Resonating valence bond states in a doped Mott insulator was proposed to explain superconductivity in cuprates in January 1987 by Anderson. A challenging task then was proving existence of this unconventional mechanism and a wealth of possibilities, with a rigor acceptable in standard condensed matter physics, in a microscopic theory and develop suitable many body techniques. Shortly, a paper by Anderson, Zou and us (BZA) undertook this task and initiated a program. Three key papers that followed, shortly, essentially completed the program, as far as superconductivity is concerned: i) a gauge theory approach by Anderson and us, that went beyond mean field theory ii) Kotliar's d-wave solution in BZA theory iii) improvement of a renormalized Hamiltonian in BZA theory, using a Gutzwiller approximation by Zhang, Gros, Rice and Shiba. In this article I shall focus on the merits of BZA and gauge theory papers. They turned out to be a foundation for subsequent developments dealing with more aspects that were unconventional - d-wave order parameter with nodal Bogoliubov quasi particles, Affleck-Marston's
π-flux condensed spin liquid phase, unconventional spin-1 collective mode at
(π,π), and other fascinating developments. Kivelson, Rokhsar and Sethna's idea of holons and their bose condensation found expression in the slave boson formalism and lead to results similar to BZA program. Further, t-J model is a good minimal model around optimal doping, where RVB superconductivity is also at its best.
Using continuity, we derive a renormalized Hamiltonian from the parent $t\text{\ensuremath{-}}J$ model to describe the properties of underdoped cuprates. The theory is constrained to agree with the behavior at half filling, which is well described by the Arovas-Auerbach valence bond state in which bosonic spinons are paired into singlets. Spinon states evolve continuously into the doped region preserving their symmetry. We assume that moving holes rapidly destroy magnetic order, which leads to a gap in the spinon spectrum and strongly renormalizes the theory. The spin gap leads to two different types hopping terms for renormalized holes. In one, a fermionic holon hops within the same sublattice accompanied by a singlet backflow, giving rise to a non-Fermi-liquid normal state with novel properties. Spinon singlets condense below a pseudogap temperature ${T}^{\ensuremath{\ast}}$ (
< spin gap temperature
T0), which allows holons to propagate coherently, forming a spinless Fermi liquid, but without an observable holon Fermi surface. Above ${T}^{\ensuremath{\ast}}$, holons are localized. This is the so-called strange metal phase, which is actually a new type of insulator since its resistivity would be infinite at
T=0. In the second term a pair of holons belonging to opposite sublattices hop, accompanied by a singlet backflow. In the presence of the singlet condensate holon pairs condense, leading to
d-wave superconductivity; the symmetry is primarily determined by the symmetry of the valence bond state at half filling. The metal and the superconductor preserve the two-sublattice character of the valence bond state. A careful examination of the nuclear magnetic resonance, tunneling, and transport data shows that the predictions of the theory is consistent with experimental results. Remarkably, the existence of the spin gap provides a natural explanation for the phenomenon of two dimensionality of the normal state in the presence of interplane hopping. The marked asymmetry between hole-doped and electron-doped cuprates is also easily explained.
There are two seemingly unrelated puzzles about the cuprate superconductors. The first puzzle concerns the strong non-BCS behavior around
xc, the end point of the superconducting dome on the overdoped side, where the cuprate is believed to be well described by the Fermi-liquid theory. This is the most evident in the observed ${\ensuremath{\rho}}_{s}(0)\ensuremath{-}{T}_{c}$ scaling and the large amount of uncondensed optical spectral weight at low energy. The second puzzle concerns the remarkable robustness of the
d-wave pairing against the inevitable disorder effect in such a doped system, which is also totally unexpected from the conventional BCS picture. Here we show that these two puzzles are deeply connected to the origin of a third puzzle about the cuprate superconductors, namely, the mysterious quantum critical behavior observed around
x∗, the so called pseudogap end point. Through a systematic variational Monte Carlo (VMC) study of the disordered 2D $t\ensuremath{-}J$ model from the resonating valence bond (RVB) perspective, we find that the
d-wave pairing in this model is remarkably more robust against the disorder effect than that in a conventional
d-wave BCS superconductor. We find that such remarkable robustness can be attributed to the spin-charge separation mechanism in the RVB picture, through which the
d-wave RVB pairing of the charge-neutral spinons becomes essentially immune to the disorder potential except for the secondary effect related to the modulation of the local doping level by the disorder. We propose that there exists a Mott transition at
x∗, where the RVB pairing in the underdoped regime is transmuted into the increasingly more BCS-like pairing for
x>x∗, whose increasing fragility against the disorder effect leads to the non-BCS behavior and the ultimate suppression of superconductivity around
xc.
In recent years there has been significant work aimed at understanding what effect the variation of electronic doping has on material properties. In the high transition-temperature (high-T
c) cuprate superconductors hole doping has an impact on the superconducting transition temperature. In the underdoped regime, the cuprates exhibit anomalous properties due to a pseudogap which forms and is thought to be related to Mott insulating physics. While there is no general consensus as to the mechanism underlying high temperature superconductivity, the resonating valence bond (RVB) theory proposed by Anderson in 1987 with a Gutzwiller projected d-wave BCS wave function could give a first picture of the high-T
c cuprates. We have calculated properties of the cuprates using the assumption that the pseudogap state acts as a normal state to an otherwise standard BCS mean field theory. We find that the phenomenological RVB spin liquid model proposed by Yang, Rice and Zhang (YRZ) is highly successful at describing the doping dependent features of the cuprates. Through application of the YRZ model and the tools of many-body theory we present results on anomalous properties observed in: electronic specific heat; Raman and angle-resolved photoemission spectroscopy (ARPES) data; effective mass renormalization; and thermal broadening seen in ARPES. We verify that the YRZ ansatz qualitatively describes these anomalies along with their doping dependent variations. We conclude from this work that the physics underlying the pseudogap, while distinct in origin from superconductivity, is likely to arise from an RVB wavefunction that is closely related to the BCS state. In graphene, variation in doping modifies the polarization function which describes a screened electron-electron interaction. This leads to additional features in the spectral function which are due to electron-plasmon coupling. In this work, we calculated the electronic density of states including this interaction along with its doping dependence with and without an electron-phonon interaction. We find clear features of electron-electron interactions in the density of states. These features are related to the energies of plasmaron bands in the spectral function and can be modified through doping so as to be distinct from the phonon energy scales.
There are two seemingly unrelated puzzles about the cuprate superconductors. The first puzzle concerns the strong non-BCS behavior around
xc, the end point of the superconducting dome on the overdoped side, where the cuparte is believed to be well described by the fermi liquid theory. This is the most evident in the observed
ρs(0)−Tc scaling and the large amount of uncondensed optical spectral weight at low energy. The second puzzle concerns the remarkable robustness of the d-wave pairing against the inevitable disorder effect in such a doped system, which is also totally unexpected from the conventional BCS picture. Here we show that these two puzzles are deeply connected to the origin of a third puzzle about the cuprate superconductors, namely, the mysterious quantum critical behavior observed around
x∗, the so-called pseudogap end point. Through a systematic variational optimization of the disordered 2D
t−J model from the resonating valence bond(RVB) perspective, we find that the d-wave pairing in this model is remarkably more robust against the disorder effect than that in a conventional d-wave BCS superconductor. We find that such remarkable robustness can be attributed to the spin-charge separation mechanism in the RVB picture, through which the d-wave RVB pairing of the charge neutral spinons becomes essentially immune to the impurity potential except for the secondary effect related to the modulation of the local doping level by the disorder. We propose that there exists a Mott transition at
x∗, where the RVB pairing in the underdoped regime is transmuted into the increasingly more BCS-like pairing for
x>x∗, whose increasing fragility against the disorder effect leads to the non-BCS behavior and the ultimate suppression of superconductivity around
xc.
We use an effective Hamiltonian for two-dimensional Hubbard model including an antiferromagnetic spin-spin coupling term to study recently proposed Gossamer superconductivity. We apply a renormalized mean field theory to approximately take into account the strong correlation effect in partially projected Gutzwiller wave functions. At the half-filling, there is a first order phase transition to separate a Mott insulator at large Coulomb repulsion
U from a Gossamer superconductor at small
U. At the critical value
U=Uc, the charge carrier density and the superconducting (SC) order parameter change discontinuously from zero in the Mott insulating phase to finite values in the Gossamer SC phase. The first order transition is due to the interplay of the kinetic and spin exchange energies. As the electron density changes away from half-filling, the Gossamer SC state changes smoothly, while the Mott insulator is evolved into a resonating valence bond (RVB) SC state. The Gossamer and RVB SC states have the same pairing symmetry. The SC order parameter changes smoothly from a RVB SC state at
U>Uc to a Gossamer SC state at
U<Uc at a fixed nonhalf-filled electron density. We argue that the RVB SC state is smoothly connected to the Gossamer SC state, hence to the BCS state.