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arXiv:2112.07860 · Physical Review Research

Operational models of temperature superpositions

Carolyn E. Wood, Harshit Verma, Fabio Costa, Magdalena Zych

Published Nov 8, 2025• 1 citation
arXivHTMLPDF

Abstract

An interacting quantum system and thermal bath can reach thermal equilibrium, resulting in the system and bath acquiring the same temperature. But how does a delocalized quantum system thermalize with a bath whose local temperature varies as, for example, in the Tolman effect? Here, we formulate two scenarios in which the notion of a “superposition of temperatures” may arise: first, a probe interaction with two different baths dependent on the state of another quantum system (a control); and second, a probe interaction with a single bath whose purified state is a superposition of states that each correspond to different temperatures. We show that the two scenarios are fundamentally different and can be operationally distinguished. Moreover, we show that the final probe state is sensitive to the specific realization of the thermalizing channels, and that our results hold for partial and prethermalization cases. Our models may be applied to scenarios involving joint quantum and relativistic phenomena, and explain some recent results found in quantum interference of relativistic probes thermalizing with Unruh or Hawking radiation.

DOI
10.1103/wf8m-zkqg

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An interacting quantum system and thermal bath can reach thermal equilibrium, resulting in the system and bath acquiring the same temperature. But how does a delocalized quantum system thermalize with a bath whose local temperature varies as, for example, in the Tolman effect? Here, we formulate two scenarios in which the notion of a “superposition of temperatures” may arise: first, a probe interaction with two different baths dependent on the state of another quantum system (a control); and second, a probe interaction with a single bath whose purified state is a superposition of states that each correspond to different temperatures. We show that the two scenarios are fundamentally different and can be operationally distinguished. Moreover, we show that the final probe state is sensitive to the specific realization of the thermalizing channels, and that our results hold for partial and prethermalization cases. Our models may be applied to scenarios involving joint quantum and relativistic phenomena, and explain some recent results found in quantum interference of relativistic probes thermalizing with Unruh or Hawking radiation.
The usual paradigm of open quantum systems falls short when the environment is actually coupled to additional fields or components that drive it out of equilibrium. Here we explore the simplest such scenario, by considering a two level system coupled to a first thermal reservoir that in turn couples to a second thermal bath at a different temperature. We derive a master equation description for the system and show that, in this situation, the dynamics can be especially rich. In particular, we observe prethermalization, a transitory phenomenon in which the system initially approaches thermal equilibrium with respect to the first reservoir, but after a longer time converges to the thermal state dictated by the temperature of the second environment. Using analytical arguments and numerical simulations, we analyze the occurrence of this phenomenon, and how it depends on temperatures and coupling strengths. The phenomenology gets even richer if the system is placed between two such non-equilibrium environments. In this case, the energy current through the system may exhibit transient features and even switch direction, before the system eventually reaches a non-equilibrium steady state.
Abstract The usual paradigm of open quantum systems falls short when the environment is actually coupled to additional fields or components that drive it out of equilibrium. Here we explore the simplest such scenario, by considering a two level system coupled to a first thermal reservoir that in turn couples to a second thermal bath at a different temperature. We derive a master equation description for the system and show that, in this situation, the dynamics can be especially rich. In particular, we observe prethermalization, a transitory phenomenon in which the system initially approaches thermal equilibrium with respect to the first reservoir, but after a longer time converges to the thermal state dictated by the temperature of the second environment. Using analytical arguments and numerical simulations, we analyze the occurrence of this phenomenon, and how it depends on temperatures and coupling strengths. The phenomenology gets even richer if the system is placed between two such non-equilibrium environments. In this case, the energy current through the system may exhibit transient features and even switch direction, before the system eventually reaches a non-equilibrium steady state.
We address a particular instance where open quantum systems may be used as quantum probes for an emergent property of a complex system, as the temperature of a thermal bath. The inherent fragility of the quantum probes against decoherence is the key feature making the overall scheme very sensitive. The specific setting examined here is that of quantum thermometry, which aims to exploit decoherence as a resource to estimate the temperature of a sample. We focus on temperature estimation for a bosonic bath at equilibrium in the Ohmic regime (ranging from sub-Ohmic to super-Ohmic), by using pairs of qubits in different initial states and interacting with different environments, consisting either of a single thermal bath or of two independent ones at the same temperature. Our scheme involves pure dephasing of the probes, thus avoiding energy exchange with the sample and the consequent perturbation of temperature itself. We discuss the role of correlations among the probes and the presence of a local versus a global bath. We show that entanglement improves thermometry at short times if the two qubits are embedded in a common bath, whereas if the interaction time is not constrained, then coherence rather than entanglement is the key resource in quantum thermometry.
Temperature is usually defined for physical systems at thermal equilibrium. Nevertheless one may wonder if it would be possible to attribute a meaningful notion of temperature to an arbitrary quantum state, beyond simply the thermal (Gibbs) state. In this Letter, we propose such a notion of temperature considering an operational task, inspired by the zeroth law of thermodynamics. Specifically, we define two effective temperatures for quantifying the ability of a quantum system to cool down or heat up a thermal environment. In this way we can associate an operationally meaningful notion of temperature to any quantum density matrix. We provide general expressions for these effective temperatures, for both single- and many-copy systems, establishing connections to concepts previously discussed in the literature. Finally, we consider a more sophisticated scenario where the heat exchange between the system and the thermal environment is assisted by a quantum reference frame. This leads to an effect of "coherent quantum catalysis," where the use of a coherent catalyst allows for exploiting quantum energetic coherences in the system, now leading to much colder or hotter effective temperatures. We demonstrate our findings using a two-level atom coupled to a single mode of the electromagnetic field.
Prethermalization When a physical system is subjected to a rapid change of conditions (for example, a gas of atoms is allowed to occupy a volume twice the size of the original container), it quickly achieves a new temperature (thermalizes) through collisions. However, in some quantum systems many conserved variables inhibit thermalization; understanding the phases the systems go through in the slowing process is of great interest to cosmologists and physicists. Gring et al. (p. 1318 , published online 31 August) separate an ultracold one-dimensional gas of bosonic atoms into two nearly identical halves, and follow how local differences in phase between the halves evolve in time by examining their interference. Initially, the local phases are almost identical, but a rapid decoherence ensues, followed by a very slow further decay. The authors analyze the relative state reached after the initial fast decay and find that it can be described by an equilibrium function with an effective temperature several times less than the initial temperature. Because this cannot be the final state of the system, the authors term the initial process prethermalization.
One of the fundamental problems of quantum statistical physics is how an ideally isolated quantum system can ever reach thermal equilibrium behavior despite the unitary time evolution of quantum-mechanical systems. Here, we study, via explicit time evolution for the generic model system of an interacting, trapped Bose gas with discrete single-particle levels, how the measurement of one or more observables subdivides the system into observed and non-observed Hilbert subspaces and the tracing over the non-measured quantum numbers defines an effective, thermodynamic bath, induces the entanglement of the observed Hilbert subspace with the bath, and leads to a bi-exponential approach of the entanglement entropy and of the measured observables to thermal equilibrium behavior as a function of time. We find this to be more generally fulfilled than in the scenario of the eigenstate thermalization hypothesis (ETH), namely for both local particle occupation numbers and non-local density correlation functions, and independent of the specific initial quantum state of the time evolution.