Dynamical phases are obtained for a quantum thermal engine, whose working medium is a single harmonic oscillator. The dynamics of this engine is obtained by using four steps where in two steps the time dependent frequency is changing. In the other two steps, the thermal engine is coupled alternatively to hot and cold heat baths. Similar dynamical phases are obtained in a quantum thermal engine whose working medium is spin 1/2 system. The role of times durations of such steps in the quantum engines for getting maximal efficiency is analyzed. The dynamic of charge pumping in a quantum dot coupled to two reservoirs is studied. The effects of many modulation parameters including their fluctuations for getting geometric phases are analyzed. Since the separate steps in thermal engines describe non-cyclic circuits, we propose to use a special method for measuring geometric phases in thermal engines for non-cyclic circuits which is gauge invariant.
Dynamical phases are obtained for a quantum thermal engine, whose working medium is a single harmonic oscillator. The dynamics of this engine is obtained by using four steps where in two steps the time dependent frequency is changing. In the other two steps, the thermal engine is coupled alternatively to hot and cold heat baths. Similar dynamical phases are obtained in a quantum thermal engine whose working medium is spin 1/2 system. The role of times durations of such steps in the quantum engines for getting maximal efficiency is analyzed. The dynamic of charge pumping in a quantum dot coupled to two reservoirs is studied. The effects of many modulation parameters including their fluctuations for getting geometric phases are analyzed. Since the separate steps in thermal engines describe non-cyclic circuits, we propose to use a special method for measuring geometric phases in thermal engines for non-cyclic circuits which is gauge invariant.
Quantum Carnot engine whose working medium is a two-dimensional spin 1/2 system, with a time-dependent magnetic field in the symmetric z direction is described. The dynamic of this engine is obtained by using four steps, where in two steps the system is coupled alternatively to hot and cold heat baths, and in the other two steps the time development is adiabatic and isentropic (with constant entropy). The conditions for getting a reversible Carnot cycle and the role of time duration for its irreversibility are discussed. Since the calculations are made for the expectation values of the Hamiltonian, only dynamical phases are obtained which cannot be used for interference effects. An alternative method is developed for getting geometric phases, which can be used in interferometry. Parallel transport equations for pure states are generalized to mixed states by which dynamical phases are eliminated. The geometric phases are derived by unitary SU(2) transformations, including time-dependent parameters which are a function of the magnetic fields interactions. A special form of the unitary transformation for the mixed thermal states is developed, by which geometric phases are obtained, which are different from those obtained in NMR and neutron interferometry.
We discuss whether, and under which conditions, it is possible to realize a heat engine simply by dynamically modulating the couplings between the quantum working medium and thermal reservoirs. For that purpose, we consider the paradigmatic model of a quantum harmonic oscillator, exposed to a minimal modulation, that is, a monochromatic driving of the coupling to only one of the thermal baths. We demonstrate, at any order in the system/bath coupling strength, that in this setup non-Markovianity of the bath is a necessary condition to obtain a heat engine. In addition, we identify suitable structured environments for the engine to approach the ideal Carnot efficiency. Our results open up new possibilities for the use of non-Markovian open quantum systems for the construction and optimization of quantum thermal machines.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
In this work we study the effect of quantum and thermal fluctuations on the statistics of quantum heat engine performance parameters, like efficiency and power. We begin by deriving an explicit solution for the characteristic function of the heat distribution of a thermal quantum harmonic oscillator. We then derive a general framework based on the standard two-point-measurement scheme to compute the efficiency distribution of a quantum Otto cycle. We analyze the generic properties of this distribution for scale-invariant driving Hamiltonians which describe a large class of single-particle, many-body, and nonlinear systems. We find that the efficiency is deterministic and that its mean is equal to the macroscopic efficiency for adiabatic driving. We continue our research by studying the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follow the ’universal’ theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We can relate this unusual property to the perfect anticorrelation between work output and heat input that suppresses thermal as well as quantum fluctuations. We then probe our findings in an experimental NMR setup using spin-1/2 systems and find them to agree rather well with our theoretical predictions. Afterward, we move on to the finite-time quantum Carnot cycle and investigate its power fluctuations. In particular, we consider how level degeneracy and level number, two commonly found properties in quantum systems, influence the relative work fluctuations. We find that their optimal performance may surpass those of nondegenerate two-level engines or harmonic oscillator motors. Our results highlight that these parameters can be employed to realize high-performance, high-stability cyclic quantum heat engines.
Abstract In the quest for high-performance quantum thermal machines, looking for an optimal thermodynamic efficiency is only part of the issue. Indeed, at the level of quantum devices, fluctuations become extremely relevant and need to be taken into account. In this paper we study the thermodynamic uncertainty relations for a quantum thermal machine with a quantum harmonic oscillator as a working medium, connected to two thermal baths, one of which is dynamically coupled. We show that parameters can be found such that the machine operates both as a quantum engine or refrigerator, with both sizeable efficiency and small fluctuations.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.