrate that it is the fluctuation of heat that fundamentally determines temperature precision through the temperature-heat uncertainty relation. Specifically, we find that heat is divided into trajectory heat and correlation heat, which are associated with the heat exchange along the thermometer's evolution and the correlation between the thermometer and the sample, respectively. Based on two types of thermometers, we show that both of these heat terms are resources for enhancing temperature precision. By clearly distinguishing the resources for enhancing estimation precision, our findings not only explain why various quantum features are crucial for accurate temperature sensing but also provide valuable insights for designing ultrahigh-sensitive quantum thermometers. Additionally, we demonstrate that the temperature-heat uncertainty relation is consistent with the well-known temperature-energy uncertainty relation in thermodynamics. It establishes a connection between the information theory and the thermodynamics.
Temperature uncertainty of a quantum system in canonical ensemble is inversely determined by its energy fluctuation, which is known as the temperature-energy uncertainty relation. No such uncertainty relation was discovered for a non-equilibrium open quantum system. In this article, we derive a universal temperature uncertainty relation for general non-equilibrium processes. We find that it is the fluctuation of heat, which is defined as the change in bath energy, determines the temperature uncertainty in non-equilibrium case. Specifically, the heat is divided into trajectory heat and backaction heat, which are associated with the system's trajectory of evolution and the backaction of partial measurement on system, respectively. Based on this decomposition, we reveal that both correlations between system and bath's process function and state function are the resources for enhancing temperature precision. Our findings are conductive to design ultrahigh sensitive quantum thermometer.
The Heisenberg uncertainty relation, ΔxΔpx ⩾ ℏ/2 (ℏ ≡ h/2π), is well known. The purpose of this paper is to study a linkage between macroscopic thermodynamic quantities and the uncertainty relation. To simplify matters, we consider one-dimensional harmonic oscillator model. The calculations are carried out by two steps. First, the thermal average of the uncertainty relation is obtained for canonical system in thermal equilibrium at temperature T, which is denoted by (Δx)T(Δpx)T. Second, the thermodynamic quantities are expressed analytically as a function of (Δx)T(Δpx)T within the harmonic oscillator model. Finally, a connection between the energy fluctuations and the uncertainty relation is clarified for the Einstein’s heat capacity model. The analysis is made on the basis of fluctuation theory. The uncertainty relation is valid not only in quantum state but also at finite temperature.
Contrary to the conventional wisdom that deviations from standard thermodynamics originate from the strong coupling to the bath, it is shown that in quantum mechanics, these deviations originate from the uncertainty principle and are supported by the non-Markovian character of the dynamics. Specifically, it is shown that the lower bound of the dispersion of the total energy of the system, imposed by the uncertainty principle, is dominated by the bath power spectrum; therefore, quantum mechanics inhibits the system thermal-equilibrium-state from being described by the canonical Boltzmann's distribution. We show for a wide class of systems, systems interacting via central forces with pairwise-self-interacting environments; this general observation is in sharp contrast to the classical case, for which the thermal equilibrium distribution, irrespective of the interaction strength, is exactly characterized by the canonical Boltzmann distribution; therefore, no dependence on the bath power spectrum is present. We define an effective coupling to the environment that depends on all energy scales in the system and reservoir interaction. Sample computations in regimes predicted by this effective coupling are demonstrated. For example, for the case of strong effective coupling, deviations from standard thermodynamics are present and for the case of weak effective coupling, quantum features such as stationary entanglement are possible at high temperatures.