We introduce a general setup for the analog quantum simulation of the dynamics of open quantum systems based on semiconductor quantum dots electrically connected to an array of quantum RLC electronic circuits.The dots are chosen to be in the regime of spin-charge hybridization to enhance their sensitivity to the RLC circuits while mitigating the detrimental effects of unwanted noise.In this context, we establish an experimentally realizable map between the hybrid system and a qubit coupled to thermal harmonic environments of arbitrary complexity that enables the analog quantum simulation of open quantum systems.We assess the utility of the simulator by numerically exact emulations that indicate that the experimental setup can faithfully mimic the intended target even in the presence of its natural inherent noise.We further provide a detailed analysis of the physical requirements on the quantum dots and the RLC circuits needed to experimentally realize this proposal that indicates that the simulator can be created with existing technology.The approach can exactly capture the effects of highly structured non-Markovian quantum environments typical of photosynthesis and chemical dynamics and it offers clear potential advantages over conventional and even quantum computation.The proposal opens up a general path for effective quantum dynamics simulations based on semiconductor quantum dots.
We introduce a general setup for the analog quantum simulation of the dynamics of open quantum systems based on semiconductor quantum dots electrically connected to an array of quantum RLC electronic circuits.The dots are chosen to be in the regime of spin-charge hybridization to enhance their sensitivity to the RLC circuits while mitigating the detrimental effects of unwanted noise.In this context, we establish an experimentally realizable map between the hybrid system and a qubit coupled to thermal harmonic environments of arbitrary complexity that enables the analog quantum simulation of open quantum systems.We assess the utility of the simulator by numerically exact emulations that indicate that the experimental setup can faithfully mimic the intended target even in the presence of its natural inherent noise.We further provide a detailed analysis of the physical requirements on the quantum dots and the RLC circuits needed to experimentally realize this proposal that indicates that the simulator can be created with existing technology.The approach can exactly capture the effects of highly structured non-Markovian quantum environments typical of photosynthesis and chemical dynamics and it offers clear potential advantages over conventional and even quantum computation.The proposal opens up a general path for effective quantum dynamics simulations based on semiconductor quantum dots.
Open quantum system approaches are widely used in the description of physical, chemical and biological systems. A famous example is electronic excitation transfer in the initial stage of photosynthesis, where harvested energy is transferred with remarkably high efficiency to a reaction center. This transport is affected by the motion of a structured vibrational environment, which makes simulations on a classical computer very demanding. Here we propose an analog quantum simulator of complex open system dynamics with a precisely engineered quantum environment. Our setup is based on superconducting circuits, a well established technology. As an example, we demonstrate that it is feasible to simulate exciton transport in the Fenna–Matthews–Olson photosynthetic complex. Our approach allows for a controllable single-molecule simulation and the investigation of energy transfer pathways as well as non-Markovian noise-correlation effects.
Modern computational techniques used to simulate quantum chemistry are on the boundary of tractability due to the exponential growth of the molecular wavefunction, requiring a careful balance between molecule size and simulation accuracy. In recent years, quantum computing has risen in popularity as a potential alternative to conventional (classical) techniques; however, most methods rely on access to "digital" quantum computers composed of qubits and quantum gates, which at present are severely limited by noise. We have developed a real-time, analog approach to simulate vibronic chemical dynamics with existing quantum technology. Our approach uses an intuitive mapping of molecular electronic and vibrational degrees of freedom onto quantum resonators and qudit (d-level system) states, with controllable couplings between degrees of freedom. The measurement output can be mapped onto different time-dependent observables, including the time-domain simulation of vibronic spectra. Our approach can also incorporate controlled sources of noise to simulate system-bath interactions and dissipative dynamics at a minimal cost. We present experimental results using a trapped-ion device, thus showing the potential for near-term simulation of chemical dynamics in complex environments beyond the abilities of classical computers.
Quantum systems are inherently open and susceptible to environmental noise, which can have both detrimental and beneficial effects on their dynamics.This phenomenon has been observed in biomolecular systems, where noise enables novel functionalities, making the simulation of their dynamics a crucial target for digital and analog quantum simulation.Nevertheless, the computational capabilities of current quantum devices are often limited due to their inherent noise.In this work, we present a novel approach that capitalizes on the intrinsic noise of quantum devices to reduce the computational resources required for simulating open quantum systems.Our approach combines quantum noise characterization methods with quantum error mitigation techniques, enabling us to manipulate and control the intrinsic noise in a quantum circuit.Specifically, we selectively enhance or reduce decoherence rates in the quantum circuit to achieve the desired simulation of open-system dynamics.We provide a detailed description of our methods and report on the results of noise characterization and quantum error mitigation experiments conducted on both real and emulated IBM Quantum computers.Additionally, we estimate the experimental resource requirements for our techniques.Our approach holds the potential to unlock new simulation techniques in noisy intermediate-scale quantum devices, harnessing their intrinsic noise to enhance quantum computations.
The spin of an electron confined in semiconductor quantum dots is currently a promising candidate for quantum bit (qubit) implementations. Taking advantage of the existing CMOS integration technologies, such devices can offer a platform for large scale quantum computation. However, a quantum mechanical framework bridging a device's physical design and operational parameters to the qubit's energy space is lacking. Furthermore, the spin to charge coupling introduced by intrinsic or induced spin-orbit interaction (SOI) exposes the qubits to charge noise compromising their coherence properties and inducing quantum gate errors. We present here a comodeling framework for double quantum dot (DQD) devices and their charge noise environments. We use a combination of an electrostatic potential solver, full configuration interaction quantum mechanical methods, and two-level-fluctuator models to study the quantum gate performance in realistic device designs and operation conditions. We utilize the developed models together alongside the single electron solutions of the quantum dots to simulate one- and two-qubit gates in the presence of charge noise. We find an inverse correlation between quantum gate errors and quantum dot confinement frequencies. We calculate X-gate fidelities >97 in the simulated Si-MOS devices at a typical TLF density of ${10}^{11}\phantom{\rule{4pt}{0ex}}{\mathrm{cm}}^{\ensuremath{-}2}$. We also find that exchange driven two-qubit SWAP gates show higher sensitivity to charge noise with fidelities down to 91 in the presence of the same density of TLFs. We further investigate the one- and two-qubit gate fidelities at different TLF densities. We find that given the small size of the quantum dots, sensitivity of a quantum gate to the distance between the noise sources and the quantum dot creates a strong variability in the quantum gate fidelities, which can compromise the device yields in scaled qubit technologies.
Scalable solid-state quantum computers will require integration with analog and digital electronics. Efficiently simulating the quantum-classical electronic interface is hence of paramount importance. Here, we present Verilog-A compact models with a focus on quantum-dot-based systems, relevant to semiconductor- and Majorana-based quantum computing. Our models are capable of faithfully reproducing coherent quantum behavior and decoherence effects within a standard electronic circuit simulator, enabling compromise-free co-simulation of hybrid quantum devices. In particular, we present results from co-simulations performed in Cadence Spectre®, showcasing coherent quantum phenomena in circuits with both quantum and classical components using an industry-standard electronic design and automation tool. Our work paves the way for a new paradigm in the design of quantum systems, which leverages the many decades of development of electronic computer-aided design and automation tools in the semiconductor industry to now simulate and optimize quantum processing units, quantum-classical interfaces, and hybrid quantum-analog circuits.
Quantum computing offers promising new avenues for tackling the long-standing challenge of simulating the quantum dynamics of complex chemical systems, particularly open quantum systems coupled to external baths. However, simulating such nonunitary dynamics on quantum computers is challenging since quantum circuits are specifically designed to carry out unitary transformations. Furthermore, chemical systems are often strongly coupled to the surrounding environment, rendering the dynamics non-Markovian and beyond the scope of Markovian quantum master equations like Lindblad or Redfield. In this work, we introduce a quantum algorithm designed to simulate non-Markovian dynamics of open quantum systems. Our approach enables the implementation of arbitrary quantum master equations on noisy intermediate-scale quantum (NISQ) computers. We illustrate the method as applied in conjunction with the numerically exact hierarchical equations of motion (HEOM) method. The effectiveness of the resulting quantum HEOM algorithm is demonstrated as applied to simulations of the non-Lindbladian electronic energy and charge transfer dynamics in models of the carotenoid-porphyrin-C 60 molecular triad dissolved in tetrahydrofuran and the Fenna–Matthews–Olson complex.