In the classical world, temperature is a measure of how hot or cold a physical object is. We never find a physical system which can be both hot and cold at the same time. Here, we show that for a quantum system, it is possible to have superposition of two temperatures which can lead to a situation that it can be found both in hot and cold state. We propose a physical mechanism for how to create a quantum state which is superposition of two temperatures. Furthermore, we define an operator for the inverse temperature and show that the thermal state is, in fact, an eigenstate of this operator. The quantum state which represents superposition of two temperatures is not an eigenstate of the inverse temperature operator. Our findings can have new applications in quantum thermodynamics, quantum nano scale devices and quantum statistical mechanics.
In the classical world, temperature is a measure of how hot or cold a physical object is. We never find a physical system which can be both hot and cold at the same time. Here, we show that for a quantum system, it is possible to have superposition of two temperatures which can lead to a situation that it can be found both in hot and cold state. We propose a physical mechanism for how to create a quantum state which is superposition of two temperatures. Furthermore, we define an operator for the inverse temperature and show that the thermal state is, in fact, an eigenstate of this operator. The quantum state which represents superposition of two temperatures is not an eigenstate of the inverse temperature operator. Our findings can have new applications in quantum thermodynamics, quantum nano scale devices and quantum statistical mechanics.
The rather new field of quantum thermodynamics intends to derive thermodynamics from quantum mechanics, as well as to study thermodynamical behavior of quantum systems. It turns out that, indeed, thermalization can be obtained even for very small quantum systems due to the interaction with an appropriate environment. The consideration of an ensemble, as in statistical mechanics, is not necessary. However, the total system - consisting of system and environment - in quantum thermodynamics is usually considered to be closed. In particular, there exists no interaction with an external observer. Since quantum measurements typically influence the measured system, one may wonder which influence such an observation will have in the quantum thermodynamical setting. In this thesis, we study this influence of measurements in quantum thermodynamical systems. It turns out that various concepts known from statistical mechanics arise from such a "quantum thermodynamics under observation", although they do not have any meaning in the isolated quantum thermodynamical setting. The model discussed in the first part consists of a two-level system coupled to a large spin environment, the magnetization of which is measured periodically. This leads to quasi-classical trajectories for the system and - as in statistical mechanics - thermalization and temperature only have a meaning in terms of an ensemble average or a long-time average. Calculating these averages, we prove the ergodicity of the system. Interestingly, the entropy of the obtained attractor state depends on the time between the measurements and can be shown to be connected with the subjective lack of knowledge of the observer. In case of optimal measurements, the ensemble averaged state of the system under periodic measurements equals the state of the system in the quantum thermodynamical model without measurements. Introducing a detuning between system and environment, we find that the system can be prepared in almost arbitrary thermal states due to the periodic measurements. Even the creation of inversion becomes possible. As shown in numerical simulations, our results, which were analytically obtained for large environments, are even applicable to describe the behavior of the system coupled to small environments consisting of only a few spins. Besides measurements of the environment, we also study direct projective measurements of the system, as well as measurements with finite duration, obtaining that the dynamics of the system is almost independent of the concrete realization of the measurements. In the second part of the thesis, we discuss the meaning of temperature fluctuations in quantum thermodynamical systems. In statistical mechanics, there exist different approaches to the problem of temperature fluctuations, which lead to the well-known temperature fluctuation formula. The nature and operational accessibility of these fluctuations, however, remains rather unclear. We argue that according to quantum thermodynamics a system relaxes into a quasi-stationary thermal state and therefore the temperature does not fluctuate. However, since temperature is not an observable, it can only be determined indirectly. For modular systems, we show that the fluctuations of the temperature estimate obtained from a single energy measurement, indeed, are given by the temperature fluctuation formula derived in statistical mechanics, but only within a certain temperature range. The validity range of this formula increases with increasing size of the system. Thus, one can conclude that these "temperature fluctuations" can be interpreted as representing a fundamental limit for the instantaneous determination of temperature.
A large class of isolated quantum systems in a pure state can equilibrate and serve as a heat bath. We show that, once equilibrium is reached, any of its subsystems, which are much smaller than the isolated system, can be thermalized such that the subsystem is governed by the Gibbs distribution. Within this theoretical framework, the celebrated superposition principle of quantum mechanics leads to a prediction of a thermalized subsystem with multiple temperatures when the isolated system is in a superposition state of energy eigenstates of multiple distinct energy scales. This multiple-temperature state is at equilibrium, completely different from a non-equilibrium state that has multiple temperatures at different parts. Feasible experimental schemes, in particular with ultra-cold atoms, to verify this prediction are discussed.
In this paper, we discuss the importance of measurement in quantum mechanics and the so-called measurement problem. Any quantum system can be described as a linear combination of eigenstates of an operator representing a physical quantity; this means that the system can be in a superposition of states that corresponds to different eigenvalues, i.e., different physical outcomes, each one incompatible with the others. The measurement process converts a state of superposition (not macroscopically defined) in a well-defined state. We show that, if we describe the measurement by the standard laws of quantum mechanics, the system would preserve its state of superposition even on a macroscopic scale. Since this is not the case, we assume that a measurement does not obey to standard quantum mechanics, but to a new set of laws that form a “quantum measurement theory”.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Recent theoretical and experimental work on the foundations of statistical mechanics and thermodynamics has shown that quantum pure states typically evolve to thermal equilibrium. We focus on formulating the second law of thermodynamics for these states. The standard quantum von Neumann quantum entropy is constant during equilibration, S^{vN}=0, in apparent conflict with the entropy increase of the second law, ΔS_{univ} > 0. We explore a recently developed entropy S_{univ}^Q for a pure state and test its behavior in simulations of a model system and environment evolving in time with heat flow to equilibrium. We find that the entropy approaches the correct classical value in a type of classical limit with weak coupling. With stronger coupling, we find a new source of quantum "excess entropy production," which has its origin in the quantum spreading of the wavepacket. Are there quantum thermodynamic effects related to this new source of entropy? To test this, we developed a model for a small variable temperature quantum oscillator bath. We performed simulations where two small baths are linked by a system, with unequal couplings to the baths. The model evolves to a novel type of equilibrium state with unequal temperatures in the baths, with heat flow from cold to hot along the path to equilibrium. We give an account of this behavior in terms of the second law with the quantum entropy S_{univ}^Q. The new formulation of the second law thus appears well-founded and fruitful, with surprising new quantum thermodynamic effects that may still be awaiting discovery, for example in molecules or systems far from equilibrium. \n\nThis dissertation includes previously published and unpublished co-authored material.
Temperature is a deceptively simple concept that still raises deep questions at the forefront of quantum physics research. The observation of thermalization in completely isolated quantum systems, such as cold-atom quantum simulators, implies that a temperature can be assigned even to individual, pure quantum states. Here, we propose a scheme to measure the temperature of such pure states through quantum interference. Our proposal involves interferometry of an auxiliary qubit probe, which is prepared in a superposition state and subsequently decoheres due to weak coupling with a closed, thermalized many-body system. Using only a few basic assumptions about chaotic quantum systems, namely, the eigenstate thermalization hypothesis and the emergence of hydrodynamics at long times, we show that the qubit undergoes pure exponential decoherence at a rate that depends on the temperature of its surroundings. We verify our predictions by numerical experiments on a quantum spin chain that thermalizes after absorbing energy from a periodic drive. Our Letter provides a general method to measure the temperature of isolated, strongly interacting systems under minimal assumptions.