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arXiv:1804.03861 · Physical Review A

Entropy production and correlations in a controlled non-Markovian setting

Maria Popovic, Bassano Vacchini, Steve Campbell

Published Jul 23, 2018• 46 citations
arXivHTMLPDF

Abstract

We study the relationship between (non-)Markovian evolutions, established correlations, and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady-state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.

DOI
10.1103/physreva.98.012130

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We study the relationship between (non-)Markovian evolutions, established correlations, and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady-state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.
We study the relationship between a (non-)Markovian evolution and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.
We investigate the irreversible entropy production of a qubit in contact with an environment modelled by a microscopic collision model in both Markovian and non-Markovian regimes. Our main goal is to contribute to the discussions on the relationship between non-Markovian dynamics and negative entropy production rates. We employ two different types of collision models that do or do not keep the correlations established between the system and the incoming environmental particle, while both of them pertain to their non-Markovian nature through information backflow from the environment to the system. We observe that as the former model, where the correlations between the system and environment are preserved, gives rise to negative entropy production rates in the transient dynamics, the latter one always maintains positive rates, even though the convergence to the steady-state value is slower as compared to the corresponding Markovian dynamics. Our results suggest that the mechanism underpinning the negative entropy production rates is not solely non-Markovianity through information backflow, but rather the contribution to it through established system-environment correlations.
Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovianity. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovianity and when it does not. For a system coupled to a single heat bath, this can be established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a Markovian master equation and (ii) the classical Hamiltonian dynamics of a system coupled to a bath. The quantum version of the latter result is shown not to hold despite the fact that the integrated thermodynamic description is formally equivalent to the classical case. The instantaneous fixed point of a non-Markovian dynamics plays an important role in our study. Our key contribution is to provide a consistent theoretical framework to study the finite-time thermodynamics of a large class of dynamics with a precise link to its non-Markovianity.
We study the thermalization dynamics and thermodynamics of a qubit coupled to a structured, memory-carrying environment modeled as a single bosonic mode continuously thermalized by a Markovian bath. The competition between coherent qubit-mode coupling g and thermalization rate κ is controlled by the dimensionless ratio μ=g/κ, which drives a crossover between Markovian and strongly non-Markovian regimes. In the strongly non-Markovian limit, coherent energy exchange produces transient shortcuts to local thermalization, whereby the qubit approaches its thermal state long before global equilibration. In the opposite limit, we derive an original convolution master equation with an exponential memory kernel, which reduces to a thermal GKSL equation as μ→0. The crossover between the two regimes closely mirrors the underdamped-to-overdamped transition of a classical damped oscillator. From the thermodynamic side, we derive an original decomposition of the reduced entropy production in terms of qubit-ancilla mutual information and ancilla relative entropy, providing a quantitative fingerprint of non-Markovian corrections. We then extend this framework to the stochastic level via two monitoring protocols — Fock-state tracking and energy-exchange detection — constructing trajectory-level entropy productions and establishing fluctuation theorems tailored to each scheme. Together, these results demonstrate that a self-consistent stochastic thermodynamics can be formulated for non-Markovian open quantum systems under continuous monitoring.
Understanding the entropy production of systems strongly coupled to thermal baths is a core problem of both quantum thermodynamics and mesoscopic physics. While many techniques exist to accurately study entropy production in such systems, they typically require a microscopic description of the baths, which can become numerically intractable to study for large systems. Alternatively an open-systems approach can be employed with all the nuances associated with various levels of approximation. Recently, the mesoscopic leads approach has emerged as a powerful method for studying such quantum systems strongly coupled to multiple thermal baths. In this method, a set of discretized lead modes, each locally damped, provide a Markovian embedding. Here we show that this method proves extremely useful to describe entropy production of a strongly coupled open quantum system. We show numerically, for both noninteracting and interacting setups, that a system coupled to a single bath exhibits a thermal fixed point at the level of the embedding. This allows us to use various results from the thermodynamics of quantum dynamical semigroups to infer the nonequilibrium thermodynamics of the strongly coupled, non-Markovian central systems. In particular, we show that the entropy production in the transient regime recovers the well-established microscopic definitions of entropy production with a correction that can be computed explicitly for both the single- and multiple-lead cases.
We examine the elements of the balance equation of entropy in open quantum evolutions and their response as we go from a Markovian to a non-Markovian situation. In particular, we look at the heat current and entropy production rate in the non-Markovian reduced evolution, as well as a Markovian limit of the same, experienced by one of two interacting systems immersed in a Markovian bath. The analysis naturally leads us to define a heat current deficit and an entropy production rate deficit, which are differences between the global and local versions of the corresponding quantities. The investigation leads, in certain cases, to a complementarity of the time-integrated heat current deficit and the relative entropy of entanglement between the two systems.