Ultracold polar molecules are promising candidate qubits for quantum computing and quantum simulations. Their long-lived molecular rotational states form robust qubits, and the long-range dipolar interaction between molecules provides quantum entanglement. In this work, we demonstrate dipolar spin-exchange interactions between single calcium monofluoride (CaF) molecules trapped in an optical tweezer array. We realized the spin-[Formula: see text] quantum XY model by encoding an effective spin-[Formula: see text] system into the rotational states of the molecules and used it to generate a Bell state through an iSWAP operation. Conditioned on the verified existence of molecules in both tweezers at the end of the measurement, we obtained a Bell state fidelity of 0.89(6). Using interleaved tweezer arrays, we demonstrate single-site molecular addressability.Ultracold polar molecules are promising candidate qubits for quantum computing and quantum simulations. Their long-lived molecular rotational states form robust qubits, and the long-range dipolar interaction between molecules provides quantum entanglement. In this work, we demonstrate dipolar spin-exchange interactions between single calcium monofluoride (CaF) molecules trapped in an optical tweezer array. We realized the spin-[Formula: see text] quantum XY model by encoding an effective spin-[Formula: see text] system into the rotational states of the molecules and used it to generate a Bell state through an iSWAP operation. Conditioned on the verified existence of molecules in both tweezers at the end of the measurement, we obtained a Bell state fidelity of 0.89(6). Using interleaved tweezer arrays, we demonstrate single-site molecular addressability.

arXiv:2211.09780ScienceDec 7, 2023126 citations

Quantum engineering for optical clocks

Christian Lisdat, Carsten Klempt

NatureDec 16, 20203 citations

Multi-qubit gates and Schrödinger cat states in an optical clock

Alec Cao, William J. Eckner, Theodor Lukin Yelin +8 more

arXiv:2402.16289NatureOct 9, 2024110 citations

Long-lived metastable states in the 4f$^{13} $5d6s configuration of Yb$ ^+$Long-lived metastable states in the 4f$^{13}$5d6s configuration of Yb$^+$

Z. E. D. Ackerman, A. Cadarso Quevedo, Ilango Maran +4 more

We study the occurrence of long-lived metastable states in the 4f$^{13} $5d6s electron configuration of Yb$ ^+$. By optical pumping of a single trapped ion on the $^2F^\text{o}_{7/2}\rightarrow (7/2,0)_{7/2}$ transition at 377.5 nm, we prepare a wide range of metastable electronic states. We use a co-trapped control ion to sympathetically cool the spectroscopy ion, allowing us to accurately time its subsequent decay. We record a strong decay signal corresponding to a lifetime of 0.92(8) s, a weaker decay signal with lifetime 9.8(+2.9, -2.0) s, and find evidence for a much longer lifetime, $>$ 30 s. We identify the metastable states with these lifetimes qualitatively, and corroborate our results with atomic structure calculations that support the observed lifetimes and decay paths. These long-lived states provide new opportunities in qubit and qudit state detection and optical clocks.We study the occurrence of long-lived metastable states in the 4f$^{13}$5d6s electron configuration of Yb$^+$. By optical pumping of a single trapped ion on the $^2F^\text{o}_{7/2}\rightarrow (7/2,0)_{7/2}$ transition at 377.5 nm, we prepare a wide range of metastable electronic states. We use a co-trapped control ion to sympathetically cool the spectroscopy ion, allowing us to accurately time its subsequent decay. We record a strong decay signal corresponding to a lifetime of 0.92(8) s, a weaker decay signal with lifetime 9.8(+2.9, -2.0) s, and find evidence for a much longer lifetime, $>$ 30 s. We identify the metastable states with these lifetimes qualitatively, and corroborate our results with atomic structure calculations that support the observed lifetimes and decay paths. These long-lived states provide new opportunities in qubit and qudit state detection and optical clocks.

physics.atom-phCross-listedarXiv:2603.04250Physical Review AMar 5, 20261 citation

Subradiant Bell States in Distant Atomic Arrays

P.-O. Guimond, Andrey Grankin, Denis V. Vasilyev +2 more

We study collective "free-space" radiation properties of two distant single-layer arrays of quantum emitters as two-level atoms. We show that this system can support a long-lived Bell superposition state of atomic excitations exhibiting strong subradiance, which corresponds to a nonlocal excitation of the two arrays. We describe the preparation of these states and their application in quantum information as a resource of nonlocal entanglement, including deterministic quantum state transfer with high fidelity between the arrays representing quantum memories. We discuss experimental realizations using cold atoms in optical trap arrays with subwavelength spacing, and analyze the role of imperfections.We study collective "free-space" radiation properties of two distant single-layer arrays of quantum emitters as two-level atoms. We show that this system can support a long-lived Bell superposition state of atomic excitations exhibiting strong subradiance, which corresponds to a nonlocal excitation of the two arrays. We describe the preparation of these states and their application in quantum information as a resource of nonlocal entanglement, including deterministic quantum state transfer with high fidelity between the arrays representing quantum memories. We discuss experimental realizations using cold atoms in optical trap arrays with subwavelength spacing, and analyze the role of imperfections.

arXiv:1901.02665Physical Review LettersMar 5, 2019144 citations

Individual Optical Addressing of Atomic Clock Qubits With Stark Shifts

Aaron Lee, Jacob Smith, Phil Richerme +4 more

Bulletin of the American Physical SocietyMay 26, 20160 citations

Long-lived metastable states in the 4f$^{13}

5d6s configuration of Yb

^+$

We study the occurrence of long-lived metastable states in the 4f$^{13}

5d6s electron configuration of Yb

^+$. By optical pumping of a single trapped ion on the

^2F^\text{o}_{7/2}\rightarrow (7/2,0)_{7/2}

transition at 377.5 nm, we prepare a wide range of metastable electronic states. We use a co-trapped control ion to sympathetically cool the spectroscopy ion, allowing us to accurately time its subsequent decay. We record a strong decay signal corresponding to a lifetime of 0.92(8) s, a weaker decay signal with lifetime 9.8(+2.9, -2.0) s, and find evidence for a much longer lifetime,

>

30 s. We identify the metastable states with these lifetimes qualitatively, and corroborate our results with atomic structure calculations that support the observed lifetimes and decay paths. These long-lived states provide new opportunities in qubit and qudit state detection and optical clocks.