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arXiv:2302.07296 · Physical Review Letters

Formation of Ultracold Molecules by Merging Optical Tweezers

Daniel K. Ruttley, Alexander Guttridge, Stefan Spence, Robert C. Bird, C. Ruth Le Sueur, Jeremy M. Hutson, Simon L. Cornish

Published May 31, 2023• 59 citations
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Abstract

We demonstrate the formation of a single RbCs molecule during the merging of two optical tweezers, one containing a single Rb atom and the other a single Cs atom. Both atoms are initially predominantly in the motional ground states of their respective tweezers. We confirm molecule formation and establish the state of the molecule formed by measuring its binding energy. We find that the probability of molecule formation can be controlled by tuning the confinement of the traps during the merging process, in good agreement with coupled-channel calculations. We show that the conversion efficiency from atoms to molecules using this technique is comparable to magnetoassociation.

DOI
10.1103/physrevlett.130.223401

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We demonstrate the formation of a single RbCs molecule during the merging of two optical tweezers, one containing a single Rb atom and the other a single Cs atom. Both atoms are initially predominantly in the motional ground states of their respective tweezers. We confirm molecule formation and establish the state of the molecule formed by measuring its binding energy. We find that the probability of molecule formation can be controlled by tuning the confinement of the traps during the merging process, in good agreement with coupled-channel calculations. We show that the conversion efficiency from atoms to molecules using this technique is comparable to magnetoassociation.
Abstract We report the preparation of exactly one 87Rb atom and one 133Cs atom in the same optical tweezer as the essential first step towards the construction of a tweezer array of individually trapped 87Rb133Cs molecules. Through careful selection of the tweezer wavelengths, we show how to engineer species-selective trapping potentials suitable for high-fidelity preparation of Rb + Cs atom pairs. Using a wavelength of 814 nm to trap Rb and 938 nm to trap Cs, we achieve loading probabilities of 0.508(6) for Rb and 0.547(6) for Cs using standard red-detuned molasses cooling. Loading the traps sequentially yields exactly one Rb and one Cs atom in 28.4(6)% of experimental runs. Using a combination of an acousto-optic deflector and a piezo-controlled mirror to control the relative position of the tweezers, we merge the two tweezers, retaining the atom pair with a probability of 0.9 9 ( − 0.02 ) ( + 0.01 ) . We use this capability to study hyperfine-state-dependent collisions of Rb and Cs in the combined tweezer and compare the measured two-body loss rates with coupled-channel quantum scattering calculations.
We present a new approach to investigating Rydberg molecules by demonstrating the formation and characterization of individual Rb^{*}Cs Rydberg molecules using optical tweezers. By employing single-atom detection of Rb and Cs, we observe molecule formation via correlated loss of both species and study the formation dynamics with single-particle resolution. We control the interatomic distances by manipulating the relative wave function of atom pairs using the tweezer intensity, optimizing the coupling to molecular states and exploring the effect of the tweezer on these states. Additionally, we demonstrate molecule association with atoms trapped in separate tweezers, paving the way for state-selective assembly of polyatomic molecules. The observed binding energies, molecular alignment, and bond lengths are in good agreement with theory. Our approach is broadly applicable to Rydberg tweezer platforms, expanding the range of available molecular systems and enabling the integration of Rydberg molecules into existing quantum science platforms.
We demonstrate full quantum state control of two species of single atoms using optical tweezers and assemble the atoms into a molecule.Our demonstration includes 3D ground-state cooling of a single atom (Cs) in an optical tweezer, transport by several microns with minimal heating, and merging with a single Na atom.Subsequently, both atoms occupy the simultaneous motional ground state with 61(4)% probability.This realizes a sample of exactly two cotrapped atoms near the phase-space-density limit of one, and allows for efficient stimulated-Raman transfer of a pair of atoms into a molecular bound state of the triplet electronic ground potential a 3 Σ þ .The results are key steps toward coherent creation of single ultracold molecules for future exploration of quantum simulation and quantum information processing.
We demonstrate the formation of a single NaCs molecule in an optical tweezer by magnetoassociation through an s-wave Feshbach resonance at 864.11(5) G. Starting from single atoms cooled to their motional ground states, we achieve conversion efficiencies of 47(1)%, and measure a molecular lifetime of 4.7(7) ms. By construction, the single molecules are predominantly [77(5)%] in the center-of-mass motional ground state of the tweezer. Furthermore, we produce a single p-wave molecule near 807 G by first preparing one of the atoms with one quantum of motional excitation. Our creation of a single weakly bound molecule in a designated internal state in the motional ground state of an optical tweezer is a crucial step towards coherent control of single molecules in optical tweezer arrays.
Abstract We report simultaneous Raman sideband cooling of a single 87Rb atom and a single 133Cs atom held in separate optical tweezers at 814 nm and 938 nm, respectively. Starting from outside the Lamb-Dicke regime, after 45 ms of cooling we measure probabilities to occupy the three-dimensional motional ground state of 0.8 6 − 0.04 + 0.03 for Rb and 0.9 5 − 0.04 + 0.03 for Cs. Our setup overlaps the Raman laser beams used to cool Rb and Cs, reducing hardware requirements by sharing equipment along the same beam path. The cooling protocol is scalable, and we demonstrate cooling of single Rb atoms in an array of four tweezers. After motional ground-state cooling, a 938 nm tweezer is translated to overlap with a 814 nm tweezer so that a single Rb and a single Cs atom can be transferred into a common 1064 nm trap. By minimising the heating during the merging and transfer, we prepare the atoms in the relative motional ground state with an efficiency of 0.8 1 − 0.08 + 0.08 . This is a crucial step towards the formation of single RbCs molecules confined in optical tweezer arrays.
Chemical reactions typically proceed via stochastic encounters between reactants. Going beyond this paradigm, we combined exactly two atoms in a single, controlled reaction. The experimental apparatus traps two individual laser-cooled atoms [one sodium (Na) and one cesium (Cs)] in separate optical tweezers and then merges them into one optical dipole trap. Subsequently, photoassociation forms an excited-state NaCs molecule. The discovery of previously unseen resonances near the molecular dissociation threshold and measurement of collision rates are enabled by the tightly trapped ultracold sample of atoms. As laser-cooling and trapping capabilities are extended to more elements, the technique will enable the study of more diverse, and eventually more complex, molecules in an isolated environment, as well as synthesis of designer molecules for qubits.