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arXiv:2306.09578

Detailed Fluctuation Theorem from the One-Time Measurement Scheme

Maeda, Kenji, Tharon Holdsworth, Sebastian Deffner, Akira Sone

Published Jun 16, 2023• 0 citations
arXivHTMLPDF

Abstract

The quantum fluctuation theorem can be regarded as the first principle of quantum nonequilibrium thermodynamics. However, many different formulations have been proposed, which depend on how quantum work is defined. In this context, we have seen that for some situations the one-time measurement (OTM) scheme can be more informative than the two-time measurement (TTM) scheme. Yet, so far the focus of OTM has been on integral fluctuation theorems, since, the work distribution of the backward process has been lacking. To this end, we prove that the OTM scheme is the nondestructive TTM scheme, in which the final state is a pointer state of the second measurement whose Hamiltonian is conditioned on the first measurement outcome. This insight leads to a derivation of the detailed fluctuation theorem for the characteristic functions of the forward and backward work distributions. Finally, our conceptual findings are experimentally verified with the IBM quantum computer.

DOI
10.13016/m2aqvs-i8y0

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•Jan 1, 2013•0 citations
The quantum fluctuation theorem can be regarded as the first principle of quantum nonequilibrium thermodynamics. However, many different formulations have been proposed, which depend on how quantum work is defined. In this context, we have seen that for some situations the one-time measurement (OTM) scheme can be more informative than the two-time measurement (TTM) scheme. Yet, so far the focus of OTM has been on integral fluctuation theorems, since, the work distribution of the backward process has been lacking. To this end, we prove that the OTM scheme is the nondestructive TTM scheme, in which the final state is a pointer state of the second measurement whose Hamiltonian is conditioned on the first measurement outcome. This insight leads to a derivation of the detailed fluctuation theorem for the characteristic functions of the forward and backward work distributions. Finally, our conceptual findings are experimentally verified with the IBM quantum computer.
Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward out-of-equilibrium quantum process and in a corresponding backward one. In particular, the initial states of the two processes are thermal states and thus incoherent in the energy basis. Here we aim to investigate the role of initial quantum coherence in work fluctuation theorems, by considering a quasiprobability distribution of work. To do this, we formulate and examine the implications of a detailed fluctuation theorem, which reproduces the Tasaki-Crooks fluctuation theorem in the absence of initial quantum coherence.
Fluctuation theorems establish exact relations for nonequilibrium dynamics, profoundly advancing the field of stochastic thermodynamics. In this work, we extend quantum fluctuation theorems beyond the traditional thermodynamic framework to quantum multipartite information dynamics, where both the system and the environment are multipartite without assuming any thermodynamic constraints. Based on the two-point measurement scheme and the classical probability, we establish the fluctuation theorem for the dynamics of classical multipartite mutual information. By extending to quasiprobability, we derive quantum fluctuation theorems for multipartite coherence and quantum correlations, presenting them in both integral and detailed forms. Our theoretical results are illustrated and verified using three-qubit examples, and feasible experimental verification protocols are proposed. These findings uncover the statistical structure underlying the nonequilibrium quantum information dynamics, providing fundamental insights and alternative tools for advancing quantum technologies.
We derive the fluctuation theorem for quantum-state statistics that can be obtained when we initially measure the total energy of a quantum system at thermal equilibrium, let the system evolve unitarily, and record the quantum-state data reconstructed at the end of the process. The obtained theorem shows that the quantum-state statistics for the forward and backward processes is related to the equilibrium free-energy difference through an infinite series of independent relations, which gives the quantum work fluctuation theorem as a special case, and reproduces the out-of-time-order fluctuation-dissipation theorem near thermal equilibrium. The quantum-state statistics exhibits a system-size scaling behavior that differs between integrable and non-integrable (quantum chaotic) systems as demonstrated numerically for one-dimensional quantum lattice models.
Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate spectra. In the particular case of microcanonical initial states, explicit expressions for the characteristic function and the corresponding probability density of work are formulated. Their classical limit as well as their relations to the corresponding canonical expressions are discussed. A fluctuation theorem is derived that expresses the ratio of probabilities of work for a process and its time reversal to the ratio of densities of states of the microcanonical equilibrium systems with corresponding initial and final Hamiltonians. From this Crooks-type fluctuation theorem a relation between entropies of different systems can be derived which does not involve the time-reversed process. This entropy-from-work theorem provides an experimentally accessible way to measure entropies.
We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.