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arXiv:2303.18020 · Physical review. E

General theory for discrete symmetry-breaking equilibrium states in quantum systems

Ángel L. Corps, Armando Relaño

Published Sep 30, 2024• 4 citations
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Abstract

Spontaneous symmetry breaking in phase transitions occurs when the system Hamiltonian is symmetric under a certain transformation, but the equilibrium states observed in nature are not. Here we build two noncommuting quantities from the order parameter of the transition and the symmetry operator that are constants of motion when such equilibrium states exist. Then, we derive a general equilibrium ensemble for the ordered phase and show that equilibrium states consisting of superpositions of different symmetry-breaking states, like positive and negative magnetized states, may exist. We propose an experimental realization of such equilibrium states with the state-of-the-art quantum technologies, and test it by means of numerical calculations. Finally, we show that a small symmetry-breaking perturbation in the Hamiltonian stabilizes the conservation of one of the two former quantities, implying that symmetry-breaking equilibrium states become stable even in small quantum systems.

DOI
10.1103/physreve.110.034137

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Spontaneous symmetry breaking in phase transitions occurs when the system Hamiltonian is symmetric under a certain transformation, but the equilibrium states observed in nature are not. Here we build two noncommuting quantities from the order parameter of the transition and the symmetry operator that are constants of motion when such equilibrium states exist. Then, we derive a general equilibrium ensemble for the ordered phase and show that equilibrium states consisting of superpositions of different symmetry-breaking states, like positive and negative magnetized states, may exist. We propose an experimental realization of such equilibrium states with the state-of-the-art quantum technologies, and test it by means of numerical calculations. Finally, we show that a small symmetry-breaking perturbation in the Hamiltonian stabilizes the conservation of one of the two former quantities, implying that symmetry-breaking equilibrium states become stable even in small quantum systems.
A cornerstone of the theory of phase transitions is the observation that many-body systems exhibiting a spontaneous symmetry breaking in the thermodynamic limit generally show extensive fluctuations of an order parameter in large but finite systems. In this work, we introduce the dynamical analog of such a theory. Specifically, we consider local dissipative dynamics preparing an equilibrium steady-state of quantum spins on a lattice exhibiting a discrete or continuous symmetry but with extensive fluctuations in a local order parameter. We show that for all such processes, there exist asymptotically stationary symmetry-breaking states, i.e., states that become stationary in the thermodynamic limit and give a finite value to the order parameter. We give results both for discrete and continuous symmetries and explicitly show how to construct the symmetry-breaking states. Our results show in a simple way that, in large systems, local dissipative dynamics satisfying detailed balance cannot uniquely and efficiently prepare states with extensive fluctuations with respect to local operators. We discuss the implications of our results for quantum simulators and dissipative state preparation.
We propose a generalization of the eigenstate thermalization hypothesis accountin g for the emergence of symmetry-breaking phases. It consists of two conditions that any system with a degenerate spectrum must fulfill in order to thermalize. The failure of each condition generates a different nonthermalizing scenario. One is due to the absence of chaos and may indicate that extra constants of motion are required to describe equilibrium states. The other one implies the existence of initial conditions evolving toward symmetry-breaking equilibrium states. If it spreads across an entire spectral region, then this region gives rise to a symmetry-breaking phase. We explore the applicability of this formalism by means of numerical experiments on a three-site Bose-Hubbard model with two noncommuting discrete symmetries.
In this paper, as a personal review, we suppose a possible extension of Gibbs ensemble theory so that it can provide a reasonable description of phase transitions and spontaneous symmetry breaking. The extension is founded on three hypotheses, and can be regarded as a microscopic edition of the Landau phenomenological theory of phase transitions. Within its framework, the stable state of a system is determined by the evolution of order parameter with temperature according to such a principle that the entropy of the system will reach its minimum in this state. The evolution of order parameter can cause a change in representation of the system Hamiltonian; different phases will realize different representations, respectively; a phase transition amounts to a representation transformation. Physically, it turns out that phase transitions originate from the automatic interference among matter waves as the temperature is cooled down. Typical quantum many-body systems are studied with this extended ensemble theory. We regain the Bardeen–Cooper–Schrieffer solution for the weak-coupling superconductivity, and prove that it is stable. We find that negative-temperature and laser phases arise from the same mechanism as phase transitions, and that they are unstable. For the ideal Bose gas, we demonstrate that it will produce Bose–Einstein condensation (BEC) in the thermodynamic limit, which confirms exactly Einstein's deep physical insight. In contrast, there is no BEC either within the phonon gas in a black body or within the ideal photon gas in a solid body. We prove that it is not admissible to quantize the Dirac field by using Bose–Einstein statistics. We show that a structural phase transition belongs physically to the BEC happening in configuration space, and that a double-well anharmonic system will undergo a structural phase transition at a finite temperature. For the O( N )-symmetric vector model, we demonstrate that it will yield spontaneous symmetry breaking and produce Goldstone bosons; and if it is coupled with a gauge field, the gauge field will obtain a mass (Higgs mechanism). Also, we show that an interacting Bose gas is stable only if the interaction is repulsive. For the weak interaction case, we find that the BEC is a 'λ-transition' and its transition temperature can be lowered by the repulsive interaction. In connection with liquid 4 He, it is found that the specific heat at constant pressure C P will show a T 3 law at low temperatures, which is in agreement with the experiment. If the system is further cooled down, the theory predicts that C P will vanish linearly as , which is anticipating experimental verifications.
Abstract Spontaneous symmetry breaking is well understood under equilibrium conditions as a consequence of the singularity of the thermodynamic limit. How a single global orientation of the order parameter dynamically emerges from an initially symmetric state during a phase transition, however, is not captured by this paradigm. Here, we present a series of symmetry arguments suggesting that singling out a global choice for the ordered state is in fact forbidden under unitary time evolution, even in the presence of an environment and infinitesimal symmetry breaking perturbations. We thus argue that the observation of phase transitions in our everyday world presents a manifestation of the unitarity of quantum dynamics itself being spontaneously broken. We argue that this agrees with the observation that Schrödinger’s time dependent equation is rendered unstable for macroscopic objects owing to the same singular thermodynamic limit that affects equilibrium configurations.
We present a theory characterizing the phases emerging as a consequence of continuous symmetry-breaking in quantum and classical systems. In symmetry-breaking phases, dynamics is restricted due to the existence of a set of conserved charges derived from the order parameter of the phase transition. Their expectation values are determined by the privileged direction appearing in the ordered phase as a consequence of symmetry breaking, and thus they can be used to determine whether this direction is well defined or has quantum fluctuations. Our theory is numerically exemplified via the two-dimensional limit of the vibron model, a fully connected system invariant under a rotation operator which generates the continuous symmetry-breaking.
The theory of spontaneous symmetry breaking---one of the cornerstones of modern condensed-matter physics---underlies the connection between a classically ordered object in the thermodynamic limit and its microscopic quantum-mechanical constituents. However, a large, but not infinitely large, system requires a finite symmetry-breaking perturbation to stabilize a symmetry-broken state over the exact quantum-mechanical ground state, respecting the symmetry. Here, we use the example of a particular antiferromagnetic model system to show that no matter how slowly such a symmetry-breaking perturbation is driven, the adiabatic limit can never be reached. Dynamically induced collective excitations---``quantum defects''---preempt the symmetry-breaking phenomenon and trigger the appearance of a symmetric nonequilibrium state that recursively collapses into the classical equilibrium state, breaking the symmetry at punctured times. The presence of this state allows ``quantum-classical'' transitions to be investigated and controlled in mesoscopic devices by externally supplying a proper dynamical symmetry-breaking perturbation.