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arXiv:1605.09374

On approximating the free harmonic oscillator by a particle in a box

Kunle Adegoke, Adenike Olatinwo, Henry Otobrise, Rauf Giwa, Gbenga Olunloyo

Published May 29, 2016• 0 citations
arXivHTMLPDF

Abstract

The main purpose of this paper is to demonstrate and illustrate, once again, the potency of the variational technique as an approximation procedure for the quantization of quantum mechanical systems. By choosing particle-in-a-box wavefunctions as trial wavefunctions, with the size of the box as the variation parameter, approximate eigenenergies and the corresponding eigenfunctions are obtained for the one dimensional free harmonic oscillator.

DOI
10.48550/arxiv.1605.09374

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The main purpose of this paper is to demonstrate and illustrate, once again, the potency of the variational technique as an approximation procedure for the quantization of quantum mechanical systems. By choosing particle-in-a-box wavefunctions as trial wavefunctions, with the size of the box as the variation parameter, approximate eigenenergies and the corresponding eigenfunctions are obtained for the one dimensional free harmonic oscillator.
Variational calculations play an important role in quantum mechanics, particularly in determining the ground-state energy of physical systems. Didactic examples in which one can see how the exact energy and wave function are approached by using a family of trial functions are not very numerous. An example was given in a recent book [M. Moshinsky, The Harmonic Oscillator in Modern Physics: From Atoms to Quarks (Gordon and Breach, New York, 1969)] which discusses the ground state of the hydrogen atom using as trial wave function a linear combination of harmonic-oscillator states. In the present paper we carry out a similar analysis for the ground state of a particle of mass m in a three-dimensional square-well potential. We discuss not only the approach to the exact energy when we vary the frequency and the number of oscillator states but also analyze the overlap of the exact and variational wave functions and compare the exact and approximate form factors.
The direct variational method is used to study two simple confined systems, namely, the hydrogen atom and the harmonic oscillator within impenetrable spherical boxes. The trial wave functions have been assumed as the product of the ‘‘free’’ solutions of the corresponding Schrödinger equation and a simple function that satisfies the respective boundary conditions. The energy levels obtained in this way are extremely close to the exact ones, thus proving the utility of the proposed method. This might constitute a complementary exercise for undergraduate students since usual quantum mechanics textbooks do not explore the use of the variational method to study confined systems.
Quantum mechanics is one of the branches of physics. In this mechanics, physical problems are solved by algebraic and analytic methods. By applying a simple procedure we can find the general solutions of Schrodinger’s time - independent wave equation of one dimensional quantum mechanical harmonic oscillator without making any approximation. In this paper, we will discuss the Eigenenergy values and Eigenfunctions of one of the most important physical models of quantum mechanics, namely the one-dimensional Quantum mechanical Harmonic Oscillator by modifying the Hermite differential equation.