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arXiv:2205.09400 · Physical review. E

Quantum Otto cycle under strong coupling

Mao Kaneyasu, Yoshihiko Hasegawa

Published Apr 27, 2023• 21 citations
arXivHTMLPDF

Abstract

Quantum heat engines are often discussed under the weak-coupling assumption that the interaction between the system and the reservoirs is negligible. Although this setup is easier to analyze, this assumption cannot be justified on the quantum scale. In this study, a quantum Otto cycle model that can be generally applied without the weak-coupling assumption is proposed. We replace the thermalization process in the weak-coupling model with a process comprising thermalization and decoupling. The efficiency of the proposed model is analytically calculated and indicates that, when the contribution of the interaction terms is neglected in the weak-interaction limit, it reduces to that of the earlier model. The sufficient condition for the efficiency of the proposed model not to surpass that of the weak-coupling model is that the decoupling processes of our model have a positive cost. Moreover, the relation between the interaction strength and the efficiency of the proposed model is numerically examined by using a simple two-level system. Furthermore, we show that our model's efficiency can surpass that of the weak-coupling model under particular cases. From analyzing the majorization relation, we also find a design method of the optimal interaction Hamiltonians, which are expected to provide the maximum efficiency of the proposed model. Under these interaction Hamiltonians, the numerical experiment shows that the proposed model achieves higher efficiency than that of its weak-coupling counterpart.

DOI
10.1103/physreve.107.044127

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Quantum heat engines are often discussed under the weak-coupling assumption that the interaction between the system and the reservoirs is negligible. Although this setup is easier to analyze, this assumption cannot be justified on the quantum scale. In this study, a quantum Otto cycle model that can be generally applied without the weak-coupling assumption is proposed. We replace the thermalization process in the weak-coupling model with a process comprising thermalization and decoupling. The efficiency of the proposed model is analytically calculated and indicates that, when the contribution of the interaction terms is neglected in the weak-interaction limit, it reduces to that of the earlier model. The sufficient condition for the efficiency of the proposed model not to surpass that of the weak-coupling model is that the decoupling processes of our model have a positive cost. Moreover, the relation between the interaction strength and the efficiency of the proposed model is numerically examined by using a simple two-level system. Furthermore, we show that our model's efficiency can surpass that of the weak-coupling model under particular cases. From analyzing the majorization relation, we also find a design method of the optimal interaction Hamiltonians, which are expected to provide the maximum efficiency of the proposed model. Under these interaction Hamiltonians, the numerical experiment shows that the proposed model achieves higher efficiency than that of its weak-coupling counterpart.
We study a quantum heat engine at strong coupling between the system and the thermal reservoirs. Exploiting a collective coordinate mapping, we incorporate system-reservoir correlations into a consistent thermodynamic analysis, thus circumventing the usual restriction to weak coupling and vanishing correlations. We apply our formalism to the example of a quantum Otto cycle, demonstrating that the performance of the engine is diminished in the strong coupling regime with respect to its weakly coupled counterpart, producing a reduced net work output and operating at a lower energy conversion efficiency. We identify costs imposed by sudden decoupling of the system and reservoirs around the cycle as being primarily responsible for the diminished performance, and we define an alternative operational procedure which can partially recover the work output and efficiency. More generally, the collective coordinate mapping holds considerable promise for wider studies of thermodynamic systems beyond weak reservoir coupling.
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been shown earlier that the said interaction provides an enhancement of cycle efficiency, with an upper bound that is tighter than the Carnot efficiency. However, the necessary conditions governing engine performance and the relevant upper bound for efficiency are unknown for the general case of arbitrary spin magnitudes. By analyzing extreme case scenarios, we formulate heuristics to infer the necessary conditions for an engine with uncoupled as well as coupled spin model. These conditions lead us to a connection between performance of quantum heat engines and the notion of majorization. Furthermore, the study of complete Otto cycles inherent in the average cycle also yields interesting insights into the average performance.
Algebraic methods for solving time-dependent Hamiltonians are used to investigate the performance of quantum thermal machines. We investigate the thermodynamic properties of an engine formed by two coupled qubits, performing an Otto cycle. The thermal interaction occurs with two baths at different temperatures, while work is associated with the interaction with an arbitrary time-dependent magnetic field that varies in intensity and direction. For the coupling, we consider the 1D isotropic Heisenberg model, which allows us to describe the system by means of the irreducible representation of the su(2)\mathrm{su}(2)su(2) Lie algebra within the triplet subspace. We also inspect different settings of the temperatures and frequencies of the cycle, and investigate the corresponding operation regimes. We describe how these regimes can change with the speed of the protocol. Finally, we compare the weak and strong coupling regimes, and conclude that for the weak case the efficiency is optimal and can surpass the value of the classical Otto cycle. For low temperatures of the heat baths, we show that losses due to quantum friction are reduced in the strong coupling limit.
Abstract The efficiency of a quantum heat engine is maximum when the unitary strokes of the quantum Otto cycle are adiabatic. On the other hand, this may not be always possible due to small energy gaps in the system, especially at the critical point (CP) where the gap between the ground state and the first excited state vanishes and the system gets excited. With the aim to regain this lost adiabaticity, we modify one of the unitary strokes of the Otto cycle by allowing the system to first evolve with a time dependent Hamiltonian as in the case of a usual Otto cycle, followed by an additional evolution with a different time independent Hamiltonian so that the system reaches a less excited state. This will help in increasing the magnitude of the heat absorbed from the hot bath so that the work output and efficiency of the engine can be increased. We demonstrate this method using an integrable model and a non-integrable model as the working medium and discuss the generality and limitations of this method. In the case of a two spin system, the optimal value for the time till which the system needs to be freely evolved is calculated analytically in the adiabatic limit. The results show that implementing this modified unitary stroke significantly improves the work output and efficiency of the engine, especially when it crosses the CP.
Enhancement of thermal efficiency of quantum heat engines has been discussed mainly in terms of quantumness of working substances. In the present study, we propose as another possibility to utilize a quantum-mechanical (reversible) feature of system-reservoir interaction, which reveals itself in the short-time regime as a non-Markovian effect on the reduced dynamics of the substance, before asymptotically approaching irreversible processes. For this purpose, we study a limit cycle of the quantum Otto engine comprising a working two-level system and two reservoirs, including the non-Markovian effect for the finite-time isochoric processes while the work-extracting processes are kept quantum adiabatic. Assuming that the system interacts weakly with the reservoirs consisting of infinite bosons, we find a parameter regime beyond the Carnot efficiency in which a positive work is extracted by including a non-Markovian effect called energy backflow. We also find that the interaction energy is finite and contributes to the positive work even for the weak interaction. The work diminishes if we include into the work the energy for detaching the working substance from reservoirs.
This study presents a comparative analysis of three quantum thermal engines utilizing a two-qubit Heisenberg XXZ chain as the working substance. A novel generalized quantum Otto cycle (GQOC) is introduced, featuring two distinct coupling configurations to thermal reservoirs. The GQOC exhibits the potential for 100% efficiency, surpassing the efficiency of the conventional quantum Otto cycle. Essential conditions for positive work extraction and achieving maximum unity efficiency are derived. An experimental implementation using quantum electrodynamic circuits and Transmon qudit is proposed. This work contributes to the advancement of quantum heat engines, highlighting the benefits of nonequilibrium processes and asymmetric coupling for enhanced work extraction and efficiency.