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arXiv:2209.02527 · Physical review. E

Most general class of quasiprobability distributions of work

Gianluca Francica

Published Nov 14, 2022• 26 citations
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Abstract

How to give a statistical description of the thermodynamics in quantum systems is an open fundamental question. Concerning the work, the presence of initial quantum coherence in the energy basis can give rise to a quasiprobability of work, which can take negative values. Our aim is to identify the most general quasiprobability of work satisfying some fundamental conditions. By doing so, we introduce a general notion of quasiprobability in analogy to Gleason's theorem. Then, we use these quasiprobabilities to define the quasiprobability of work, and finally we discuss the contextuality of the protocol.

DOI
10.1103/physreve.106.054129

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How to give a statistical description of the thermodynamics in quantum systems is an open fundamental question. Concerning the work, the presence of initial quantum coherence in the energy basis can give rise to a quasiprobability of work, which can take negative values. Our aim is to identify the most general quasiprobability of work satisfying some fundamental conditions. By doing so, we introduce a general notion of quasiprobability in analogy to Gleason's theorem. Then, we use these quasiprobabilities to define the quasiprobability of work, and finally we discuss the contextuality of the protocol.
The work is a concept of fundamental importance in thermodynamics. An open question is how to describe the work fluctuation for quantum coherent processes in the presence of initial quantum coherence in the energy basis. With the aim of giving a unified description, here we introduce and study a class of quasiprobability distributions of work, which give an average work equal to the average energy change of the system and reduce to the two-projective measurement scheme for an initial incoherent state. Moreover, we characterize the work with the help of fluctuation relations. In particular, by considering the joint distribution of work and initial quantum coherence, we find a fluctuation theorem involving quantum coherence, from which follows a second law of thermodynamics in the case of initial thermal populations. Furthermore, we propose a way to measure the characteristic function of work and we discuss the negativity of the quasiprobability. The effects of coherence are also investigated for a simple system of a qubit.
The work is a concept of fundamental importance in thermodynamics. An open question is how to describe the work fluctuation for quantum coherent processes in the presence of initial quantum coherence in the energy basis. With the aim of giving a unified description, here we introduce and study a class of quasiprobability distributions of work, which give an average work equal to the average energy change of the system and reduce to the two-projective-measurement scheme for an initial incoherent state. Moreover, we characterize the work with the help of fluctuation relations. In particular, by considering the joint distribution of work and initial quantum coherence, we find a fluctuation theorem involving quantum coherence, from which follows a second law of thermodynamics in the case of initial thermal populations.
A complete understanding of the statistics of the work done by quenching a parameter of a quantum many-body system is still lacking in the presence of an initial quantum coherence in the energy basis. In this case, the work can be represented by a class of quasiprobability distributions. Here, we try to clarify the genuinely quantum features of the process by studying the work quasiprobability for an Ising model in a transverse field. We consider both a global and local quench by focusing mainly on the thermodynamic limit. We find that, while for a global quench there is a symmetric noncontextual representation with a Gaussian probability distribution of work, for a local quench we can get quantum contextuality as signaled by a negative fourth moment of the work. Furthermore, we examine the critical features related to a quantum phase transition and the role of the initial quantum coherence as a useful resource.
Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward out-of-equilibrium quantum process and in a corresponding backward one. In particular, the initial states of the two processes are thermal states and thus incoherent in the energy basis. Here we aim to investigate the role of initial quantum coherence in work fluctuation theorems, by considering a quasiprobability distribution of work. To do this, we formulate and examine the implications of a detailed fluctuation theorem, which reproduces the Tasaki-Crooks fluctuation theorem in the absence of initial quantum coherence.
In quantum thermodynamics, the two-projective-measurement (TPM) scheme provides a successful description of stochastic work only in the absence of initial quantum coherence. Extending the quantum work distribution to quasiprobability is a general way to characterize work fluctuation in the presence of initial coherence. However, among a large number of different definitions, there is no consensus on the most appropriate work quasiprobability. In this article, we list several physically reasonable requirements including the first law of thermodynamics, time-reversal symmetry, positivity of second-order moment, and a support condition for the work distribution. We prove that the only definition that satisfies all these requirements is the Margenau-Hill (MH) quasiprobability of work. In this sense, the MH quasiprobability of work shows its advantages over other definitions. As an illustration, we calculate the MH work distribution of a breathing harmonic oscillator with initial squeezed states and show the convergence to classical work distribution in the classical limit.
In this article, we introduce a quasiprobability distribution of work that is based on the Wigner function. This proposal rests on the idea that the work conducted on an isolated system can be coherently measured by coupling the system to a quantum measurement apparatus. In this way, a quasiprobability distribution of work can be defined in terms of the Wigner function of the apparatus. This quasidistribution contains the information of the work statistics and also holds a clear operational definition that can be directly measured in a real experiment. Moreover, it is shown that the presence of quantum coherence in the energy eigenbasis is related with the appearance of features related to non-classicality in the Wigner function such as negativity and interference fringes. On the other hand, from this quasiprobability distribution, it is straightforward to obtain the standard two-point measurement probability distribution of work and also the difference in average energy for initial states with coherences.