Abstract The macroscopic fluctuation theory (MFT) is an effective framework to describe transports and their fluctuations in classical out-of-equilibrium diffusive systems. Whether the MFT may be extended to the quantum realm and which form this extension may take is yet terra incognita but is a timely question. In this short introductory review, I discuss possible questions that a quantum version of the MFT could address and how analysing quantum simple exclusion processes yields pieces of answers to these questions.
Abstract The macroscopic fluctuation theory (MFT) is an effective framework to describe transports and their fluctuations in classical out-of-equilibrium diffusive systems. Whether the MFT may be extended to the quantum realm and which form this extension may take is yet terra incognita but is a timely question. In this short introductory review, I discuss possible questions that a quantum version of the MFT could address and how analysing quantum simple exclusion processes yields pieces of answers to these questions.
A universal characterization of non-equilibrium steady states in interacting quantum many-body systems remains one of the central challenges of statistical physics. Here, we address this problem for a paradigmatic model of diffusive interacting quantum matter---the boundary-driven XXZ spin chain with bulk dephasing---and derive, directly from its microscopic Lindblad dynamics, an emergent classical Macroscopic Fluctuation Theory (MFT) governing its large-scale fluctuations. Crucially, the resulting hydrodynamics carries a density-dependent diffusivity and mobility as the fingerprint of interactions. This effective description enables the exact computation of the stationary density profile, long-range correlations, and the full counting statistics of the current, in excellent agreement with tensor-network simulations. Our work demonstrates that noisy quantum many-body systems can realize the universality class of genuinely interacting diffusive matter, beyond the constant-diffusivity class of the symmetric simple exclusion process, and establishes MFT as a powerful universal framework for interacting diffusive quantum systems.
We study the fluctuation statistics of integrated currents in noisy quantum diffusive systems, focusing on the Quantum Symmetric Simple Exclusion and Inclusion Processes (QSSEP/QSSIP). These one-dimensional fermionic (QSSEP) and bosonic (QSSIP) models feature stochastic nearest-neighbor hopping driven by Brownian noise, together with boundary injection and removal processes. They provide solvable microscopic settings in which quantum coherence coexists with diffusion. Upon noise averaging, their dynamics reduce to those of the classical SSEP/SSIP. We show that the cumulant-generating function of the integrated current, at large scales, obeys a large deviation principle. To leading order in system size and for each noise realization, it converges to that of the corresponding classical process, establishing a classical typicality of current fluctuations in these noisy quantum systems. We further demonstrate a direct connection with Macroscopic Fluctuation Theory (MFT), showing that the large-scale equations satisfied by biased quantum densities coincide with the steady-state Hamilton equations of MFT, thereby providing a microscopic quantum justification of the MFT framework in these models. Finally, we identify the leading finite-size corrections to the current statistics. We show the existence of subleading contributions of purely quantum origin, which are absent in the corresponding classical setting, and provide their explicit expressions for the second and third current cumulants. These quantum corrections are amenable to direct experimental or numerical verification, provided sufficient control over the noise realizations can be achieved. Their presence points toward the necessity of a quantum extension of MFT.
We introduce a new universal framework describing fluctuations and correlations in quantum and classical many-body systems, at the Euler hydrodynamic scale of space and time. The framework adapts the ideas of the conventional macroscopic fluctuation theory (MFT) to systems that support ballistic transport. The resulting “ballistic MFT” (BMFT) is solely based on the Euler hydrodynamics data of the many-body system. Within this framework, mesoscopic observables are classical random variables depending only on the fluctuating conserved densities, and Euler-scale fluctuations are obtained by deterministically transporting thermodynamic fluctuations via the Euler hydrodynamics. Using the BMFT, we show that long-range correlations in space generically develop over time from long-wavelength inhomogeneous initial states in interacting models. This result, which we verify by numerical calculations, challenges the long-held paradigm that at the Euler scale, fluid cells may be considered uncorrelated. We also show that the Gallavotti-Cohen fluctuation theorem for non-equilibrium ballistic transport follows purely from time-reversal invariance of the Euler hydrodynamics. We check the validity of the BMFT by applying it to integrable systems, and in particular the hard-rod gas, with extensive simulations that confirm our analytical results.
Abstract Processes at the nanoscale happen far away from the thermodynamic limit, far from equilibrium and are dominated by fluctuations and, perhaps, even quantum effects. This book establishes a consistent thermodynamic framework for such processes by combining tools from non-equilibrium statistical mechanics and the theory of open quantum systems. The book is accessible for graduate students and of interest to all researchers striving for a deeper understanding of the laws of thermodynamics beyond their traditional realm of applicability. It puts most emphasis on the microscopic derivation and understanding of key principles and concepts as well as their interrelation. The topics covered in this book include (quantum) stochastic processes, (quantum) master equations, local detailed balance, classical stochastic thermodynamics, (quantum) fluctuation theorems, strong coupling and non non-Markovian effects, thermodynamic uncertainty relations, operational approaches, Maxwell's demon and time-reversal symmetry, among other topics. Furthermore, the book treats a few applications in detail to illustrate the general theory and its potential for practical applications. These are single-molecule pulling experiments, quantum transport and thermoelectric effects in quantum dots, the micromaser and related set-ups in quantum optics.
Macroscopic quantum phenomena (MQP) is a relatively new research venue, with exciting ongoing experiments and bright prospects, yet with surprisingly little theoretical activity. What makes MQP intellectually stimulating is because it is counterpoised against the traditional view that macroscopic means classical. This simplistic and hitherto rarely challenged view need be scrutinized anew, perhaps with much of the conventional wisdoms repealed. In this series of papers we report on a systematic investigation into some key foundational issues of MQP, with the hope of constructing a viable theoretical framework for this new endeavour. The three major themes discussed in these three essays are the large N expansion, the correlation hierarchy and quantum entanglement for systems of 'large' sizes, with many components or degrees of freedom. In this paper we use different theories in a variety of contexts to examine the conditions or criteria whereby a macroscopic quantum system may take on classical attributes, and, more interestingly, that it keeps some of its quantum features. The theories we consider here are, the O ( N ) quantum mechanical model, semiclassical stochastic gravity and gauge / string theories; the contexts include that of a 'quantum roll' in inflationary cosmology, entropy generation in quantum Vlasov equation for plasmas, the leading order and next-to-leading order large N behaviour, and hydrodynamic / thermodynamic limits. The criteria for classicality in our consideration include the use of uncertainty relations, the correlation between classical canonical variables, randomization of quantum phase, environment-induced decoherence, decoherent history of hydrodynamic variables, etc. All this exercise is to ask only one simple question: Is it really so surprising that quantum features can appear in macroscopic objects? By examining different representative systems where detailed theoretical analysis has been carried out, we find that there is no a priori good reason why quantum phenomena in macroscopic objects cannot exist.
We use macroscopic fluctuation theory (MFT) to establish the typicality of charge-transfer statistics and entanglement dynamics in the quantum symmetric exclusion process, a model of stochastically hopping free fermions with diffusive transport and long-range quantum coherence. We show that the leading long-time charge-transfer full counting statistics of individual noise realizations coincide almost surely with those of the classical symmetric exclusion process (SSEP), in equilibrium and following quenches from arbitrary occupation-diagonal product states. Our results apply to transient fluctuations in the thermodynamic limit, extending previous work that has primarily focused on stationary regimes. Our approach compares the noise averages of the charge-transfer generating function and its inverse. The former reduces to SSEP, while the latter maps to an auxiliary Brownian energy process whose MFT saddle-point problem is related to that of SSEP, yielding matching large-deviation exponents. Through free-fermion identities relating entanglement to subsystem-number fluctuations, this establishes the self-averaging of the covariance-matrix eigenvalue distribution and of Rényi and von Neumann entropies. We obtain asymptotically exact predictions for entanglement growth from domain-wall and Néel initial states, in excellent agreement with numerical simulations.