Thermodynamic (TUR) and kinetic (KUR) uncertainty relations are fundamental bounds constraining the fluctuations of current observables in classical, nonequilibrium systems. Several works have verified, however, violations of these classical bounds in open quantum systems, motivating the derivation of new quantum TURs and KURs that account for the role of quantum coherence. Here, we go one step further by deriving multidimensional KUR and TUR for multiple observables in open quantum systems undergoing Markovian dynamics. Our derivation exploits a multiparameter metrology approach, in which the Fisher information matrix plays a central role. Crucially, our bounds are tighter than previously derived quantum TURs and KURs for single observables, precisely because they incorporate correlations between multiple observables. We also find an intriguing quantum signature of correlations that is captured by the off-diagonal element of the Fisher information matrix, which vanishes for classical stochastic dynamics. By considering two examples, namely a coherently driven qubit system and the three-level maser, we demonstrate that the multidimensional quantum KUR bound can even be saturated when the observables are perfectly correlated.
Thermodynamic (TUR) and kinetic (KUR) uncertainty relations are fundamental bounds constraining the fluctuations of current observables in classical, nonequilibrium systems. Several works have verified, however, violations of these classical bounds in open quantum systems, motivating the derivation of new quantum TURs and KURs that account for the role of quantum coherence. Here, we go one step further by deriving multidimensional KUR and TUR for multiple observables in open quantum systems undergoing Markovian dynamics. Our derivation exploits a multiparameter metrology approach, in which the Fisher information matrix plays a central role. Crucially, our bounds are tighter than previously derived quantum TURs and KURs for single observables, precisely because they incorporate correlations between multiple observables. We also find an intriguing quantum signature of correlations that is captured by the off-diagonal element of the Fisher information matrix, which vanishes for classical stochastic dynamics. By considering two examples, namely a coherently driven qubit system and the three-level maser, we demonstrate that the multidimensional quantum KUR bound can even be saturated when the observables are perfectly correlated.
The kinetic uncertainty relation (KUR) constrains fluctuations of individual currents in classical nonequilibrium systems in terms of the dynamical activity, which quantifies the average number of transitions per unit of time. Here, we derive a multi-current KUR (MKUR) establishing the precision limit for multiple currents generated in classical stochastic processes in the nonequilibrium steady state. We then apply our theory to identify quantum devices whose correlated current fluctuations surpass this classical limit by comparing the quantum system to a classical emulator with the same average currents in the steady state. In this way, violations of the emulator's MKUR have a clear physical meaning, i.e., that the quantum-coherent evolution reduces joint current fluctuations below what is possible for a classical Markovian system with the same energy-level structure and incoherent resources. Since the MKUR incorporates correlations between currents, its violation pinpoints nonclassical fluctuations in parameter regimes where the single-current KUR is satisfied. We illustrate the essential and complementary role of these bounds for characterizing joint current precision with two examples: a coherently driven two-level system and an experimentally motivated model of a three-level heat engine subject to parasitic environmental couplings.
The precision and response of trajectory observables offer valuable insights into the behavior of nonequilibrium systems. For classical systems, trade-offs between these characteristics and thermodynamic costs, such as entropy production and dynamical activity, have been established through uncertainty relations. Quantum systems, however, present unique challenges, where quantum coherence can enhance precision and violate classical uncertainty relations. In this study, we derive trade-off relations for stochastic observables in Markovian open quantum systems. Specifically, we present three key results: (i) a quantum generalization of the thermokinetic uncertainty relation, which bounds the relative fluctuations of currents in terms of entropy production and dynamical activity; (ii) a quantum inverse uncertainty relation, which constrains the relative fluctuations of arbitrary counting observables based on their instantaneous fluctuations and the spectral gap of the symmetrized Liouvillian; and (iii) a quantum response kinetic uncertainty relation, which bounds the response of general observables to kinetic perturbations in terms of dynamical activity. These fundamental bounds, validated numerically using a three-level maser and a boundary-driven X X Z spin chain, provide a comprehensive framework for understanding the interplay between precision, response, and thermodynamic costs in quantum systems.
Thermodynamic uncertainty relations (TURs) and kinetic uncertainty relations (KURs) provide tradeoff relations between measurement fluctuation and thermodynamic cost, such as entropy production and activity. Conventionally, these relations are derived using the Cramér-Rao inequality, which involves an auxiliary perturbation in deterministic differential equations governing the time evolution of the system’s probability distribution. In this study, without relying on the previous formulation based on a deterministic evolving equation, we demonstrate that the main previously discovered uncertainty relations can be derived solely through the stochastic representation of the same dynamics. For this purpose, we propose a unified method based on stochastic representations for general Markovian dynamics. Extending beyond classical systems, we apply this method to Markovian open quantum systems by unraveling their dynamics, deriving quantum uncertainty relations that are tighter than existing ones in regimes where quantum effects play a significant role. This fully establishes uncertainty relations for both classical and quantum systems as intrinsic properties of their stochastic nature. Thermodynamic and kinetic uncertainty relations describe trade-offs between measurement fluctuations and thermodynamic costs, such as entropy production and activity. In this work, the authors present a general framework for deriving uncertainty relations in classical and quantum systems, leveraging the intrinsic stochastic properties of these systems.
Fluctuations are intrinsic to microscopic systems and impose fundamental limits on nonequilibrium precision, as captured by the thermodynamic uncertainty relation (TUR), which links current fluctuations to entropy production. While feedback control is expected to further suppress fluctuations, its role within the TUR framework has remained unclear, particularly in quantum systems where control is inherently information-driven. In this Letter, we consider open quantum systems weakly coupled to a thermal environment, in which quantum jumps are continuously monitored, and Markovian feedback is applied. Using quantum mutual information to quantify the information contribution induced by feedback, we derive a finite-time TUR for arbitrary time-integrated currents in terms of entropy production and mutual information. Our results uncover how feedback control suppresses fluctuations together with thermodynamic cost and establish a fundamental precision bound imposed by information-based control. As an application, we analyze a quantum clock model and demonstrate that the clock precision can be enhanced by feedback control in the presence of a single thermal reservoir.
The kinetic uncertainty relation (KUR) bounds the signal-to-noise ratio of stochastic currents in terms of the number of transitions per unit time, known as the dynamical activity. This bound was derived in a classical context and can be violated in the quantum regime due to coherent effects. However, the precise connection between KUR violations and quantum coherence has so far remained elusive, despite significant investigation. In this Letter, we solve this problem by deriving a modified bound that exactly pinpoints how, and when, coherence might lead to KUR violations. Our bound is sensitive to the specific kind of unraveling of the quantum master equation. It, therefore, allows one to compare quantum jumps and quantum diffusion, and understand, in each case, how quantum coherence affects fluctuations. We illustrate our result on a double quantum dot, where the electron current is monitored either by electron jump detection or with continuous diffusive charge measurement.
Thermodynamic uncertainty relations (TURs) represent one of the few broad-based and fundamental relations in our toolbox for tackling the thermodynamics of nonequilibrium systems. One form of TUR quantifies the minimal energetic cost of achieving a certain precision in determining a nonequilibrium current. In this initial stage of our research program, our goal is to provide the quantum theoretical basis of TURs using microphysics models of linear open quantum systems where it is possible to obtain exact solutions. In paper [Dong et al., Entropy 2022, 24, 870], we show how TURs are rooted in the quantum uncertainty principles and the fluctuation-dissipation inequalities (FDI) under fully nonequilibrium conditions. In this paper, we shift our attention from the quantum basis to the thermal manifests. Using a microscopic model for the bath's spectral density in quantum Brownian motion studies, we formulate a "thermal" FDI in the quantum nonequilibrium dynamics which is valid at high temperatures. This brings the quantum TURs we derive here to the classical domain and can thus be compared with some popular forms of TURs. In the thermal-energy-dominated regimes, our FDIs provide better estimates on the uncertainty of thermodynamic quantities. Our treatment includes full back-action from the environment onto the system. As a concrete example of the generalized current, we examine the energy flux or power entering the Brownian particle and find an exact expression of the corresponding current-current correlations. In so doing, we show that the statistical properties of the bath and the causality of the system+bath interaction both enter into the TURs obeyed by the thermodynamic quantities.