A deeper understanding of the differences between quantum and classical dynamics promises great potential for emerging technologies. Nevertheless, some aspects remain poorly understood, particularly concerning the role of quantum coherence in open quantum systems. On the one hand, coherence leads to entanglement and even nonlocality. On the other, it may lead to a suppression of fluctuations, causing violations of thermokinetic uncertainty relations (TUR and KUR) that are valid for classical processes. These represent two different manifestations of coherence, one depending only on the state of the system (static) and one depending on two-time correlation functions (dynamical). Here we employ these manifestations of coherence to determine when mesoscopic quantum transport can be captured by a classical model based on stochastic jumps, and when such a model breaks down, implying nonclassical behavior. To this end, we focus on a minimal model of a double quantum dot coupled to two thermal reservoirs. In this system, quantum tunneling induces Rabi oscillations and results in both entanglement and nonlocality, as well as TUR and KUR violations. These effects, which describe the breakdown of a classical description, are accompanied by a peak in coherence. Our results provide guiding principles for the design of out-of-equilibrium devices that exhibit nonclassical behavior.
A deeper understanding of the differences between quantum and classical dynamics promises great potential for emerging technologies. Nevertheless, some aspects remain poorly understood, particularly concerning the role of quantum coherence in open quantum systems. On the one hand, coherence leads to entanglement and even nonlocality. On the other, it may lead to a suppression of fluctuations, causing violations of thermokinetic uncertainty relations (TUR and KUR) that are valid for classical processes. These represent two different manifestations of coherence, one depending only on the state of the system (static) and one depending on two-time correlation functions (dynamical). Here we employ these manifestations of coherence to determine when mesoscopic quantum transport can be captured by a classical model based on stochastic jumps, and when such a model breaks down, implying nonclassical behavior. To this end, we focus on a minimal model of a double quantum dot coupled to two thermal reservoirs. In this system, quantum tunneling induces Rabi oscillations and results in both entanglement and nonlocality, as well as TUR and KUR violations. These effects, which describe the breakdown of a classical description, are accompanied by a peak in coherence. Our results provide guiding principles for the design of out-of-equilibrium devices that exhibit nonclassical behavior.
Kinetic uncertainty relations (KURs) set fundamental limits on the precision of nonequilibrium transport by bounding the signal-to-noise ratio of currents in terms of the dynamical activity, a quantity that counts exchange events between a system and its reservoirs. This framework is well established in the weak-coupling regime, where transport occurs via well-defined, particlelike tunneling processes. At strong coupling, however, quantum coherence challenges both the validity of standard KURs and the notion of activity itself. In this Letter, we introduce a generalized definition of dynamical activity valid at arbitrary system-reservoir coupling, and show that it leads to a breakdown of standard KURs at strong coupling. Building on this result, we derive and prove a novel uncertainty relation, denoted quantum KUR (QKUR), which provides a genuine quantum extension of KUR, accounting for intrinsic quantum coherent contributions of the generalized activity. We demonstrate that the generalized activity reduces to the standard master-equation definition in the weak-coupling regime for generic systems of N coupled quantum dots described by a quadratic Hamiltonian, and analyze the resulting QKUR bound in paradigmatic quantum-coherent mesoscopic devices, including single- and double-quantum dot systems and a quantum point contact.
The kinetic uncertainty relation (KUR) bounds the signal-to-noise ratio of stochastic currents in terms of the number of transitions per unit time, known as the dynamical activity. This bound was derived in a classical context and can be violated in the quantum regime due to coherent effects. However, the precise connection between KUR violations and quantum coherence has so far remained elusive, despite significant investigation. In this Letter, we solve this problem by deriving a modified bound that exactly pinpoints how, and when, coherence might lead to KUR violations. Our bound is sensitive to the specific kind of unraveling of the quantum master equation. It, therefore, allows one to compare quantum jumps and quantum diffusion, and understand, in each case, how quantum coherence affects fluctuations. We illustrate our result on a double quantum dot, where the electron current is monitored either by electron jump detection or with continuous diffusive charge measurement.
Thermodynamic (TUR) and kinetic (KUR) uncertainty relations are fundamental bounds constraining the fluctuations of current observables in classical, nonequilibrium systems. Several works have verified, however, violations of these classical bounds in open quantum systems, motivating the derivation of new quantum TURs and KURs that account for the role of quantum coherence. Here, we go one step further by deriving multidimensional KUR and TUR for multiple observables in open quantum systems undergoing Markovian dynamics. Our derivation exploits a multiparameter metrology approach, in which the Fisher information matrix plays a central role. Crucially, our bounds are tighter than previously derived quantum TURs and KURs for single observables, precisely because they incorporate correlations between multiple observables. We also find an intriguing quantum signature of correlations that is captured by the off-diagonal element of the Fisher information matrix, which vanishes for classical stochastic dynamics. By considering two examples, namely a coherently driven qubit system and the three-level maser, we demonstrate that the multidimensional quantum KUR bound can even be saturated when the observables are perfectly correlated.
The thermodynamic uncertainty relation (TUR) imposes a fundamental constraint between current fluctuations and entropy production, providing a refined formulation of the second law for micro- and nanoscale systems. Quantum violations of the classical TUR reveal genuinely quantum thermodynamic effects, which are essential for improving performance and enabling optimization in quantum technologies. In this work, we analyze the TUR in a class of paradigmatic quantum thermal-machine models whose operation is enabled by coherent coupling between two energy levels forming a virtual qubit. Steady-state coherences are confined to this virtual-qubit subspace, while in the absence of coherent coupling the system satisfies detailed balance with the thermal reservoirs and supports no steady-state heat currents. We show that the steady-state currents and entropy production can be fully reproduced by an effective classical Markov process, whereas current fluctuations acquire an additional purely quantum correction originating from coherence. As a result, the thermodynamic uncertainty naturally decomposes into a classical (diagonal) contribution and a coherent contribution. The latter becomes negative under resonant conditions and reaches its minimum at the coupling strength that maximizes steady-state coherence. We further identify the conditions for minimizing the thermodynamic uncertainty, and the criteria for surpassing the classical TUR bound in the vicinity of the reversible limit.
The minimal bound of the thermodynamic uncertainty relation (TUR) is modulated from that of the classical counterpart ( Q min = 2 ) when a quantumness is present in the dynamical process far from equilibrium. A recent study on a dissipative two-level system (TLS) subject to an external field indicates that quantum coherence can suppress the fluctuations of the irreversible current and loosens the TUR bound to Q min TLS ≈ 1.25 . Here, by extending the field-driven single TLS to a quantum mechanically coupled two-qubit system (TQS), we explore how the quantum coupling between the two qubits, an additional complexity introduced to the probem of TLS, affects the photon current, fluctuations, and the TUR bound. We find that the TUR bound of the TQS depends on the strength of coupling, such that Q min TQS = Q min TLS ≈ 1.25 when the two qubits are effectively decoupled under weak coupling, whereas another loose bound Q min TQS ≈ 1.36 is identified for two strongly coupled qubits under strong fields. By contrasting the TQS against two coupled noisy oscillators, we illuminate the quantumness unique to the TQS and its effect on the TUR. Our findings from the study of the TQS form the basis for understanding the TUR of more general N -qubit systems.
Thermodynamic uncertainty relations (TURs), originally discovered for classical systems, dictate the tradeoff between dissipation and fluctuations of irreversible current, specifying a minimal bound that constrains the two quantities. In a series of efforts to extend the relation to the one under more generalized conditions, it has been noticed that the bound is less tight in open quantum processes. To study the origin of the loose bounds, we consider an external field-driven transition dynamics of a two-level quantum system weakly coupled to the bosonic bath as a model of an open quantum system. The model makes it explicit that the imaginary part of quantum coherence, which contributes to dissipation to the environment, is responsible for loosening the TUR bound by suppressing the relative fluctuations in the irreversible current of transitions, whereas the real part of the coherence tightens it. Our study offers a better understanding of how quantum nature affects the TUR bound.