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arXiv:2203.10449

Poeschl-Teller quantum oscillator and its limiting cases

Yu. G. Rudoy, Enock Oluwole Oladimeji

Published Mar 20, 2022• 0 citations
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Abstract

One of the most interesting models of the nonrelativistic quantum mechanics (in one-dimensional case) introduced by G. Poeschl and E.Teller at 1933 is considered. It is shown that this model possesses as its limiting cases two most popular quantum models: the quasi-free quantum particle in the box as well as the quantum harmonic oscillator introduced by F. Bloch at 1932.

DOI
10.48550/arxiv.2203.10449

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One of the most interesting models of the nonrelativistic quantum mechanics (in one-dimensional case) introduced by G. Poeschl and E.Teller at 1933 is considered. It is shown that this model possesses as its limiting cases two most popular quantum models: the quasi-free quantum particle in the box as well as the quantum harmonic oscillator introduced by F. Bloch at 1932.
In this paper the detailed investigation of one of the most interested models in the non relativistic quantum mechanics of one massive particle i.e., introduced by G. Poeschl and E. Teller in 1933 is presented. This model includes as particular cases two most popular and valuable models: the quasi free particle in the box with impenetrable hard walls (i.e., the model with confinement) and Bloch quantum harmonic oscillator, which is unconfined in space; both models are frequently and effectively exploited in modern nanotechnology e.g., in quantum dots and magnetic traps. We give the extensive and elementary exposition of the potentials, wave functions and energetic spectra of all these interconnected models. Moreover, the pressure operator is defined following the lines of G. Helmann and R. Feynman which were the first who introduced this idea in the late 30ies in quantum chemistry. By these means the baroenergetic equation of state is obtained and analyzed for all three models; in particular, it is shown the absence of the pressure for the Bloch oscillator due to the infinite width of the box. The generalization of these results on the case of nonzero temperature will be given later.
The quantum-mechanical properties of the strongly non-linear quantum oscillator in the Pöeschl-Teller model are considered. In the first place, the energy spectrum and its dependence upon the confinement parameter (i.e., the width of the “box”) are studied. Moreover, on the grounds of the Hellman-Feynman theorem the pressure operator in this model is obtained and (along with the energy spectrum) is studied in two main approximations: the “particle in the box” and “linear (harmonic) oscillator” for large and low values of the main quantum number; the critical value is also evaluated. Semi-classical approximation as well as perturbation theory for the Pöeschl-Teller are also considered. The results obtained here are intended for future thermodynamic calculations: first of all, for the generalization of the well-known Bloch result for the linear harmonic oscillator in the thermostat. To this end, the density matrix for the Pöeschl-Teller oscillator will be calculated and the full Carnot cycle conducted.
In this paper the detailed investigation of one of the most interesting models in the non relativistic quantum mechanics of one massive particle i.e., introduced by G. Poeschl and E. Teller in 1933 is continued; the starting point of dynamic analysis for potentials, wave functions and energy spectrum was carried on by the same authors in the paper. The generalization of these results on the case of nonzero temperature includes the approximate calculation of the partition function of the model and then also the Massieu Planck thermodynamic potential and its most important derivatives, i.e. internal energy, heat capacity and pressure. The analysis of the results is carried on separately for low and high temperature regions because of the lack of exact unifying expressions of the potential at all temperatures.