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arXiv:2201.08691 · Physical Review A

Fluctuation theorems for multitime processes

Zhiqiang Huang

Published Jun 28, 2022• 8 citations
arXivHTMLPDF

Abstract

In this paper, we extend the fluctuation theorems used for quantum channels to multitime processes. The fluctuation theorems for quantum channels are less restrictive. We show that the given entropy production can be equal to the result of a closed system environment. The assumption that the system evolves under a completely positive and trace-preserving map is quite general, but it is more specific for cases in which the system is initially correlated with the environment. System-environment correlations arise naturally in multitime processes with which we can give clear and physical interpretations regarding the effects of correlations. Multitime processes can provide many-body channels. The Choi state of such a many-body channel is called a process tensor. One can derive channels by executing the process tensor on a set of operations. We establish a general quantum fluctuation theorem framework for a many-body channel and its derived channels. In this framework, the effects of correlations are reflected in a Markovian property. For Markovian processes, we can extend the two-point measurement to a three-point measurement and obtain that the fluctuation theorems contain complete information about the intermediate state. For non-Markovian processes, the complete measurement of the intermediate state leads to conflicts. Therefore, we use a general measurement, which only provides partial information, for the intermediate state. The corresponding fluctuation theorems show that memory effects can reduce these fluctuations. This is consistent with the fact that system states can be recovered under non-Markovian processes.

DOI
10.1103/physreva.105.062217

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In this paper, we extend the fluctuation theorems used for quantum channels to multitime processes. The fluctuation theorems for quantum channels are less restrictive. We show that the given entropy production can be equal to the result of a closed system environment. The assumption that the system evolves under a completely positive and trace-preserving map is quite general, but it is more specific for cases in which the system is initially correlated with the environment. System-environment correlations arise naturally in multitime processes with which we can give clear and physical interpretations regarding the effects of correlations. Multitime processes can provide many-body channels. The Choi state of such a many-body channel is called a process tensor. One can derive channels by executing the process tensor on a set of operations. We establish a general quantum fluctuation theorem framework for a many-body channel and its derived channels. In this framework, the effects of correlations are reflected in a Markovian property. For Markovian processes, we can extend the two-point measurement to a three-point measurement and obtain that the fluctuation theorems contain complete information about the intermediate state. For non-Markovian processes, the complete measurement of the intermediate state leads to conflicts. Therefore, we use a general measurement, which only provides partial information, for the intermediate state. The corresponding fluctuation theorems show that memory effects can reduce these fluctuations. This is consistent with the fact that system states can be recovered under non-Markovian processes.
Entropy production and the detailed fluctuation theorem are of fundamental importance for thermodynamic processes. In this paper we study the multiple entropy production for multitime quantum processes in a unified framework. For closed quantum systems and Markovian open quantum systems, the given entropy productions all satisfy the detailed fluctuation relation. This also shows that the entropy production rate under these processes is non-negative. For non-Markovian open quantum systems, the memory effect can lead to a negative-entropy production rate. Thus, in general, the entropy production of the marginal distribution does not satisfy the detailed fluctuation theorem relation. Our framework can be applied to a wide range of physical systems and dynamics. It provides a systematic tool for studying entropy production and its rate under arbitrary quantum processes.
In the dynamics of open quantum systems, information may propagate in time through either the system or the environment, giving rise to Markovian and non-Markovian temporal correlations, respectively. However, despite their notable coexistence in most physical situations, it is not yet clear how these two quantities may limit the existence of one another. Here, we address this issue by deriving several inequalities relating the temporal correlations of general multitime quantum processes. The dynamics are described by process tensors, and the correlations are quantified by the mutual information between subsystems of their Choi states. First, we prove a set of upper bounds to the non-Markovianity of a process given the degree of Markovianity in each of its steps. This immediately implies a nontrivial maximum value for the non-Markovianity of any process, independent of its Markovianity. Finally, we determine how the non-Markovianity limits the amount of total temporal correlations that could be present in a given process. These results show that, although any multitime process must pay a price in total correlations to have a given amount of non-Markovianity, this price vanishes exponentially with the number of steps of the process, while the maximum non-Markovianity grows only linearly. This implies that even a highly non-Markovian process might be arbitrarily close to having the maximum amount of total correlations if it has a sufficiently large number of steps.
We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and Markovian regime, holds for both local and global master equations, corroborating the thermodynamic consistency of local quantum master equations. The theorem is genuinely quantum, as it can be expressed in terms of conservation of a Hermitian operator, describing the dynamics of the system state operator and of the entropy change in the baths. The integral fluctuation theorem follows from the properties of such an operator. Furthermore, it is also valid when the system is described by a time-dependent Hamiltonian. As such, the quantum Jarzynski equality is a particular case of the general result presented here. Moreover, our result can be extended to nonthermal baths, as long as microreversibility is preserved. We present some numerical examples to showcase the exact results previously obtained. We finally generalize the fluctuation theorem to the case where the interaction between the system and the bath is explicitly taken into account. We show that the fluctuation theorem amounts to a relation between time-reversed dynamics of the global density matrix and a two-time correlation function along the forward dynamics involving the baths' entropy alone.
Exploiting previous results on Markovian dynamics and fluctuation theorems, we study the consequences of memory effects on single realizations of nonequilibrium processes within an open system approach. The entropy production along single trajectories for forward and backward processes is obtained with the help of a recently proposed classical-like non-Markovian stochastic unravelling, which is demonstrated to lead to a correction of the standard entropic fluctuation theorem. This correction is interpreted as resulting from the interplay between the information extracted from the system through measurements and the flow of information from the environment to the open system: Due to memory effects, single realizations of a dynamical process are no longer independent and their correlations fundamentally affect the behavior of entropy fluctuations.
We establish the general framework of quantum fluctuation theorems by finding the symmetry between the forward and backward transitions of any given quantum channel. The Petz recovery map is adopted as the reverse quantum channel, and the notion of entropy production in thermodynamics is extended to the quantum regime. Our result shows that the fluctuation theorems, which are normally considered for thermodynamic processes, can be a powerful tool to study the detailed statistics of quantum systems as well as the effect of coherence transfer in an arbitrary non-equilibrium quantum process. We introduce a complex-valued entropy production to fully understand the relation between the forward and backward processes through the quantum channel. We find the physical meaning of the imaginary part of entropy production to witness the broken symmetry of the quantum channel. We also show that the imaginary part plays a crucial role in deriving the second law from the quantum fluctuation theorem. The dissipation and fluctuation of various quantum resources including quantum free energy, asymmetry and entanglement can be coherently understood in our unified framework. Our fluctuation theorem can be applied to a wide range of physical systems and dynamics to query the reversibility of a quantum state for the given quantum processing channel involving coherence and entanglement.
Currently, there is no systematic way to describe a quantum process with memory solely in terms of experimentally accessible quantities. However, recent technological advances mean we have control over systems at scales where memory effects are non-negligible. The lack of such an operational description has hindered advances in understanding physical, chemical, and biological processes, where often unjustified theoretical assumptions are made to render a dynamical description tractable. This has led to theories plagued with unphysical results and no consensus on what a quantum Markov (memoryless) process is. Here, we develop a universal framework to characterize arbitrary non-Markovian quantum processes. We show how a multitime non-Markovian process can be reconstructed experimentally, and that it has a natural representation as a many-body quantum state, where temporal correlations are mapped to spatial ones. Moreover, this state is expected to have an efficient matrix-product-operator form in many cases. Our framework constitutes a systematic tool for the effective description of memory-bearing open-system evolutions.