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arXiv:2205.00653 · Journal of Mathematical Physics

The asymmetric valence-bond-solid states in quantum spin chains: The difference between odd and even spins

Daisuke Maekawa, Hal Tasaki

Published Mar 1, 2023• 7 citations
arXivHTMLPDF

Abstract

The qualitative difference in low-energy properties of spin S quantum antiferromagnetic chains with integer S and half-odd-integer S discovered by Haldane [F. D. M. Haldane, arXiv:1612.00076 (1981); Phys. Lett. A 93, 464–468 (1983); Phys. Rev. Lett. 50, 1153–1156 (1983)] and Tasaki [Tasaki, Graduate Texts in Physics (Springer, 2020)] can be intuitively understood in terms of the valence-bond picture proposed by Affleck et al. [I. Affleck, Phys. Rev. Lett. 59, 799 (1987); Commun. Math. Phys. 115, 477–528 (1988)]. Here, we develop a similarly intuitive diagrammatic explanation of the qualitative difference between chains with odd S and even S, which is at the heart of the theory of symmetry-protected topological (SPT) phases. (There is a 24 min video in which the essence of the present work is discussed: https://youtu.be/URsf9e_PLlc.) More precisely, we define one-parameter families of states, which we call the asymmetric valence-bond solid (VBS) states, that continuously interpolate between the Affleck–Kennedy–Lieb–Tasaki (AKLT) state and the trivial zero state in quantum spin chains with S = 1 and 2. The asymmetric VBS state is obtained by systematically modifying the AKLT state. It always has exponentially decaying truncated correlation functions and is a unique gapped ground state of a short-ranged Hamiltonian. We also observe that the asymmetric VBS state possesses the time-reversal, the Z2×Z2, and the bond-centered inversion symmetries for S = 2 but not for S = 1. This is consistent with the known fact that the AKLT model belongs to the trivial SPT phase if S = 2 and to a nontrivial SPT phase if S = 1. Although such interpolating families of disordered states were already known, our construction is unified and is based on a simple physical picture. It also extends to spin chains with general integer S and provides us with an intuitive explanation of the essential difference between models with odd and even spins.

DOI
10.1063/5.0123743

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The qualitative difference in low-energy properties of spin S quantum antiferromagnetic chains with integer S and half-odd-integer S discovered by Haldane [F. D. M. Haldane, arXiv:1612.00076 (1981); Phys. Lett. A 93, 464–468 (1983); Phys. Rev. Lett. 50, 1153–1156 (1983)] and Tasaki [Tasaki, Graduate Texts in Physics (Springer, 2020)] can be intuitively understood in terms of the valence-bond picture proposed by Affleck et al. [I. Affleck, Phys. Rev. Lett. 59, 799 (1987); Commun. Math. Phys. 115, 477–528 (1988)]. Here, we develop a similarly intuitive diagrammatic explanation of the qualitative difference between chains with odd S and even S, which is at the heart of the theory of symmetry-protected topological (SPT) phases. (There is a 24 min video in which the essence of the present work is discussed: https://youtu.be/URsf9e_PLlc.) More precisely, we define one-parameter families of states, which we call the asymmetric valence-bond solid (VBS) states, that continuously interpolate between the Affleck–Kennedy–Lieb–Tasaki (AKLT) state and the trivial zero state in quantum spin chains with S = 1 and 2. The asymmetric VBS state is obtained by systematically modifying the AKLT state. It always has exponentially decaying truncated correlation functions and is a unique gapped ground state of a short-ranged Hamiltonian. We also observe that the asymmetric VBS state possesses the time-reversal, the Z2×Z2, and the bond-centered inversion symmetries for S = 2 but not for S = 1. This is consistent with the known fact that the AKLT model belongs to the trivial SPT phase if S = 2 and to a nontrivial SPT phase if S = 1. Although such interpolating families of disordered states were already known, our construction is unified and is based on a simple physical picture. It also extends to spin chains with general integer S and provides us with an intuitive explanation of the essential difference between models with odd and even spins.
Applying a symmetric bulk bipartition to the one-dimensional Affleck-Kennedy-Lieb-Tasaki valence-bond solid (VBS) states for the integer spin-SSS Haldane gapped phase, we can create an array of fractionalized spin-SSS/2 edge states with the super unit cell lll in the reduced bulk system, and the topological properties encoded in the VBS wave functions can be revealed. The entanglement Hamiltonian (EH) with even lll corresponds to the quantum antiferromagnetic Heisenberg spin-SSS/2 model. For the even integer spins, the EH still describes the Haldane gapped phase. For the odd integer spins, however, the EH just corresponds to the quantum antiferromagnetic Heisenberg half-odd integer-spin model with spinon excitations, characterizing the critical point separating the topological Haldane phase from the trivial gapped phase. Our results thus demonstrate that the topological bulk property not only determines its fractionalized edge states but also the quantum criticality associated with the topological phase, where the elementary excitations are precisely those fractionalized edge degrees of freedom confined in the bulk of the topological phase.
We investigate disordered phases realized in one-dimensional quantum spin systems.We revisit an effective field theory proposed by Schulz [Phys.Rev. B 34, 6372 (1986)], which encapsulates several essential properties in low energy, from the point of view of symmetry.Although this effective theory was originally derived by perturbation theory, we find that it is fully consistent with the symmetry of the Hamiltonian and thus uniquely identified in the non-perturbative sense.This theory explains many possible phase transitions known to occur among valence-bond-solid phases, which are typical disordered phases in one-dimensional spin systems.Furthermore, this theory indicates that the phase transitions only occur under one of four symmetries: time reversal, bond-centered inversion, dihedral group of spin rotations, and site-centered inversion combined with a spin rotation.Surprisingly, the first three symmetries are consistent with those protecting the Haldane phase in spin-1 chains, which have already been found by a completely different approach using the matrix-product state (MPS).On the other hand, the last one is not known so far.To understand it, we explicitly construct a microscopic model that has two distinct disordered phases protected by the combined inversion symmetry.We examine this model and confirm the existence of those disordered phases by perturbation theory and numerical simulations.For completeness, we further give a more rigorous proof of their existence, based on the non-translation-invariant MPS.We also propose an extension of the Lieb-Schultz-Mattis theorem for the absence of a unique gapped ground state in half-odd-integer spin systems with site-centered inversion symmetry.
Two-dimensional (spin-2) Affleck-Kennedy-Lieb-Tasaki (AKLT) type valence bond solids on a square lattice are known to be symmetry-protected topological (SPT) gapped spin liquids [S. Takayoshi, P. Pujol, and A. Tanaka Phys. Rev. B 94, 235159 (2016)]. Using the projected entangled pair state framework, we extend the construction of the AKLT state to the case of SU(3)\text{SU}(3)SU(3), relevant for cold atom systems. The entanglement spectrum is shown to be described by an alternating SU(3)\text{SU}(3)SU(3) chain of ``quarks'' and ``antiquarks'', subject to exponentially decaying (with distance) Heisenberg interactions, in close similarity with its SU(2)\text{SU}(2)SU(2) analog. We discuss the SPT feature of the state.
Abstract. We study the structure of quantum ground states of simplex solid models, which are generalizations of the valence bond construction for quantum antiferromagnets originally proposed by Affleck, Kennedy, Lieb, and Tasaki (AKLT) (1987 Phys. Rev. Lett . 59 799). Whereas the AKLT states are created by application of bond singlet operators for spins, the simplex solid construction is based on N -simplex singlet operators for spins. In both cases, a discrete one-parameter family of translationally-invariant models with exactly solvable ground states is defined on any regular lattice, and the equal time ground state correlations are given by the finite temperature correlations of an associated classical model on the same lattice, owing to the product form of the wave functions when expressed in a coherent state representation. We study these classical companion models via a mix of Monte Carlo simulations, mean-field arguments, and low-temperature effective field theories. Our analysis reveals that the ground states of edge- and face-sharing cubic lattice simplex solid models are long range ordered for sufficiently large values of the discrete parameter, whereas the ground states of the models on the kagome (2D) and hyperkagome (3D) lattices are always quantum disordered. The kagome simplex solid exhibits strong local order absent in its three-dimensional hyperkagome counterpart, a contrast that we rationalize with arguments similar to those leading to ‘order by disorder’.
Affleck, Kennedy, Lieb, and Taski (AKLT) constructed an exemplary spin-3/2 valence-bond solid (VBS) state on the hexagonal lattice, which is the ground state of an isotropic quantum antiferromagnet and possesses no spontaneous magnetization but finite correlation length. This is distinct from the N\'eel ordered state of the spin-3/2 Heisenberg model on the same lattice. Niggemann, Kl\"umper, and Zittartz then generalized the AKLT Hamiltonian to one family invariant under spin rotation about the zzz axis. The ground states of this family can be parameterized by a single parameter that deforms the AKLT state, and this system exhibits a quantum phase transition between the VBS and N\'eel phases, as the parameter increases from the AKLT point to large anisotropy. We investigate the opposite regime when the parameter decreases from the AKLT point and find that there appears to be a Berezinskii-Kosterlitz-Thouless-like transition from the VBS phase to an XY phase. Such a transition also occurs in the deformation of other types of AKLT states with triplet-bond constructions on the same lattice. However, we do not find such an XY-like phase in the deformed AKLT models on other trivalent lattices, such as square-octagon, cross, and star lattices. On the star lattice, the deformed family of AKLT states remain in the same phase as the isotropic AKLT state throughout the whole region of the parameter. However, for two triplet-bond generalizations, the triplet VBS phase is sandwiched between two ferromagnetic phases (for large and small deformation parameters, respectively), which are characterized by spontaneous magnetizations along different axes. Along the way, we also discuss how various deformed AKLT states can be used for the purpose of universal quantum computation.