We consider quantum batteries given by composite interacting quantum systems in terms of the thermodynamic work cost of local random unitary processes. We characterize quantum correlations by monitoring the average energy change and its fluctuations in the high-dimensional bipartite systems. We derive a hierarchy of bounds on high-dimensional entanglement (the so-called Schmidt number) from the work fluctuations and thereby show that larger work fluctuations can verify the presence of stronger entanglement in the system. Finally, we develop two-point measurement protocols with noisy detectors that can estimate work fluctuations, showing that the dimensionality of entanglement can be probed in this manner.
We consider quantum batteries given by composite interacting quantum systems in terms of the thermodynamic work cost of local random unitary processes. We characterize quantum correlations by monitoring the average energy change and its fluctuations in the high-dimensional bipartite systems. We derive a hierarchy of bounds on high-dimensional entanglement (the so-called Schmidt number) from the work fluctuations and thereby show that larger work fluctuations can verify the presence of stronger entanglement in the system. Finally, we develop two-point measurement protocols with noisy detectors that can estimate work fluctuations, showing that the dimensionality of entanglement can be probed in this manner.
Within quantum thermodynamics, many tasks are modeled by processes that require work sources represented by out-of-equilibrium quantum systems, often dubbed quantum batteries, in which work can be deposited or from which work can be extracted. Here we consider quantum batteries modeled as finite-dimensional quantum systems initially in thermal equilibrium that are charged via cyclic Hamiltonian processes. We present optimal or near-optimal protocols for N identical two-level systems and individual d-level systems with equally spaced energy gaps in terms of the charging precision and work fluctuations during the charging process. We analyze the trade-off between these figures of merit as well as the performance of local and global operations.
In this paper, we consider fluctuations in a three-stroke cycle based on quantum measurement. In the first stroke, the engine is fueled by a nonselective quantum measurement; in the second stroke, an appropriate unitary operation is applied to extract work; and finally, the working medium is thermalized to complete the cycle. This protocol is analogous to charging, then discharging, and finally thermalizing a quantum battery. Using the Kirkwood-Dirac quasiprobability, we derive equations that provide insights into the fluctuations of heat and work, and thus into the charging and discharging processes. We then propose a quantum circuit to measure the cumulants of work and heat using a qubit ancilla. Afterward, we derive important upper and lower bounds on fluctuations in heat; this is thanks to the way we decompose heat fluctuations and the Kadison-Schwarz inequality. We also show, for the first time, that the imaginary part of the second cumulant of work equals the linear response of an average work (to be defined in the main text) or the quantum cross entropy. We further introduce an operator whose average defines the battery capacity and whose variance quantifies the corresponding fluctuations of the battery capacity. Our analytical results are illustrated and discussed through representative examples. We believe that our study will, on the one hand, be useful for understanding fluctuations in energy extracted from and injected into quantum batteries based on quantum measurements and, on the other hand, contribute to the foundations of quantum thermodynamics. More generally, our results can be applied beyond the three-stroke cycle considered here, especially to quantum batteries subject to environmental noise and decoherence.
Charging a quantum battery through a pumped charger can lock a substantial part of its stored energy inside the bipartite correlations that grow between the constituent cells, and this \emph{correlation ergotropy}, being the energy that no local single-cell operation can reach and that only collective operations can recover, is the object of the present study. Following the charging trajectory of two coupled three-level cells, we find that the correlation ergotropy closely tracks the logarithmic negativity, which shows that the locked energy is carried by genuine bipartite entanglement rather than by coherent collective dynamics alone, and that an equal-strength coherent non-entangling drive produces no such locking at all. For a pure two-cell battery we establish an exact, basis-independent closed form in which the locked energy depends only on the sorted eigenvalues of the reduced cell and the cell energy levels, revealing that the locked fraction rises from zero at the separable corners of the Schmidt simplex to unity at the symmetric maximally entangled state and remains invariant under local unitaries. Decoherence and dephasing, which destroy the correlations, do \emph{not} release this energy but erase it, so extraction must be collective and must take place while the correlations persist, while cold damping leaves the effect intact and thermal occupation suppresses it. These results give a resource-theoretic reading of correlations in quantum batteries, sharpen the line between genuine entanglement and coherent collective dynamics, and point to experimentally accessible conditions for correlated-charge and collective-extraction protocols.
The Schmidt coefficients capture all entanglement properties of a pure bipartite state and therefore determine its usefulness for quantum information processing. While the quantification of the corresponding properties in mixed states is important both from a theoretical and a practical point of view, it is considerably more difficult, and methods beyond estimates for the concurrence are elusive. In particular this holds for a quantitative assessment of the most valuable resource, the forms of entanglement that can only exist in high-dimensional systems. We derive a framework for lower bounding the appropriate measure of entanglement, the so-called G-concurrence, through few local measurements. Moreover, we show that these bounds have relevant applications also for multipartite states.
In realistic situations, physical systems can not be completely isolated from its environment. Its inevitable interaction with the environment can influence the working process of the device. In this paper, we consider two-qubit quantum batteries where one qubit of the battery is successively interacting with the spins present in the surrounding environment. We examine the effect of the interaction on the maximum amount of energy that can be extracted from the battery using unitaries. In this context, we use the notion of locally passive states. In particular, we examine the behavior of the amount of extractable work from the noisy battery, initially prepared in a locally passive or ordinary pure state, having a fixed initial entanglement, with the number of interactions the qubit has gone through. We also examine the amount of locally extractable work from the noisy battery. We realize though the amount of extractable energy, be it global or local, as a whole will decrease with the number of spins of environment it interacted with, but if we increase the time interval of the interaction with each spin, after a cut off value of the interval, the small time behavior shows a peculiarity, i.e., the extractable energy within a single interaction starts to increase with time. The cut-off time indicates the Markovian-to-non-Markovian transition of the interaction. We also observe a non-Markovian increase in extractable energy from the Markovian scenario.
The heat capacity of a system quantifies how it energetically responds to changes in temperature at equilibrium. Whilst this quantity is positive and even additive for non-interacting systems, self-gravitating systems such as stars or subsystems of strongly interacting quantum systems are known to have negative or anomalous specific heat capacities. In this work, we investigate how the presence of entanglement at equilibrium can influence how an interacting system responds energetically to changes in temperature. We examine the local heat capacity of interacting quantum systems providing an analytical understanding for when anomalies occur. Most interestingly, we find a connection between local heat capacity anomalies and entanglement by deriving a separability bound based on the fluctuations of local and interaction energies. We illustrate our results with two examples (i) a nearest neighbour spin-1/2 chain and (ii) two coupled quantum harmonic oscillators. Lastly, we provide an information-theoretic formula connecting mutual information and athermality to the non-additivity of the heat capacity. Our results provide model-independent thermodynamic entanglement detection bounds and insight into the relationship between quantum correlations and the heat capacity of quantum systems.