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arXiv:2303.14949

Breakdown of additivity of transition rates in systems connected to multiple thermal reservoirs

Vaibhav H. Wasnik

Published Mar 27, 2023• 0 citations
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Abstract

In stochastic thermodynamics, it is commonly assumed that for a system coupled to multiple thermal reservoirs, the transition rates between two energy levels are additive across baths. In this work, we first demonstrate through an explicit construction of two subsystems-that are parts of a single composite system, each coupled to a distinct thermal reservoir-that while each subsystem individually evolves Markovianly, their joint evolution is inherently non-Markovian. We then present a general algebraic argument showing that, even if one assumes a Markovian description with additive transition rates, the steady-state condition imposed by the master equation leads to an inconsistency. The analysis identifies the precise structural limitation that arises in describing systems simultaneously interacting with multiple baths within a Markovian framework.

DOI
10.48550/arxiv.2303.14949

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In stochastic thermodynamics, it is commonly assumed that for a system coupled to multiple thermal reservoirs, the transition rates between two energy levels are additive across baths. In this work, we first demonstrate through an explicit construction of two subsystems-that are parts of a single composite system, each coupled to a distinct thermal reservoir-that while each subsystem individually evolves Markovianly, their joint evolution is inherently non-Markovian. We then present a general algebraic argument showing that, even if one assumes a Markovian description with additive transition rates, the steady-state condition imposed by the master equation leads to an inconsistency. The analysis identifies the precise structural limitation that arises in describing systems simultaneously interacting with multiple baths within a Markovian framework.
Markovian quantum master equations are generally thought to satisfy the following three conditions: (i) they describe the dynamics of time scales that are larger than the reservoir correlation time scale, (ii) these stationary solutions give the thermal equilibrium states with a reservoir, and (iii) they can be written in the Lindblad form. In fact, for single systems such as a single harmonic oscillator and a single two-level system, Markovian quantum master equations satisfying all these conditions can be obtained. However, for composite systems, which consist of more than one subsystem coupled with each other, such equations have not been obtained thus far. In this study, we found that we cannot use the Born–Markov approximation for obtaining quantum master equations for composite systems in the strong-coupling regime, no matter how short the reservoir correlation time is.
A pure-dephasing reservoir acting on an individual quantum system induces loss of coherence without energy exchange. When acting on composite quantum systems, dephasing reservoirs can lead to a radically different behavior. Transport of heat between two pure-dephasing Markovian reservoirs is predicted in this work. They are connected through a chain of coupled sites. The baths are kept in thermal equilibrium at distinct temperatures. Quantum coherence between sites is generated in the steady-state regime and results in the underlying mechanism sustaining the effect. A quantum model for the reservoirs is a necessary condition for the existence of stationary heat transport. A microscopic derivation of the non-unitary system-bath interaction is employed, valid for arbitrary inter-site coupling regime. The model assumes that each site-reservoir coupling is local.
We study the relationship between (non-)Markovian evolutions, established correlations, and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady-state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.
We present a systematic thermodynamic analysis of nonsecular GKLS master equations. When some energy transitions in the system are comparable with the dissipative rate, the secular approximation is not valid, and the positivity of the dynamics must be ensured via other approximations. The dynamics then presents features reminiscent from strong coupling to the environment: e.g. the equilibrium state with an environment at thermal equilibrium is not a Gibbs state of the local system Hamiltonian and the dynamics couples energy coherences and populations. Nonetheless, we build a unified, consistent thermodynamic framework for those dynamics. We focus on two approximations beyond the full secular approximation (the local and the more accurate geometric-arithmetic approximations), and then employ systematic perturbation theory on microscopic expressions for the first and second law of thermodynamics which relate irreversibility to the increase of system-environment correlations. We show that, in spite of the weak system-bath coupling, the system-bath interaction energy participates to the energy balance, and is directly linked to the Lamb-shift Hamiltonian. We compare this microscopic entropy production with the definition based on the contractivity of the reduced system dynamics (Spohn inequality). We show that, unlike for secular master equations, the two entropy production rates differ because of the presence of non-vanishing stationary coherences in the energy eigenbasis. However, in the case of a single thermal bath, the difference is purely transient, and no work can be cyclically extracted from the steady-state despite its non-Gibbs form. Finally, we illustrate our results with simple examples, clarifying and completing the thermodynamic picture of Markovian dynamics in the quantum regime.
We study the relationship between a (non-)Markovian evolution and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.
A master equation for a quantum system coupled to a heat bath with stochastically fluctuating energy levels is derived by making use of the ensemble averaging and the averaging with respect to a stochastic process in the bath. Relaxation terms are determined in the Born approximation with respect to the system-bath interaction and the damping parameters related to a relaxation kernel are specified. In parallel with the spectral strength of the bath, the damping parameters determine the transient times for the Markovian description creating the physical origin of the slippage [A. Suarez, R. Sibey, and I. Oppenheim, J. Chem. Phys. 97, 5101 (1992)]. The influence of energy fluctuations of the bath is analyzed for a two-level system including the solution of the corresponding non-Markovian equation for the level population difference. The conditions for the formation of Boltzmann's thermal ratio between steady-state populations are evaluated as well.