The thermal or equilibrium ensemble is one of the most ubiquitous states of matter.For models comprised of many locally interacting quantum particles, it describes a wide range of physical situations, relevant to condensed-matter physics, high-energy physics, quantum chemistry and quantum computing, among others.We give a pedagogical overview of some of the most important universal features about the physics and complexity of these states, which have the fact that interactions in the Hamiltonian are short ranged at its core.We focus on mathematically rigorous statements, many of them inspired by ideas and tools from quantum information theory.These include bounds on their correlations, the form of the subsystems, various statistical properties, and the performance of classical and quantum algorithms.We also include a summary of a few of the most important technical tools, as well as some self-contained proofs.
The thermal or equilibrium ensemble is one of the most ubiquitous states of matter.For models comprised of many locally interacting quantum particles, it describes a wide range of physical situations, relevant to condensed-matter physics, high-energy physics, quantum chemistry and quantum computing, among others.We give a pedagogical overview of some of the most important universal features about the physics and complexity of these states, which have the fact that interactions in the Hamiltonian are short ranged at its core.We focus on mathematically rigorous statements, many of them inspired by ideas and tools from quantum information theory.These include bounds on their correlations, the form of the subsystems, various statistical properties, and the performance of classical and quantum algorithms.We also include a summary of a few of the most important technical tools, as well as some self-contained proofs.
We review several properties of thermal states of spin Hamiltonians with short range interactions. In particular, we focus on those aspects in which the application of tools coming from quantum information theory has been specially successful in the recent years. This comprises the study of the correlations at finite and zero temperature, the stability against distant and/or weak perturbations, the locality of temperature and their classical simulatability. For the case of states with a finite correlation length, we review the results on their energy distribution and the equivalence of the canonical and microcanonical ensemble.
Among the few lessons that Physics teaches us on a daily basis, one in particular is hard to miss: thermalization processes are ubiquitous. With the same degree of certainty, one can predict an apple to fall onto the ground if its stalk is cut, or a cup of tea to be found cold if left on the table for too long. In this respect, generic classical and quantum mechanical systems seem to behave in the same way. This is also one of the main difficulties in the experimental observation of the bizarre effects predicted from the quantum theory, as several of these are known to disappear at finite temperatures. It has been known for a long time that thermalization is associated with “chaotic” behavior at the microscopic level, but recently systematic efforts, both theoretical and experimental, have allowed us to understand its mechanisms at an unprecedented level of accuracy. Indeed, it has been realized that thermalization generally occurs also in isolated systems, where the absence of interactions with the environment allows for first principle theoretical investigations1. In this case thermalization takes place locally, as the whole system acts as a thermal bath for its own subsystems. Theoretical research has been motivated and paralleled by exciting experimental progress in cold-atom physics, which has provided robust, nearly ideal realizations of several theoretical models2. As an established piece of knowledge, recent research has now confirmed that two outstanding exceptions actually exist in the quantum realm, where thermalization is prevented to occur. These are many-body localized systems3, where disorder plays a crucial role, and integrable ones, which are protected by the existence of higher conservation laws. By their own nature, these systems display exceptional non-equilibrium features, which are not washed out by the onset of thermalization as relaxation occurs. At the core of the present thesis lie the remarkable properties of integrable systems out of equilibrium, with a special attention to physical effects which could be observed in cold-atom realizations. The work collected here is part of a large theoretical effort4 which in the past decade has focused on the study of relatively simple protocols to bring a quantum system out of equilibrium, such as the so-called quantum quench. In these “theoretical laboratories” it has been possible to provide quantitative predictions which helped us to develop an intuition on general questions regarding non-equilibrium and thermalization processes. Furthermore, in some cases these studies have highlighted interesting physical effects which could be directly probed experimentally within cold-atom settings. The contribution of the present thesis is two-fold. On the one hand, we have developed new technical tools for the study of integrable systems out of equilibrium, and for the computation of measurable physical quantities such as correlation functions. The techniques employed are mainly analytical and rooted within the mathematical structures of integrability. On the other hand, we have singled out physically relevant nonequilibrium situations where exotic, non-thermal states of matter emerge after relaxation occurs, and provided quantitative analytical predictions in these cases. A comprehensive discussion of the motivations and results of our work will be presented in Chapter 1, where we provide a complete overview of this thesis and discuss the organization of its content.
Abstract This book is an introduction to the techniques of many-body quantum theory with a large number of applications to condensed matter physics. The basic idea of the book is to provide a self-contained formulation of the theoretical framework without losing mathematical rigor, while at the same time providing physical motivation and examples. The examples are taken from applications in electron systems and transport theory. On the formal side, the book covers an introduction to second quantization, many-body Green's function, finite temperature Feynman diagrams and bosonization. The applications include traditional transport theory in bulk as well as mesoscopic systems, where both the Landau-Büttiker formalism and recent developments in correlated transport phenomena in mesoscopic systems and nano-structures are covered. Other topics include interacting electron gases, plasmons, electron-phonon interactions, superconductivity and a final chapter on one-dimensional systems where a detailed treatment of Luttinger liquid theory and bosonization techniques is given. Having grown out of a set of lecture notes, and containing many pedagogical exercises, this book is designed as a textbook for an advanced undergraduate or graduate course, and is also well suited for self-study.
The study of far-from-equilibrium quantum systems is a rapidly growing field of condensed matter physics. Notions of quantum information theory have emerged as important tools in this context, central to understanding the quantum thermalization process. In this thesis, we study the dynamics of such quantities, and uncover many of their interesting universal features. We achieve this by combining the study of simple minimal models, with extensive numerical simulations, developing a `hydrodynamics of quantum information'.
Quantum Mechanics was established as the theory of the microscopic world, which allowed to understand processes in atoms and molecules. Its emergence led to a new scientific paradigm that quickly spread to different research fields. Two relevant examples are Quantum Thermodynamics and Quantum Many-Body Theory, where the former aims to characterize thermodynamic processes in quantum systems and the latter intends to understand the properties of quantum many-body systems. In this thesis, we tackle some of the questions in the overlap between these disciplines, focusing on the concepts of temperature and correlations. Specifically, it contains results on the following topics: locality of temperature, correlations in long-range interacting systems and thermometry at low temperature. The problem of locality of temperature is considered for a system at thermal equilibrium and consists in studying whether it is possible to assign a temperature to any of the subsystems of the global system such that both local and global temperatures are equal. We tackle this problem in two different settings, for generic one-dimensional spin chains and for a bosonic system with a phase transition at non-zero temperature. In the first case, we consider generic one-dimensional translation-invariant spin systems with short-range interactions and prove that it is always possible to assign a local temperature equal to the global one for any temperature, including at criticality. For the second case, we consider a three-dimensional discretized version of the Bose-Einstein model at the grand canonical ensemble for some temperature and particle density, and characterize its non-zero-temperature phase transition. Then, we show that temperature is locally well-defined at any temperature and at any particle density, including at the phase transition. Additionally, we observe a qualitative relation between correlations and locality of temperature in the system. Moving to correlations, we consider fermionic two-site long-range interacting systems at thermal equilibrium. We show that correlations between anti-commutative operators at non-zero temperature are upper bounded by a function that decays polynomially with the distance and with an exponent that is equal to the interaction exponent, which characterizes the interactions in the Hamiltonian. Moreover, we show that our bound is asymptotically tight and that the results extend to density-density correlations as well as other types of correlations for quadratic and fermionic Hamiltonians with long-range interactions. Regarding the results on thermometry, we consider a bosonic model and prove that strong coupling between the probe and the system can boost the thermal sensitivity for low temperature. Furthermore, we provide a feasible measurement scheme capable of producing optimal estimates at the considered regime.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.