We propose a quantum sensing protocol that leverages the dynamical response of physical observables to quenches in quantum systems. Specifically, we use the nitrogen-vacancy (NV) color center in diamond to realize both scalar and vector magnetometry via quantum response. Furthermore, we suggest a method for detecting the instantaneous motion of magnetic nanoparticles. To achieve this, we derive the closed exact form of the Berry curvature corresponding to NV centers and design quenching protocols to extract the Berry curvature via dynamical response. By constructing and solving nonlinear equations, the magnetic field and instantaneous motion velocity of the magnetic nanoparticle can be deduced. We investigate the feasibility of our sensing scheme in the presence of decoherence and show through numerical simulations that it is robust to decoherence. Intriguingly, we have observed that a vanishing nuclear spin polarization in diamond benefits our dynamic sensing scheme, which stands in contrast with conventional Ramsey-based schemes. In comparison with Ramsey-based sensing schemes, our proposed scheme can sense an arbitrary time-dependent magnetic field if its time dependence is nearly adiabatic.
We propose a quantum sensing protocol that leverages the dynamical response of physical observables to quenches in quantum systems. Specifically, we use the nitrogen-vacancy (NV) color center in diamond to realize both scalar and vector magnetometry via quantum response. Furthermore, we suggest a method for detecting the instantaneous motion of magnetic nanoparticles. To achieve this, we derive the closed exact form of the Berry curvature corresponding to NV centers and design quenching protocols to extract the Berry curvature via dynamical response. By constructing and solving nonlinear equations, the magnetic field and instantaneous motion velocity of the magnetic nanoparticle can be deduced. We investigate the feasibility of our sensing scheme in the presence of decoherence and show through numerical simulations that it is robust to decoherence. Intriguingly, we have observed that a vanishing nuclear spin polarization in diamond benefits our dynamic sensing scheme, which stands in contrast with conventional Ramsey-based schemes. In comparison with Ramsey-based sensing schemes, our proposed scheme can sense an arbitrary time-dependent magnetic field if its time dependence is nearly adiabatic.
In modern-day quantum metrology, quantum sensors are widely employed to detect weak magnetic fields or nanoscale signals. Quantum devices, exploiting quantum coherence, are inevitably connected to physical constants and can achieve accuracy, repeatability, and precision approaching fundamental limits. As a result, these sensors have shown utility in a wide range of research domains spanning both science and technology. A rapidly emerging quantum sensing platform employs atomic-scale defects in crystals. In particular, magnetometry using nitrogen-vacancy (NV) color centers in diamond has garnered increasing interest. NV systems possess a combination of remarkable properties, optical addressability, long coherence times, and biocompatibility. Sensors based on NV centers excel in spatial resolution and magnetic sensitivity. These diamond-based sensors promise comparable combination of high spatial resolution and magnetic sensitivity without cryogenic operation. The above properties of NV magnetometers promise increasingly integrated quantum measurement technology, as a result, they have been extensively developed with various protocols and find use in numerous applications spanning materials characterization, nuclear magnetic resonance (NMR), condensed matter physics, paleomagnetism, neuroscience and living systems biology, and industrial vector magnetometry. In this chapter, NV centers are explored for magnetic sensing in a number of contexts. In general, we introduce novel regimes for magnetic-field probes with NV ensembles. Specifically, NV centers are developed for sensitive magnetometers for applications where microwaves (MWs) are prohibitively invasive and operations need to be carried out under zero ambient magnetic field. The primary goal of our discussion is to improve the utility of these NV center-based magnetometers.
This thesis investigates the theoretical foundations, material properties, and experimental realization of quantum sensors based on the Nitrogen-Vacancy (NV) centers in diamond, a solid-state system that combines quantum coherence with room-temperature operability. The first chapter introduces the principles of quantum sensing, outlining the fundamental definitions, operating protocols, and physical processes underlying the quantum measurement paradigm. Emphasis is placed on the quantum sensing Hamiltonian and the distinction between various classes of quantum sensors. The second chapter focuses on diamond as a host material and on the NV center as a quantum defect. The electronic structure, optical transitions, and spin properties of the NV center are analyzed in detail. Several techniques of NV-based magnetometry are presented, including continuouswave and pulsed optically detected magnetic resonance (ODMR). The discussion also addresses coherence times (T1, T2, and T∗2 ) and methods of diamond synthesis together with NV-center generation through irradiation and annealing. Chapter three develops the physical theory describing the NV center. The Hamiltonian formalism includes spin-spin, hyperfine, and quadrupolar interactions, as well as couplings to external magnetic fields. The chapter further introduces the Bloch sphere representation, magnetic resonance phenomena, and models of lightmatter interaction, ranging from the semiclassical to the fully quantum Rabi framework. A seven-level rate-equation model is proposed to capture the spin dynamics and optical cycling processes of the NV center. The fourth chapter reports the experimental results. After describing materials and methods, several ODMR-based vector magnetometry experiments are presented, highlighting different spectral regimes and the dependence of resonance features on the external magnetic field geometry. Additional studies demonstrate temperature sensing and microwave-free magnetometry techniques for mapping magnetic field distributions. Sensitivity analysis and calibration procedures are also discussed.
Quantum sensing using nitrogen-vacancy (NV) centers in diamond has emerged as a powerful platform for detecting ultra-low magnetic fields under ambient conditions. Owing to their long spin coherence times, optical addressability, and compatibility with aqueous environments, it has found widespread applications in biosensing and bio-imaging. This review presents the fundamental principles and recent advances in NV-based quantum magnetometry for biosensing applications, with a particular focus on measurements in aqueous medium and at cellular and molecular length scales. We discuss the underlying spin physics of NV centers and highlight two primary detection modalities: optically detected magnetic resonance (ODMR) and T1 relaxometry-based sensing and how these approaches aids in the detection of both static magnetic fields and dynamic magnetic noise arising from biological processes. The review explores key application areas, including nanoscale nuclear magnetic resonance (NMR), monitoring of neural activity, detection of abnormal or rogue cells using NV-based platforms etc. In addition, strategies for enhancing sensitivity, such as surface functionalization of nanodiamonds, femtosecond (fs) laser-written photonic structures, and integration with microfluidic and lab-on-chip systems have also been discussed in depth. We also address the critical challenges, including surface-induced decoherence, charge-state instability, and signal-to-noise limitations in biofluids associated with NV-based biosensing applications. Finally, we outline future prospects, highlighting how NV-based magnetic biosensing provides a promising pathway for translating quantum sensing technologies into practical biomedical applications.
We propose a new concept for non-invasive, multiparametric liquid analysis based on nitrogen-vacancy (NV) centre magnetometry, relaxometry and surface-tethered magnetic nanoparticles. Magnetic nanoparticles are anchored to a diamond surface via DNA strands, forming nanoscale mechanical oscillators whose thermally driven motion is strongly influenced by the surrounding liquid environment. The resulting time-dependent magnetic fields couple to near-surface NV centres and are detected via optically detected magnetic resonance or changes in spin coherence time. By spatially patterning the diamond surface with regions functionalised by DNA tethers of different lengths, sequences, or chemical modifications, a single liquid is mapped onto a high-dimensional quantum response vector rather than a single scalar observable. Changes in viscosity, molecular adsorption, or chemical interactions modify the dynamics of magnetic nanoparticles in a region-specific manner, enabling differential sensing across the surface. We outline the physical transduction mechanism, discuss relevant scaling relations, and assess experimental feasibility using established wide-field NV magnetometry and relaxometry methods. The proposed platform combines quantum sensing with surface heterogeneity, offering a versatile route toward parallel, label-free liquid characterisation.
High spatial resolution quantum sensing of near-surface nitrogen vacancy (NV) centers in diamond has enabled detection of magnetic, electrical, and thermal signals at the nanoscale. At depths of just a few nanometers, NV centers serve as localized quantum probes for external spins or low-dimensional materials, but their proximity to the surface also enhances decoherence caused by fluctuating nuclear spins. While advances in surface engineering have stabilized the charge state of NV centers at depths of tens of nanometers, achieving both ultra-shallow implantation (0.5-2 nm) and long-term spin coherence remains a central challenge. In this work, we show using first-principles modeling that, by exploiting the interaction of surface-induced strain and weak dc magnetic fields, the spin coherence times of 1-nm-deep NV centers can be greatly improved near the spin-phonon-confined regime at room temperature in 12C-rich diamonds. We also demonstrate that this protocol benefits ~ 10-nm-deep NV centers in natural diamond, enabling vector magnetometry at the nanoscale. Shallow NV centers in diamond are advantageous for quantum sensing but suffer from surface magnetic noise. Using first-principles simulations supported by experiments, the authors show that a combination of small magnetic fields and surface strain can significantly enhance spin coherence of 1 nm-deep NV centers.
The nitrogen-vacancy (NV) defect center in diamond has demonstrated great capability for nanoscale magnetic sensing and imaging for both static and periodically modulated target fields. However, it remains a challenge to detect and image randomly fluctuating magnetic fields. Recent theoretical and numerical works have outlined detection schemes that exploit changes in decoherence of the detector spin as a sensitive measure for fluctuating fields. Here we experimentally monitor the decoherence of a scanning NV center in order to image the fluctuating magnetic fields from paramagnetic impurities on an underlying diamond surface. We detect a signal corresponding to roughly 800 μB in 2 s of integration time, without any control on the target spins, and obtain magnetic-field spectral information using dynamical decoupling techniques. The extracted spatial and temporal properties of the surface paramagnetic impurities provide insight to prolonging the coherence of near-surface qubits for quantum information and metrology applications.