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arXiv:1211.2956 · Laser Physics Letters

Quantum thermalization and equilibrium state with multiple temperatures

Quntao Zhuang, Biao Wu

Published Jun 10, 2014• 7 citations
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Abstract

A large class of isolated quantum systems in a pure state can equilibrate and serve as a heat bath. We show that, once equilibrium is reached, any of its subsystems, which are much smaller than the isolated system, can be thermalized such that the subsystem is governed by the Gibbs distribution. Within this theoretical framework, the celebrated superposition principle of quantum mechanics leads to a prediction of a thermalized subsystem with multiple temperatures when the isolated system is in a superposition state of energy eigenstates of multiple distinct energy scales. This multiple-temperature state is at equilibrium, completely different from a non-equilibrium state that has multiple temperatures at different parts. Feasible experimental schemes, in particular with ultra-cold atoms, to verify this prediction are discussed.

DOI
10.1088/1612-2011/11/8/085501

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A large class of isolated quantum systems in a pure state can equilibrate and serve as a heat bath. We show that, once equilibrium is reached, any of its subsystems, which are much smaller than the isolated system, can be thermalized such that the subsystem is governed by the Gibbs distribution. Within this theoretical framework, the celebrated superposition principle of quantum mechanics leads to a prediction of a thermalized subsystem with multiple temperatures when the isolated system is in a superposition state of energy eigenstates of multiple distinct energy scales. This multiple-temperature state is at equilibrium, completely different from a non-equilibrium state that has multiple temperatures at different parts. Feasible experimental schemes, in particular with ultra-cold atoms, to verify this prediction are discussed.
Two identical finite quantum systems prepared initially at different temperatures, isolated from the environment, and subsequently brought into contact are demonstrated to relax towards Gibbs-like quasi-equilibrium states with a common temperature and small fluctuations around the time-averaged expectation values of generic observables. The temporal thermalization process proceeds via a chain of intermediate Gibbs-like states. We specify the conditions under which this scenario occurs and corroborate the quantum equilibration with two different models.
The unitary dynamics of isolated quantum systems does not allow a pure state to thermalize. Because of that, if an isolated quantum system equilibrates, it will do so to the predictions of the so-called "diagonal ensemble" ρ DE . Building on the intuition provided by Jaynes' maximum entropy principle, in this paper we present a novel technique to generate progressively better approximations to ρ DE . As an example, we write down a hierarchical set of ensembles which can be used to describe the equilibrium physics of small isolated quantum systems, going beyond the "thermal ansatz" of Gibbs ensembles.
The circumstances under which a system reaches thermal equilibrium, and how to derive this from basic dynamical laws, has been a major question from the very beginning of thermodynamics and statistical mechanics. Despite considerable progress, it remains an open problem. Motivated by this issue, we address the more general question of equilibration. We prove, with virtually full generality, that reaching equilibrium is a universal property of quantum systems: almost any subsystem in interaction with a large enough bath will reach an equilibrium state and remain close to it for almost all times. We also prove several general results about other aspects of thermalization besides equilibration, for example, that the equilibrium state does not depend on the detailed microstate of the bath.
Identifying the general mechanics behind the equilibration of a complex isolated quantum system towards a state described by only a few parameters has been the focus of attention in non-equilibrium thermodynamics. And several experimentally unproven conjectures are proposed for the statistical description of quantum (non-)integrable models. The plausible eigenstate thermalization hypothesis (ETH), which suggests that each energy eigenstate itself is thermal, plays a crucial role in understanding the quantum thermalization in non-integrable systems; it is commonly believed that it does not exist in integrable systems. Nevertheless, integrable systems can still relax to the generalized Gibbs ensemble. From a microscopic perspective, understanding the origin of this generalized thermalization that occurs in an isolated integrable system is a fundamental open question lacking experimental investigations. Herein, we experimentally investigated the spin subsystem relaxation in an isolated spin-orbit coupling quantum system. By applying the quantum state engineering technique, we initialized the system with various distribution widths in the mutual eigenbasis of the conserved quantities. Then, we compared the steady state of the spin subsystem reached in a long-time coherent dynamics to the prediction of a generalized version of ETH and the underlying mechanism of the generalized thermalization is experimentally verified for the first time. Our results facilitate understanding the origin of quantum statistical mechanics.
Understanding the evolution towards thermal equilibrium of an isolated quantum system is at the foundation of statistical mechanics and a subject of interest in such diverse areas as cold atom physics or the quantum mechanics of black holes. Since a pure state can never evolve into a thermal density matrix, the Eigenstate Thermalization Hypothesis (ETH) has been put forward by Deutsch and Srednicki as a way to explain this apparent thermalization, similarly to what the ergodic theorem does in classical mechanics. In this paper this hypothesis is tested numerically. First, it is observed that thermalization happens in a subspace of states (the Krylov subspace) with dimension much smaller than that of the total Hilbert space. We check numerically the validity of ETH in such a subspace, for a system of hard core bosons on a two-dimensional lattice. We then discuss how well the eigenstates of the Hamiltonian projected on the Krylov subspace represent the true eigenstates. This discussion is aided by bringing the projected Hamiltonian to the tridiagonal form and interpreting it as an Anderson localization problem for a finite one-dimensional chain. We also consider thermalization of a subsystem and argue that generation of a large entanglement entropy can lead to a thermal density matrix for the subsystem well before the whole system thermalizes. Finally, we comment on possible implications of ETH in quantum gravity.
Temperature is one of the central concepts of thermodynamics, yet its meaning far from equilibrium remains unclear. The problem is especially challenging in isolated quantum many-body systems, whose states evolve unitarily, may remain far from equilibrium, and retain energy coherence, a genuinely quantum feature with no direct classical counterpart. Specifically, energy fluctuations in a nonstationary quantum state have two distinct origins. Part of these fluctuations comes from uncertainty in the energy populations and has the usual thermodynamic meaning. The rest comes from quantum coherence between energy sectors and is responsible for the state's time dependence. We propose that, even away from equilibrium, temperature identifies the state within the family of regular states sharing the same energy-coherence structure. The resulting inverse temperature is obtained from a principle of minimum discrimination information, which selects the least distinguishable state compatible with the prescribed energy and coherence structure. This replaces the usual maximum-entropy principle, which, applied naively, can yield a biased estimator of the inverse temperature. We also lay the groundwork for an extension of the construction to subsystems and show that, although the inverse temperature of a subsystem is not determined by its reduced state alone, under an alignment assumption, its instantaneous rate of change is a local quantity for sufficiently large subsystems.