Abstract We formalize and prove the extension to finite temperature of a class of quantum phase transitions, acting as condensations in the space of states, recently introduced and discussed at zero temperature (Ostilli and Presilla 2021 J. Phys. A: Math. Theor. 54 055005). In details, we find that if, for a quantum system at canonical thermal equilibrium, one can find a partition of its Hilbert space into two subspaces, and , such that, in the thermodynamic limit, dim ℋ cond / dim ℋ → 0 and the free energies of the system restricted to these subspaces cross each other for some value of the Hamiltonian parameters, then, the system undergoes a first-order quantum phase transition driven by those parameters. The proof is based on an exact probabilistic representation of quantum dynamics at an imaginary time identified with the inverse temperature of the system. We also show that the critical surface has universal features at high and low temperatures.
Abstract We formalize and prove the extension to finite temperature of a class of quantum phase transitions, acting as condensations in the space of states, recently introduced and discussed at zero temperature (Ostilli and Presilla 2021 J. Phys. A: Math. Theor. 54 055005). In details, we find that if, for a quantum system at canonical thermal equilibrium, one can find a partition of its Hilbert space into two subspaces, and , such that, in the thermodynamic limit, dim ℋ cond / dim ℋ → 0 and the free energies of the system restricted to these subspaces cross each other for some value of the Hamiltonian parameters, then, the system undergoes a first-order quantum phase transition driven by those parameters. The proof is based on an exact probabilistic representation of quantum dynamics at an imaginary time identified with the inverse temperature of the system. We also show that the critical surface has universal features at high and low temperatures.
Abstract We demonstrate that a large class of first-order quantum phase transitions, namely, transitions in which the ground state energy per particle is continuous but its first order derivative has a jump discontinuity, can be described as a condensation in the space of states. Given a system having Hamiltonian H = K + gV , where K and V are two non commuting operators acting on the space of states F , we may always write F = F cond ⊕ F norm where F cond is the subspace spanned by the eigenstates of V with minimal eigenvalue and F norm = F cond ⊥ . If, in the thermodynamic limit, M cond / M → 0, where M and M cond are, respectively, the dimensions of F and F cond , the above decomposition of F becomes effective, in the sense that the ground state energy per particle of the system, ϵ , coincides with the smaller between ϵ cond and ϵ norm , the ground state energies per particle of the system restricted to the subspaces F cond and F norm , respectively: ϵ = min{ ϵ cond , ϵ norm }. It may then happen that, as a function of the parameter g , the energies ϵ cond and ϵ norm cross at g = g c . In this case, a first-order quantum phase transition takes place between a condensed phase (system restricted to the small subspace F
We extend the analysis of the class of quantum phase transitions (QPTs) that can be interpreted as condensations in state space, first introduced in [M. Ostilli and C. Presilla, J. Phys. A 54, 055005 (2021)], by generalizing the arguments of [M. Ostilli and C. Presilla, Phys. Rev. Lett. 127, 040601 (2021)] to prove the existence and determine the location (via simple bounds) of QPTs in general one-parameter lattice Hamiltonians. Unlike our original formulation, this extension also encompasses second-order QPTs, for which we provide the explicit example of the transverse-field Ising model. Our analysis suggests that, under conditions typically satisfied in physical contexts, any QPT taking place in lattice systems can be interpreted as a condensation in state space.
A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterized by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The distinguishing feature of the proposed equilibrium state is that the corresponding density of states is a continuous function of the energy, and hence thermodynamic functions are well defined for finite quantum systems. The density of states, however, is not in general an analytic function. It is demonstrated that generic quantum systems therefore exhibit second-order phase transitions at finite temperatures.
A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The distinguishing feature of the proposed equilibrium state is that the corresponding density of states is a continuous function of the energy, and hence thermodynamic functions are well defined for finite quantum systems. The density of states, however, is not in general an analytic function. It is demonstrated that generic quantum systems therefore exhibit second-order (i.e. continuous) phase transitions at finite temperatures.
In nature, everything occurs at finite temperature, and quantum phase transitions (QPTs) cannot be an exception. Nevertheless, they are still mainly discussed and formulated at zero temperature. We show that the condensation QPTs recently introduced at zero temperature can naturally be extended to finite temperature just by replacing ground-state energies with corresponding free energies. We illustrate this criterion in the paradigmatic Grover model and in a system of free fermions in a one-dimensional inhomogeneous lattice. In agreement with expected universal features, the two systems show structurally similar phase diagrams. Last, we explain how finite-temperature condensation QPTs can be used to construct quantum annealers having, at finite temperature, output probability exponentially close to 1 in the system size. As examples we consider again the Grover model and the fermionic system, the latter being well within the reach of present heterostructure technology.
Introduction In the limit of zero temperature, the partition function is dominated by the ground state of the system, the free energy becomes equivalent to the ground state energy, and the central object of interest is the Hamiltonian of the system H (λ), dependent in general on one or more parameters λ. A ‘quantum’ Hamiltonian, as noted previously, is one which contains non-commuting operators. Here we concentrate on quantum spin Hamiltonians, of which the prime example is the Heisenberg model. Of particular interest is the possibility of a quantum phase transition , i.e. nonanalytic behaviour as a function of coupling λ. A quantum phase transition may exert a dominating influence on the system over a range of low temperatures above T = 0. Such phenomena have figured prominently in theoretical discussions of experiments on the cuprate superconductors, the heavy fermion materials, organic conductors, and related materials (e.g. Sachdev, 1999). In some cases, a correspondence can be found between a quantum system at zero temperature in 1 time and ( d – 1) space dimensions, and an equivalent classical system at finite temperature in d space dimensions, based on the Feynman path integral formalism – see Chapter 9 and Appendix 8 for further discussions. Under this mapping, the temperature kT in the classical system corresponds to a coupling λ in the equivalent quantum system. If a phase transition occurs, the same universal critical exponents are expected to apply in both cases.